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2,7‐Di‐t‐butyldibenzofulvene (tBu2DBF), a bulky dibenzofulvene derivative, was polymerized using n‐butyllithium as initiator in tetrahydrofuran at ?78 °C and in toluene at 0 °C. tBu2DBF afforded mainly oligomers up to trimer even at [monomer]0/[initiator]0 = 20 ([monomer]0 = 0.2 M) at ?78 °C and 0 °C, indicating that this monomer is much less reactive than dibenzofulvene (DBF), its parent compound. The reaction at the same [monomer]0/[initiator]0 ratio at an elevated [monomer]0 gave a small amount of insoluble polymer. The oligomers indicated a hypochromic effect in the absorption spectra and only monomer emission in the fluorescent spectra. The conformation of the trimer and the dimer was examined by means of NOESY NMR spectra and semiempirical calculations. In the trimer conformation, the fluorene moieties of the central and the initiation‐side monomeric units were found to be closely stacked on top of each other, while the termination‐side monomeric unit appeared to be in a faster conformational dynamics compared with the other monomeric units. Although the dimer seemed to have a relatively flexible conformation, a π‐stacked structure appeared to be involved in the conformational dynamics to show hypochromicity. The results of this study suggest that the reported intramolecular excited dimer (excimer) formation of the poly‐ and oligo(DBF)s [J Am Chem Soc 2003, 125, 15474] is based on a slight, local conformational change upon photo absorption, leading to a closer π‐stacked alignment of two neighboring fluorene units than that in the ground state. Such a local conformational transition may be difficult for the tBu2DBF trimer because of steric repulsion of the t‐butyl groups. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 561–572, 2006 相似文献
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Maria Michela Giangregorio Salvatore Gambino Eduardo Fabiano Mauro Leoncini Antonio Cardone Giuseppina Anna Corrente Amerigo Beneduci Gianluca Accorsi Giuseppe Gigli Maria Losurdo Roberto Termine Agostina-Lina Capodilupo 《Molecules (Basel, Switzerland)》2022,27(3)
We have synthetized two classes of dibenzofulvene-arylamino derivatives with an H-shape design, for a total of six different molecules. The molecular structures consist of two D-A-D units connected by a thiophene or bitiophene bridge, using diarylamino substituents as donor groups anchored to the 2,7- (Group A) and 3,6- (Group B) positions of the dibenzofulvene backbone. The donor units and the thiophene or bithiophene bridges were used as chemico-structural tools to modulate electro-optical and morphological-electrical properties. A combination of experiments, such as absorption measurements (UV-Vis spectroscopy), cyclic voltammetry, ellipsometry, Raman, atomic force microscopy, TD-DFT calculation and hole-mobility measurements, were carried out on the synthesized small organic molecules to investigate the differences between the two classes and therefore understand the relevance of the molecular design of the various properties. We found that the anchoring position on dibenzofulvene plays a crucial key for fine-tuning the optical, structural, and morphological properties of molecules. In particular, molecules with substituents in 2,7 positions (Group A) showed a lower structural disorder, a larger molecular planarity, and a lower roughness. 相似文献
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