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1.
《Mendeleev Communications》2022,32(4):534-536
Correlation times and diffusion coefficients of water molecules were measured for the first time by 1H spin relaxation and pulsed field gradient NMR in Li+, Na+ and Cs+ ionic forms of Nafion 117 membrane. Hydration numbers of Li+, Na+ and Cs+ cations were calculated. It was shown that at high humidity macroscopic transfer is controlled by the local translational motion of water molecules. 相似文献
2.
Lei Chen Hui-Qing Yang Cheng-Yu Jin Zhao-Xu Chen 《International journal of quantum chemistry》2020,120(22):e26366
We studied the ring opening of propylene oxide (PO) by salen-M coordinated OH− group [M = Al(III), Sc(III), Cr(III), Mn(III), Fe(III), Co(II), Co(III), Ni(II), Cu(II), Zn(II), Ru(III) and Rh(III)]. The results show that the ring-opening energy barriers for M(II) complexes are much lower than those with M(III) complexes in the gas phase, and the barriers correlate linearly with the negative charges on the OH− group and the Fukui function condensed on the OH− group. The nucleophilicity ordering in the gas phase can be rationalized by the ratio of formal positive charges/radius of M cations. Solvent effect greatly increases the barriers of M(II) complexes but slightly changes the results of M(III) ones, making the barriers similar. Analysis indicates that the reaction heats are linearly proportional to the reverse reaction barriers. The relationships established here can be used to estimate the ring-opening barriers and to screen epoxide ring-opening catalysts. 相似文献
3.
Alexander Krasnosel'skii Dmitrii Rachinskii 《NoDEA : Nonlinear Differential Equations and Applications》2002,9(1):93-115
We consider autonomous systems with a nonlinear part depending on a parameter and study Hopf bifurcations at infinity. The
nonlinear part consists of the nonlinear functional term and the Prandtl--Ishlinskii hysteresis term. The linear part of the
system has a special form such that the close-loop system can be considered as a hysteresis perturbation of a quasilinear
Hamiltonian system. The Hamiltonian system has a continuum of arbitrarily large cycles for each value of the parameter. We
present sufficient conditions for the existence of bifurcation points for the non-Hamiltonian system with hysteresis. These
bifurcation points are determined by simple characteristics of the hysteresis nonlinearity. 相似文献
4.
This paper presents an enhanced version of the elasto-plastic model for partially saturated soil first proposed by Bolzon,
Schrefler and Zienkiewicz in 1996, “BSZ” model, which uses the effective stress tensor and suction as independent stress variables.
It is recalled that the effective stress tensor proposed by Lewis and Schrefler in 1982 is thermodynamically consistent and,
compared with other choices of stress tensors, results particularly suitable for partially saturated soil mechanics. A hydraulic
constitutive relationship and a hydraulic hysteresis are introduced in the model, to take into account the irreversible deformation
during cyclic drying and wetting until structural collapse. For this reason the plastic rate of strain is split into the sum
of two components: one depending on the effective stress tensor and the other one on suction. This is the new feature of the
BSZ model. This enhanced model is then cast into a thermodynamical framework at macroscopic level and it is shown that it
is possible to derive the constitutive law from the Helmholtz free energy and a dissipation function, both for associative
and non- associative plasticity. Finally the model predictions have been compared with experimental data for Sion slime, with
particular emphasis on the deviatoric part, and model predictions of hysteretic behaviour have been investigated in case of
a wetting and drying cycle on compacted betonite–kaolin. 相似文献
5.
6.
Efforts are made to explore the hysteresis characteristics of vortex shedding in a pipe flow, whose velocity varies periodically in time. Results obtained show that during acceleration of the flow, the vortex strength tends to be stronger, whereas during deceleration of the flow, the situation is reversed. As reconstructed from the velocity signals measured at a point in the flow field, the shed vortex arrays appear to possess uneven vortex strengths in response to periodically-varying incoming flows. Furthermore, in the hysteresis range, the streamwise spacings between the vortices appear to be unequal. 相似文献
7.
Y. Oner O. Kamer Joseph H. Ross Jr. 《Journal of magnetism and magnetic materials》2006,300(2):373-381
We report resistivity and magnetization measurements on an amorphous Ni74Mn24Pt2 thin film in the temperature range of 3–300 K. Two significant features are apparent in both the magnetic susceptibility and electrical resistivity. A low-temperature (low-T) anomaly is observed at about 40 K, where a cusp appears in the resistivity, while a concomitant step-like increase in zero-field-cooled (ZFC) magnetization (M) appears with increasing temperature. The low-T anomaly is attributed to a crossover from a pure re-entrant spin-glass within individual domains to a mixed ferro-spin-glass regime at lower temperatures. By contrast, the high-temperature (high-T) anomaly, signaled by the appearance of hysteresis below 250 K, corresponds to the freezing of transverse spins in individual domains acting independently. Between the low-T and high-T anomalies a small but discernable magnetic hysteresis is observed for warming vs. cooling in the field-cooled (FC) case. This behavior clearly indicates the presence of domain structure in the sample, while the disappearance of this hysteresis at lower temperatures indicates the complete freezing of the spin orientation of these domains. According to these results, we have divided the magnetic state of this sample into three regions: at temperatures above 250 K, the sample behaves like a soft ferromagnet, exhibiting M vs. H loops with very small hysteresis (less than 5 Oe). As the temperature is lowered into the intermediate region (the range 40–250 K), spins become frozen randomly and progressively within the individual domains. These domains behave independently, rather than as a cooperative behavior of the sample. Weak irreversibility sets in, indicating the onset of transverse spin freezing within the domains. At temperatures below 40 K, the M vs. H loops exhibit larger hysteresis, for both the ZFC and FC cases, as in a pure spin-glass. We have also demonstrated giant noise in the resistivity at temperatures just below 250 K. Such noise can originate from fluctuations of the domains near the film surface because of competing effective bulk and surface anisotropy fields. The large observed amplitude may be explained by means of a large ferromagnetic anisotropy in the resistivity due to the large spin–orbit effect seen in NiMn systems. Finally, the low-T peak in the resistivity has been analyzed using Fisher and Langer's expression based on the Friedel Model proposed for critical transitions in transition metals (s–d systems). The fitted results are in satisfactory agreement with the predictions of this model. 相似文献
8.
Adhesion of zein to solid substrates has been studied using surface energy profiles as indices and by adhesion mapping using
atomic force microscopy (AFM). Different plasticizers like glycerol and sorbitol have been used to form mixed films with zein
and properties of these films are studied using surface energy profiles. Comparison of the results from the different mixed
samples with those from the pure zein films showed that force mapping could identify areas rich in protein. The adhesion maps
produced were deconvoluted from sample topography and contrasted with the data obtained from contact angle measurements. A
comparison of the two methods shows that the extent of contact angle hysteresis is indicative of both hydrophobicity of the
surface as well as the force of adhesion. Mechanical properties and microstructure of zein films prepared by casting from
solutions and using Langmuir-Blodgett film technique have been investigated. Pure zein seemed brittle and exhibited an essentially
linear relationship between stress and strain. Films with plasticizer were tougher than these films. In general, mixed films
showed better mechanical properties than pure films and had higher ultimate tensile strength and increased per cent elongation.
Further, the mixed films of zein showed a higher force of adhesion compared to the pure films. 相似文献
9.
10.
P. Mun F. C. Fonseca R. Muccillo R. F. Jardim 《Physica C: Superconductivity and its Applications》2003,390(4):363-373
A systematic study of the magnetic hysteresis in transport properties of polycrystalline YBa2Cu3O7−δ–Ag compounds has been made based on two kinds of measurements at 77 K and under applied magnetic fields up to 30 mT: critical current density Jc(Ba) and magnetoresistance R(Ba). The R(Ba) curves show a minimum in their decreasing branch occurring at B=Bmin which was found to be both the excitation current Iex and the maximum applied magnetic field Bam dependent. In addition, for a certain value of Bam>5 mT, we have observed that Bmin increases with increasing Iex and reaches a saturation value. The Jc(Ba) curves show a maximum in decreasing applied magnetic fields occurring at B=Bmax. We have also found that Bmax increases with increasing Bam and reaches a saturation value. The minimum in the R(Ba) and the maximum in Jc(Ba) curves were found to be related to the trapped flux within the grains. All the experimental results are discussed within the context of the flux dynamics and transport mechanisms in these high-Tc materials. 相似文献