全文获取类型
收费全文 | 628篇 |
免费 | 139篇 |
国内免费 | 42篇 |
专业分类
化学 | 391篇 |
晶体学 | 1篇 |
力学 | 76篇 |
综合类 | 9篇 |
数学 | 88篇 |
物理学 | 244篇 |
出版年
2024年 | 3篇 |
2023年 | 4篇 |
2022年 | 22篇 |
2021年 | 16篇 |
2020年 | 23篇 |
2019年 | 12篇 |
2018年 | 17篇 |
2017年 | 29篇 |
2016年 | 24篇 |
2015年 | 36篇 |
2014年 | 37篇 |
2013年 | 63篇 |
2012年 | 38篇 |
2011年 | 34篇 |
2010年 | 38篇 |
2009年 | 29篇 |
2008年 | 32篇 |
2007年 | 29篇 |
2006年 | 42篇 |
2005年 | 34篇 |
2004年 | 34篇 |
2003年 | 22篇 |
2002年 | 24篇 |
2001年 | 26篇 |
2000年 | 28篇 |
1999年 | 21篇 |
1998年 | 12篇 |
1997年 | 13篇 |
1996年 | 15篇 |
1995年 | 6篇 |
1994年 | 8篇 |
1993年 | 16篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1982年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有809条查询结果,搜索用时 281 毫秒
1.
The chiral phase transition and equation of state are studied within a novel self-consistent mean-field approximation of the two-flavor Nambu-Jona-Lasinio model. In this newly developed model, modifications to the chemical μ and chiral chemical \begin{document}$\mu_5$\end{document} ![]()
![]()
potentials are naturally included by introducing vector and axial-vector channels from Fierz-transformed Lagrangian to the standard Lagrangian. In the proper-time scheme, the chiral phase transition is a crossover in the \begin{document}$T-\mu$\end{document} ![]()
![]()
plane. However, when \begin{document}$\mu_5$\end{document} ![]()
![]()
is incorporated, our study demonstrates that a first order phase transition may emerge. Furthermore, the chiral imbalance will soften the equation of state of quark matter. The mass-radius relationship and tidal deformability of quark stars are calculated. The maximum mass and radius decrease as \begin{document}$\mu_5$\end{document} ![]()
![]()
increases. Our study also indicates that the vector and axial-vector channels exhibit an opposite influence on the equation of state. 相似文献
2.
In a previous paper (Ref. 1), an exact solution of the optimal planar interception with fixed end conditions was derived in closed form. The optimal control was expressed as an explicit function of the state variables and two fixed parameters, obtained by solving a set of nonlinear algebraic equations involving elliptic integrals. In order to facilitate the optimal control implementation, the present paper derives a highly accurate simplified solution assuming that the ratio of the pursuer turning radius to the initial range is small. An asymptotic expansion further reduces the computational workload. Construction of a near-optimal open-loop control, based on the approximations, completes the present paper. 相似文献
3.
根据栅控恒压电晕充电组合反极性电晕补偿充电法的实验结果计算出铁电驻极体的极化强度.结果说明,伴随着薄膜内孔洞气体的Paschen击穿,该铁电体的极化强度随栅压增加而显著上升.利用上述充电方法和热刺激放电(TSD)谱的分析讨论了这类空间电荷型宏观电偶极子,及与其补偿的空间电荷热退极化的电荷动态特性;阐明了这两类俘获电荷的能阱分布,即构成宏观电偶极子的位于孔洞上下介质层内的等值异号空间电荷分别被俘获在深、浅两种能值陷阱内,而位于薄膜表面层的注入空间电荷则被俘获在中等能值陷阱中.
关键词:
反极性电晕补偿充电法
铁电驻极体
充电电流
热刺激放电 相似文献
4.
Takahiro Harada Per B. Zetterlund Bunichiro Yamada 《Journal of polymer science. Part A, Polymer chemistry》2004,42(3):597-607
The unsaturated dimer of methyl acrylate [CH2C(CO2CH3)CH2CH2CO2CH3, or MAD] was copolymerized with various monomers to prepare copolymers bearing the ω-unsaturated end group [CH2C(CO2CH3)CH2 ] arising from β fragmentation of the MAD propagating radical. Copolymerizations of MAD with cyclohexyl and n-butyl acrylate resulted in copolymers with ω-unsaturated end groups, and increasing the temperature up to 180 °C resulted in an increase in the rate of β fragmentation of MAD radicals relative to propagation. Only a small amount of unsaturated end groups was introduced by copolymerization with ethyl methacrylate (EMA), and the EMA content in the copolymer increased with temperature. These findings could be explained by the reversible addition of the poly(EMA) radical to MAD. The copolymerization with ethyl α-ethyl acrylate (EEA) did yield a copolymer containing unsaturated end groups with MAD units as part of the main chain, although the steric hindrance of the ethyl group suppressed homopropagation and crosspropagation of EEA, resulting in low polymerization rates. Therefore, the copolymerization of MAD with acrylic esters at high temperatures was noted as a convenient route for obtaining acrylate–MAD copolymers bearing unsaturated end groups at the ω end (macromonomer). © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 597–607, 2004 相似文献
5.
6.
Marco Sangermano Mehmet Atilla Tasdelen Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4914-4920
Photoinitiated cationic polymerization of mono‐ and bifunctional epoxy monomers, namely cyclohexeneoxide (CHO), 4‐epoxycyclohexylmethyl‐3′,4′‐epoxycyclohexanecarboxylate (EEC), respectively by using sulphonium salts in the presence of hydroxylbutyl vinyl ether (HBVE) was studied. The real‐time FTIR spectroscopic, gel content determination, and thermal characterization studies revealed that both hydroxyl and vinyl ether functionalities of HBVE take part in the polymerization. During the polymerization, HBVE has the ability to react via both active chain end (ACE) and activated monomer mechanisms through its hydroxyl and vinyl ether functionalities, respectively. Thus, more efficient curing was observed with the addition of HBVE into EEC‐containing formulations. It was also demonstrated that HBVE is effective in facilitating the photoinduced crosslinking of monofunctional epoxy monomer, CHO in the absence of a conventional crosslinker. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4914–4920, 2007 相似文献
7.
Jie Xue Liang Chen Li Zhou Zhifeng Jia Yanping Wang Xinyuan Zhu Deyue Yan 《Journal of Polymer Science.Polymer Physics》2006,44(15):2050-2057
α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006 相似文献
8.
Summary In this note we use Theorem 2.4 in<span lang=EN-US style='font-size:10.0pt;mso-ansi-language:EN-US'>[1]to give a very short
proof of a recent result due to M. Bognár (Theorem A in [3]). We also prove that Bognár's result is in fact equivalent to
the classical Hahn-Mazurkiewicz Theorem. Finally we give generalizations in the non-compact setting. 相似文献
9.
A one-dimensional nanodusty plasma was modeled by self-consistently coupling a plasma model with nanoparticle growth, charging,
and transport models. As nanoparticles grow from subnanometer to tens of nm in diameter, the numerical results predict a rich
spatiotemporal structure, including four distinct temporal phases: a charge-limited phase, a charge accumulation phase, an
early ion drag phase, and a sheath interaction phase. 相似文献
10.
Bradley L. Thiel 《Mikrochimica acta》2004,145(1-4):243-247
The role of positive gaseous ions in the formation of secondary electron images in low vacuum scanning electron microscopes is discussed. This paper describes the charging processes and related effects that occur during high vacuum imaging of insulators and then discusses the influence of ions on those processes. The ions are responsible for a number of phenomena, including distortion of the electric field above and below the specimen surface due to space charge, removal of excess negative charge from the specimen, alteration of the specimen surface barrier, and scavenging/filtering of the secondary electron emission. The resulting electron-specimen-ion interactions can give rise to interesting contrast effects that are unique to this class of instruments. 相似文献