The effects of catalysts, pH and reaction conditions on the course of the hydrolysis and condensation of ETS40 (ethyl silicate 40), and on the composition of the reaction products were studied with the aid of gas and gel chromatography, potentiometry and gelation tests. Strong acids (HCl, HClO4, HNO3, H2SO4, p-toluenesulphonic acid), weak acids (Cl3, CCOOH, ClCH2COOH, (COOH)2, CH3COOH and HCOOH) and bases (LiOH, NH4,OH) were used as catalysts.
The hydrolysis rate increased with increasing temperature, catalyst concentration, initial water concentration and initial ethyl silicate concentration, whereas it decreased with increasing number of Si atoms in the ethyl silicate molecules. At pH 0–7 the hydrolysis was acid catalysed, but at pH above 7.0 it was base catalysed. Simultaneously with the hydrolysis, condensation occurred at a rate which increased with increasing temperature, catalyst concentration, ETS40 concentration and, above all, with increasing initial water concentration. The condensation rate depended on the pH. The condensation was at its slowest for pH around 2.0. For pH below 2.0, the condensation increased with increasing hydrogen ion concentration; for pH above 2.0 the condensation increased with decreasing hydrogen ion concentration. Phosphoric acid and hydrofluoric acid increased the rate of condensation considerably. The reaction of ETS40 with water at pH around 2.0 gave rise during the hydrolysis to solutions of ethoxyhydroxysiloxanes with an average of 14–20 Si atoms in a molecule, which displayed long-term stability. 相似文献
Reaction of an aqueous slurry of an Mg2Al-NO3 layered double hydroxide with a four-fold excess of Na[Eu(EDTA)] gives a material which analyses for Mg0.68Al0.32(OH)2[Eu(EDTA)]0.10(CO3)0.11·0.66H2O. The interlayer spacing of the material is 13.8 Å, corresponding to a gallery height of 9.0 Å, which accords with the maximal dimensions (9-10 Å) of the anion in metal-EDTA complex salts as determined by single crystal X-ray diffraction. Geometrical considerations show that the charge density on the layered double hydroxide layers is too high to be balanced by intercalation of [Eu(EDTA)]− alone, necessitating the co-intercalation of carbonate ions which have a much higher charge density. 相似文献
Iron–manganese silicate (IMS) was synthesized by chemical coprecipitation and used as a catalyst for ozonating acrylic acid (AA) in semicontinuous flow mode. The Fe-O-Mn bond, Fe-Si, and Mn-Si binary oxide were formed in IMS on the basis of the results of XRD, FTIR, and XPS analysis. The removal efficiency of AA was highest in the IMS catalytic ozonation processes (98.9% in 15 min) compared with ozonation alone (62.7%), iron silicate (IS) catalytic ozonation (95.6%), and manganese silicate catalytic ozonation (94.8%). Meanwhile, the removal efficiencies of total organic carbon (TOC) were also improved in the IMS catalytic ozonation processes. The IMS showed high stability and ozone utilization. Additionally, H2O2 was formed in the process of IMS catalytic ozonation. Electron paramagnetic resonance (EPR) analysis and radical scavenger experiments confirmed that hydroxyl radicals (•OH) were the dominant oxidants. Cl−, HCO3−, PO43−, Ca2+, and Mg2+ in aqueous solution could adversely affect AA degradation. In the IMS catalytic ozonation of AA, the surface hydroxyl groups and Lewis acid sites played an important role. 相似文献
In this paper, we investigate the exact distribution of the waiting time for ther-th ℓ-overlapping occurrence of success-runs of a specified length in a sequence of two state Markov dependent trials. The
probability generating functions are derived explicitly, and as asymptotic results, relationships of a negative binomial distribution
of orderk and an extended Poisson distribution of orderk are discussed. We provide further insights into the run-related problems from the viewpoint of the ℓ-overlapping enumeration
scheme. We also study the exact distribution of the number of ℓ-overlapping occurrences of success-runs in a fixed number
of trials and derive the probability generating functions. The present work extends several properties of distributions of
orderk and leads us a new type of geneses of the discrete distributions. 相似文献
We study the moduli scheme M(2;0,n) of rank-2 stable vector bundles with Chern classes c1=0, c2=n, on the Fano threefold X – the double space P3 of index two. New component of this scheme is produced via the Serre construction using certain families of curves on X. In particular, we show that the Abel–Jacobi map :HJ(X) of any irreducible component H of the Hilbert scheme of X containing smooth elliptic quintics on X into the intermediate Jacobian J(X) of X factors by Stein through the quasi-finite (probably birational) map g:M of (an open part of) a component M of the scheme M(2;0,3) to a translate of the theta-divisor of J(X). 相似文献
Given a non-trivial torsion-free abelian group (A,+,Q), a field F of characteristic 0, and a non-degenerate bi-additive skew-symmetric map
: AAF, we define a Lie algebra
=
(A,
) over F with basis {ex | xA/{0}} and Lie product [ex,ey] =
(x,y)ex+y. We show that
is endowed uniquely with a non-degenerate symmetric invariant bilinear form and the derivation algebra Der
of
is a complete Lie algebra. We describe the double extension D(
, T) of
by T, where T is spanned by the locally finite derivations of
, and determine the second cohomology group H2(D(
, T),F) using anti-derivations related to the form on D(
, T). Finally, we compute the second Leibniz cohomology groups HL2(
, F) and HL2(D(
, T), F).2000 Mathematics Subject Classification: 17B05, 17B30This work was supported by the NNSF of China (19971044), the Doctoral Programme Foundation of Institution of Higher Education (97005511), and the Foundation of Jiangsu Educational Committee. 相似文献