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Construction of the side chain of brassrnolide and its related compounds by the aldolreaction of lithofuran with 22-steroidal aldehyde obtained from hyodeoxycholic acid isdescribed. A key intermediate, 22R, 23R-γ-hydroxy-α, β-unsaturated lactone (16) wassynthesized. 相似文献
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油莱甾醇内酯(Brassinolide)(1)是一种高效的植物生长激素,其生理活性与侧链中C_(22)、C_(23)的构型密切相关。当C_(22)、C_(23)为S、S构型时,其活性仅为1的十分之一。在1的 相似文献
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本文报道以3α-羟基-6-羰基-5α-胆烷酸甲酯(3)为原料经六步反应合成了油菜甾醇类似物25,26,27-三失碳-B-高-7-氧-6-酮-5α-胆甾-3α,24-二醇(9a).总产率14%.9a的促进植物生长作用是24-表油菜甾醇内酯的60%. 相似文献
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A highly stereoselective synthesis of the side Chain enantiomers of brassinolide and dolicholide through an aldol reaction of 2-(4-methoxy benzyloxyl) proplonylaldehyde (5) with the anion of 1- ( tert -butyldimethylsiloxy )-3-methyl-2-butanone ( 6 ) is described. 相似文献
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N. A. Borisevich I. V. Skornyakov V. A. Khripach G. B. Tolstorozhev V. N. Zhabinskii 《Journal of Applied Spectroscopy》2007,74(5):673-680
We have analyzed the IR spectra obtained for steroidal phytohormones 24-epibrassinolide, 24-epicastasterone, 28-homobrassinolide,
and 28-homocastasterone. The characteristic frequencies of the stretching vibrations of the hydrocarbon groups CH3, CH2, and CH and also the C=O groups in the spectra of brassinolides are higher than in the spectra of castasterones, which makes
it possible to identify them from the IR spectra. Study of the spectra of these brassinosteroids in different media (pressed
samples in KBr, films, solutions in CHCl3 and CDCl3) allowed us to establish the presence of intermolecular interactions in which C=O and OH groups, OH-OH groups participate,
and also the possible formation of intramolecular hydrogen bonds between the OH groups of the molecules.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 5, pp. 610–616, September–October, 2007. 相似文献
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高效液相色谱法测定22S,23S,24R表高油菜素内酯 总被引:1,自引:0,他引:1
The sample was dissolved in ethyl acetate and reactcd with pbenylboronic acid at 80°for 3Omin.Then itwas detemined by HPLC using UV detector at 222nm. The linear relations between the amounts and thepeak areas in the range of 0. 02mg/mL to 0.12mg/mL were staisfactory(γ=0. 9999,n=6). Average recovery was 99.27%~101.5%. 相似文献
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