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Metal Complexes of Biologically Important Ligands. CIII. [1] Palladium(II), Platinum(II), Ruthenium(II), Rhodium(III), and Iridium(III) Complexes of Desoxyfructosazine The reactions of the pyrazine derivative desoxyfructosazin(pz) with K2PtCl4 and with the chlorobridged [M(PR3)Cl2]2 (M = Pd, Pt), [(η5-C5Me5)MCl2]2 and [(η6-p-Cymol)RuCl2]2 give the watersoluble complexes cis-Cl2Pt(pz)2, (R3P)(Cl)M(pz)M(Cl)(PR3) (M = Pd, Pt), (η5-C5Me5)(Cl)2M(pz)M(Cl)2(η5-C5Me5) (M = Rh, Ir), (η6-p-Cymol)(Cl2)Ru(pz)Ru(Cl)2(η6-p-Cymol). 相似文献
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