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1.
聚合物分散液晶光栅的衍射特性的研究 总被引:9,自引:4,他引:5
报道了一种由聚合物分散液晶膜与具有周期性条状电极结构板结合的新型光栅器件,借助于聚合物分散液晶膜的电光特性,这种栅对入射光的散射或衍射取决于对其施加的电压,即它是电场可调的,实验结果显示出当驱动电压超过器件器件阈值电压时,衍射光的强度和衍射斑的可见级次被电场调制,而且它能入射光的线性偏振态变为椭圆偏振态。 相似文献
2.
应用X射线衍射、偏光显微镜及电子显微镜研究了胆甾液晶与甲基丙烯酸甲酯(MMA)─甲基丙烯酸丁酯(BMA)无规共聚物共混体系的形态结构。研究了体系的结晶态及液晶态的行为和共聚物含量及组成对光学织构的影响。 相似文献
3.
Gun'ko V. M. Mikhalovskii S. V. Melillo M. Voronin E. F. Nosach L. V. Pakhlov E. M. 《Theoretical and Experimental Chemistry》2004,40(3):137-143
The interaction of ibuprofen [2-(4-isobutylphenyl)propionic acid] with the surface of carbon and oxide adsorbents was investigated. The significant role of wide pores during the adsorption of ibuprofen on carbon adsorbents in the presence of protein molecules was demonstrated. At low concentrations ibuprofen is adsorbed on the surface of hydrophilic and hydrophobic adsorbents in the form of a monomer, but the contribution from the adsorbed dimer increases with increase in its concentration. 相似文献
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通过将掺杂剂单元用化学键接到聚芴的侧链上,实现了掺杂剂单元在高分子主体中的分子水平分散,开发了一种新型的基于掺杂剂/主体材料体系的分子分散型蓝光聚芴衍生物.与纯聚芴相比,这种新的分子分散型蓝光聚芴衍生物具有很高的荧光量子效率.以这种新的分子分散型蓝光聚芴衍生物为增益介质的激光器件,在Nd:YAG 355 nm脉冲激光泵浦下,获得了较好的放大自发发射光谱,阈值达到0.25 m J/(pulse cm2).从光物理的角度对薄膜的光学增益和光学损耗进行了定量运算和分析,经过拟合发现,当泵浦能量为0.06m J/pulse时,该聚芴衍生物增益系数可达23.08 cm-1,损耗系数为6.96 cm-1.优良的放大自发发射特性表明该聚芴衍生物是非常好的有机激光增益介质材料. 相似文献
8.
In this preliminary report we present the mesomorphic properties and electro-optic investigations of three new 'banana-shaped' mesogens. The materials are structurally similar to Niori's the original bent-core materials but possess alkylthio substituents in place of alkoxy substituents. Microscopic investigations revealed an unusual 'spiral-domain texture', similar to that observed in the 'B7' phase of related materials. Further investigations support our earlier observations that the materials display antiferroelectric switching in this phase, in two of the new materials studied. The nature of this phase, in comparison with the 'switchable' (B2) and 'chiral-domain' (B4) phases of the original materials, is discussed. 相似文献
9.
Polymer dispersed liquid crystal (PDLC) films with the size gradient of the LC droplets were prepared based on the epoxy/acrylate hybrid polymer matrix. The ultraviolet (UV) intensity gradient was induced by the UV-absorbing dye over the thickness of the samples. Taking advantage of the difference between the epoxy monomers and acrylate monomers in polymerisation rates and the UV intensity gradient, the gradient distribution of the LC droplet size was formed in PDLC films. The effect of the size gradient of the LC droplets on the electro-optical and the light-scattering properties of PDLC films was investigated. The results showed that due to the size gradient distribution of the LC droplets, PDLC films could exhibit the strong light scattering in the UV-visible-near infrared (VIS-NIR) region. Consequently, it provides a potential approach for modulating NIR light transmittance. 相似文献
10.
Huimin Zhang Mei Chen Tianmeng Jiang Haiguang Chen Dechao Zhang Yunfeng Sun 《Liquid crystals》2013,40(12):1771-1782
ABSTRACTThe structures of the liquid crystal (LC) molecules have a key role in impacting the electro-optical performance of a polymer dispersed liquid crystal (PDLC) film. In this paper, the relationship between the LC molecular structures and the electro-optical properties of PDLC films is investigated based on an unexplored cyano-terminated tolane compounds (CTTCs) doped E8 LCs/UV polymers system. Due to the high polarity of CTTCs, LCs doped with the cyano-terminated tolane (CTT) molecules exhibit high birefringence and large positive dielectric anisotropy. On the whole, PDLC films doped with the CTT molecules exhibit a lower driving voltage than that doped with the pure E8. More excitingly, PDLC films based on CTT molecules with larger length-to-width ratio and longer conjugated system show higher contrast ratio (CR) and faster response time. Eventually, the mechanism of the effects of CTT-based molecular structures and the relationship between the electro-optical performance of PDLC films and CTT molecules are illustrated. This work paves a new way for optimising the electro-optical properties of PDLC films. 相似文献