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Xiang Yin Giuseppe Zuccarello Cristina García-Morales Prof. Dr. Antonio M. Echavarren 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(40):9485-9490
A novel synthesis of indanes and dihydronaphtalenes based on the intramolecular insertion into C(sp3)−H bonds of gold(I) carbenes generated by retro-Buchner reaction (decarbenation) has been developed. Deuterium-labeling and kinetic isotope effect experiments, DFT calculations, and generation of the proposed carbene intermediate from a well-characterized gold(I) carbenoid support the involvement of a three-center concerted mechanism for the C(sp3)−H functionalization process. 相似文献
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