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Magalie ColletMichel Baltas Alexandre MartinezCécile Dehoux-Baudoin Liliane Gorrichon 《Tetrahedron letters》2003,44(9):1891-1894
The aldolisation reaction of lithium ethyl fluoroacetate with cis and trans α,β-epoxyaldehydes in their racemic forms proceeds with good C3-OH diastereoselectivity and much less at the C2-F carbon atom. A two-step reaction on the major aldol compounds (iodination, lactonisation) led to racemic functionalised C2 fluorinated lactones, possessing a C2/C3cis relationship between the fluorine and hydroxyl groups. 相似文献
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