全文获取类型
收费全文 | 3466篇 |
免费 | 463篇 |
国内免费 | 172篇 |
专业分类
化学 | 3226篇 |
晶体学 | 39篇 |
力学 | 264篇 |
综合类 | 18篇 |
数学 | 430篇 |
物理学 | 124篇 |
出版年
2024年 | 1篇 |
2023年 | 19篇 |
2022年 | 43篇 |
2021年 | 65篇 |
2020年 | 129篇 |
2019年 | 76篇 |
2018年 | 82篇 |
2017年 | 87篇 |
2016年 | 212篇 |
2015年 | 167篇 |
2014年 | 186篇 |
2013年 | 299篇 |
2012年 | 172篇 |
2011年 | 169篇 |
2010年 | 174篇 |
2009年 | 163篇 |
2008年 | 189篇 |
2007年 | 212篇 |
2006年 | 229篇 |
2005年 | 211篇 |
2004年 | 169篇 |
2003年 | 181篇 |
2002年 | 134篇 |
2001年 | 85篇 |
2000年 | 77篇 |
1999年 | 96篇 |
1998年 | 88篇 |
1997年 | 75篇 |
1996年 | 45篇 |
1995年 | 48篇 |
1994年 | 40篇 |
1993年 | 18篇 |
1992年 | 26篇 |
1991年 | 22篇 |
1990年 | 19篇 |
1989年 | 13篇 |
1988年 | 17篇 |
1987年 | 13篇 |
1986年 | 14篇 |
1985年 | 17篇 |
1984年 | 11篇 |
1983年 | 4篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有4101条查询结果,搜索用时 15 毫秒
1.
Dr. Liat Avram Dr. Václav Havel Ronit Shusterman-Krush Dr. Mark A. Iron Dr. Moritz Zaiss Prof. Vladimír Šindelář Dr. Amnon Bar-Shir 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(7):1687-1690
The accumulated knowledge regarding molecular architectures is based on established, reliable, and accessible analytical tools that provide robust structural and functional information on assemblies. However, both the dynamicity and low population of noncovalently interacting moieties within studied molecular systems limit the efficiency and accuracy of traditional methods. Herein, the use of a saturation transfer-based NMR approach to study the dynamic binding characteristics of an anion to a series of synthetic receptors derived from bambusuril macrocycles is demonstrated. The exchange rates of BF4− are mediated by the side chains on the receptor (100 s−1<kex<5000 s−1), which play a critical role in receptor-anion binding dynamics. The signal amplification obtained with this approach allows for the identification of different types of intermolecular interactions between the receptor and the anion, something that could not have been detected by techniques hitherto used to study molecular assemblies. These findings, which are supported by a computational molecular dynamic study, demonstrate the uniqueness and added value of this NMR method. 相似文献
2.
3.
4.
Katsunari Inoue Kazuaki Kato Norimitsu Tohnai Mikiji Miyata 《Journal of polymer science. Part A, Polymer chemistry》2004,42(18):4648-4655
We studied simulations by computer graphics to estimate the steric mechanism of the asymmetric polymerization of prochiral diene monomers in channels of inclusion compounds of steroidal bile acids, such as deoxycholic acid (DCA) and cholic acid. We applied a hierarchization method to interpret the crystal structures of bile acids, clarifying that the chiral host molecules associated to form characteristic 21-helical assemblies with uneven surfaces. A detailed analysis of the uneven channels in a close-packing state indicated that there were many possible arrangements of the monomers in the channels. The plausible arrangements in the channel could explain a previous study, which showed that the polymerization in the DCA channel yielded chiral polymers with a predominant configuration from prochiral diene monomers, such as 2-methyl-trans-1,3-pentadiene. On the basis of such simulation studies of the arrangements of guest monomers in the channel, we examined a plausible steric mechanism for asymmetric inclusion polymerization. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4648–4655, 2004 相似文献
5.
Thorsten Brand Kyle Ratinac Jeffrey V. Castro Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5706-5713
A method was developed for free‐radical polymerization in the confines of a hollow latex particle. Hollow particles were prepared via the dynamic swelling method from polystyrene seed and divinylbenzene and had hollows of 500–1000 nm. So that these hollow poly(divinylbenzene) particles could function as submicrometer reactors, the particles were filled with a monomer (N‐isopropylacrylamide) via the dispersion of the dried particles in the molten monomer. The monomer that was not contained in the hollows was removed by washing and gentle abrasion. Free‐radical polymerization was then initiated by γ radiolysis in the solid state. Transmission electron microscopy showed that poly(N‐isopropylacrylamide) formed in the hollow interior of the particles, which functioned as submicrometer reactors. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5706–5713, 2004 相似文献
6.
7.
基于无穷维空间中的生存定理,我们研究了集值映象的不动点,得到了一个新的不动点定理,推广和改进了[1]和[5]中的相应结果。 相似文献
8.
F. Rubio F. García H. D. Burrows A. A. C. C. Pais A. J. M. Valente M. J. Tapia J. M. García 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1788-1799
The interaction between trivalent lanthanide ions and poly(1,4,7,10,13‐pentaoxacyclopentadecan‐2‐yl‐methyl methacrylate), PCR5, in aqueous solution and in the solid state have been studied. In aqueous solution, evidence of a weak interaction between the lanthanides and PCR5 comes from the small red shift of the Ce(III) emission spectra and the slight broadening of the Gd(III) EPR spectra. From the Tb(III) lifetimes in the presence of H2O and D2O the loss of one or two water coordinated molecules is confirmed when Tb(III) is bound to PCR5. An association constant of the order of 200 M?1 was obtained for a 1:1 (lanthanide:15‐crown‐5) complex from the shift of the polymer NMR signals induced by Tb(III). A similar association constant is obtained from the differences of the molar conductivity of Ce(III) solution at various concentrations in presence and absence of PCR5. When Tb(III) is adsorbed on PCR5 membranes, lifetime experiments in H2O and D2O confirm the loss of 5 or 6 water coordinated molecules indicating that in solid state the lanthanide(III)‐PCR5 interaction is stronger than in solution. The adsorption of Ce(III) in PCR5 membranes shows a Langmuir type isotherm, from which an equilibrium constant of 39 M?1 has been calculated. SEM shows that the membrane morphology is not much affected by lanthanide adsorption. Support for lanthanide ion–crown interactions comes from ab initio calculations on 15‐crown‐5/La(III) complex. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1788–1799, 2007 相似文献
9.
10.
B. Satco 《Journal of Mathematical Analysis and Applications》2007,332(2):919-933
Existence theorems and some properties of solutions set of three boundary value second order differential equations and inclusions in Banach spaces are obtained under Henstock, respectively Henstock-Kurzweil-Pettis integrability assumptions. Our results extend those obtained by Azzam, Castaing and Thibault in the Bochner integrability setting and in the Pettis integrability one. The continuity of the (unique) solution with respect to a parameter in the single-valued case is also studied. 相似文献