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1.
A liquid dewetting method for the determination of the viscoelastic properties of ultrathin polymer films has been extended to study thickness effects on the properties of ultrathin polycarbonate (PC) films. PC films with film thicknesses ranging from 4 to 299 nm were placed on glycerol at temperatures from below the macroscopic glass transition temperature (Tg) to above it with the dewetting responses being monitored. It is found that the isothermal creep results for films of the same thickness, but dewetted at different temperatures can be superposed into one master curve, which is consistent with the fact of PC being a thermorheologically simple material. Furthermore, the results show that the Tg of PC thin films is thickness dependent, but the dependence is weaker than the results for freely standing films and similar to literature data for PC films supported on rigid substrates. It was also found that the rubbery plateau region for the PC films stiffens dramatically, but still less than what has been observed for freely standing polycarbonate films. The rubbery stiffening is discussed in terms of a recently reported model that relates macroscopic segmental dynamics with the stiffening. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1559–1566 相似文献
2.
Chao Liu Liying Wang Lin Yang Famei Wang Chunhong Xu Jingwei Lv Guanglai Fu Xianli Li Qiang Liu Haiwei Mu Tao Sun Paul K. Chu 《Physics letters. A》2019,383(25):3200-3206
A single-polarization filter comprising a gold-coated photonic crystal fiber based on surface plasmon resonance is designed and investigated. The pattern matching and coupled polarization characteristics analyzed by the full-vector finite element method (FEM) and losses at 1,540 nm are achieved to 1,016.01739 dB/cm (x-pol core mode) and 33.81917 dB/cm (y-pol core mode). The crosstalk (CT) value of the 1,540 nm band is ?853.12653 dB for fiber length and the bandwidth is 850 nm. The working wavelength of the filter ranges from 1,280 nm to 1,540 nm by varying the diameter of outer air holes (), the diameter of inner air holes (), the metal film thickness (t), as well as the liquid refractive index (n). 相似文献
3.
《中国物理 B》2021,30(7):76103-076103
It has been a long-standing puzzling problem that some glasses exhibit higher glass transition temperatures(denoting high stability) but lower activation energy for relaxations(denoting low stability). In this paper, the relaxation kinetics of the nanoconfined D-mannitol(DM) glass was studied systematically using a high-precision and high-rate nanocalorimeter.The nanoconfined DM exhibits enhanced thermal stability compared to the free DM. For example, the critical cooling rate for glass formation decreases from 200 K/s to below 1 K/s; the Tg increases by about 20 K–50 K. The relaxation kinetics is analyzed based on the absolute reaction rate theory. It is found that, even though the activation energy E~*decreases,the activation entropy S~*decreases much more for the nanoconfined glass that yields a large activation free energy G~*and higher thermal stability. These results suggest that the activation entropy may provide new insights in understanding the abnormal kinetics of nanoconfined glassy systems. 相似文献
4.
In this work the results of the statistical topometric analysis of fracture surfaces of soda-lime-silica glass with and without ionic exchange treatment are reported. In this case, the mechanism of substitution is K+-Na+. atomic force microscopy (AFM) was employed to record the topometric data from the fracture surface. The roughness exponent (ζ) and the correlation length (ξ) were calculated by the variable bandwidth method. The analysis for both glasses (subjected and non-subjected to ionic exchange) for ζ shows a value ∼0.8, this value agrees well with that reported in the literature for rapid crack propagation in a variety of materials. The correlation length shows different values for each condition. These results, along with those of microhardness indentations suggest that the self-affine correlation length is influenced by the complex interactions of the stress field of microcracks with that resulting from the collective behavior of the point defects introduced by the strengthening mechanism of ionic exchange. 相似文献
5.
6.
WANG Zhong HONG Haitao XIAO Hai SUN Changku MENG Yan YE Shenghua 《Chinese Journal of Lasers》1997,6(5):435-440
1.IntroductionAbsolutedistancemeasurementisfarfromanewtopic.However,itisstillafieldstimulatinggreatinterestsnowadaysduetoitSimportantroleinmanufacturingandassembly['J.SincethegreatsuccessachievedbyMichelsonandBenoitwhentheyfirstdevelopedaninterferometertodeterminethestandardmeterintermsofthemonochromaticredcadmiumline,theopticinterferometerhasbeenprovedtobeoneofthemostpreciseandefficientwayindisplacementmeasurementbecauseofitshighdiscriminationandsimplestructure.However,thetraditionalinterfe… 相似文献
7.
We investigate the replica symmetry breaking (RSB) in a neighborhood of the instability point of the replica-symmetric solution in the axial quadrupolar glass model. We show that the solution with the first-stage RSB is stable against the subsequent RSB. Although there is no reflection symmetry, the first-stage RSB solution continuously bifurcates from the replica-symmetric one. This implies that our model does not belong to either of the two classes into which spin glasses are usually divided. 相似文献
8.
Stability of chirped bright and dark soliton-like solutions of the cubic complex Ginzburg-Landau equation with variable coefficients 总被引:1,自引:0,他引:1
Fang Fang 《Optics Communications》2006,268(2):305-310
We consider an inhomogeneous optical fiber system described by the generalized cubic complex Ginzburg-Landau (CGL) equation with varying dispersion, nonlinearity, gain (loss), nonlinear gain (absorption) and the effect of spectral limitation. Exact chirped bright and dark soliton-like solutions of the CGL equation were found by using a suitable ansatz. Furthermore, we analyze the features of the solitons and consider the problem of stability of these soliton-like solutions under finite initial perturbations. It is shown by extensive numerical simulations that both bright and dark soliton-like solutions are stable in an inhomogeneous fiber system. Finally, the interaction between two chirped bright and dark soliton-like pulses is investigated numerically. 相似文献
9.
第五讲新型光纤水听器和矢量水听器 总被引:2,自引:0,他引:2
光纤水听器和矢量水听器作为当前水声研究领域最具有代表性的两大技术倍受业界关注。光纤水听器的重要贡献在于,从一个全新的角度出发,试图解决传统的水声传感和声纳数据传输一体化设计和实现的一系列问题,这有助于改善声纳系统的可靠性,并且有可能降低其制造、使用和维护的总成本。矢量水听器则由于其特有的指向性和矢量一相位处理方法,在低频和甚低频水声微弱目标探测方面具有潜在的优势.经过不懈的努力,光纤水听器和矢量水听器系统已经从实验室逐渐进入到工程应用阶段.这些对未来声纳系统的发展会产生相当重要的影响.文章尝试从声纳设计的角度对这两者的技术现状进行简要综述,包括它们各自的物理基础、工作原理、关键技术和应用领域. 相似文献
10.
Franz H. Asthalter T. Dommach M. Ehnes A. Messel K. Sergueev I. 《Hyperfine Interactions》2002,141(1-4):131-134
The present status of the new nuclear resonance beamline PETRA 1 at HASYLAB, DESY, Hamburg is described. Besides an overview
of the experimental setup some examples of recent experiments are given. Those cover the main applications, i.e., inelastic
scattering from iron alloys and quasielastic scattering from glass-forming liquids.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献