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Shu Ping XU* Huan Wen CHEN Ai Min YU Qin Han JIN Hua Ying LIAO Changchun R&D Center for Analytical Instruments Department of Chemistry Jilin University Changchun Key Laboratory for Supramolecular Structure Spectroscopy of Ministr 《中国化学快报》2002,13(7):660-661
In recent years, the determination of Cr (VI) has attracted great attention because of its toxicity to human, plants and animals1-5. Usually, in the industrial waste water, the concentration of Cr (VI) is relatively high and should be determined frequently. So, an accurate, quick, and convenient method for the measurement of Cr (VI) in environmental water, as well as in river, lake, sea and tap water, is of great importance. The method for determination of Cr (VI) by diphenylcarbazine … 相似文献
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A spectro-streak photometer, an instrument for simultaneously measuring fluorescence intensity, time, and wavelength,I(t, ), with a single picosecond excitation pulse, has been constructed. Two typical and currently highly topical examples of mesurements are discussed. (1) the temporal development of the fluorescence form the intramolecular charge-transfer (ICT) state of the rigid aromatic compound 4,5-(1-methylindolino)3,4-naphthanthracene is studied in the protic solvent hexanol. (2) Propyl chain-linked pyrene/N,N-dimethylaniline is used as the model compound to study conformational changes associated with the transition from a contact ion pair to a sandwich exciplex. 相似文献
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Marek Trojanowicz Joanna Szpunar-Łobińska Zdzislaw Michalski 《Mikrochimica acta》1991,103(3-4):159-169
An original computer-controlled solid-state photometer has been developed and its potential for simultaneous multicomponent flow-injection analysis of binary and ternary mixtures is demonstrated. The device is simple in construction. Its principle of operation is based on rapid sequential measurements of the absorbance of the complexes formed by the analytes with chromogenic reagents at the wavelengths corresponding to the emission maxima of three light emitting diodes (563, 580 and 638 nm). 相似文献
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In this work, a downsized flow set up designed based on multicommutation concept for photometric determination of iron(II)/iron(III) and nitrite/nitrate is surface water is described. The flow system network comprised a set of three-way solenoid valves, reaction coil and a double-channel flow cell, which were nested in order to obtain a compact and small-size instrument. To accomplish the downsizing requirement light source (LED) and radiation detection (phototransistor) were coupled to the flow cell. In order to demonstrated the effectiveness of the system, the photometer methods based on Griess reaction and 1-10-phenantroline for nitrite and iron(II) determination, respectively, were selected. Under computer control the set up provided facilities to handle four reagent solutions employing a single pumping channel, thus permitting also the determination of nitrate and iron(III) after its reduction to nitrite and to iron(II), respectively. The overall system performance was demonstrated working several days running standard solution, no significant variation of base line, linear response range and slop (less than 1%) were observed. The usefulness of the downsized system was ascertained by analyzing a set of surface water. Aiming to access the accuracy sample were also analyzed employing reference procedures and no significant difference at 95% confidence level were observed for the four analytes. Other profitable features such as analytical throughput of 40 determination per hour; relative standard deviation of 1%; linear response range between 50 and 300 μg l−1 for nitrite and nitrate, 0.5-6.0 mg l−1 iron(II) and iron(III); low reagent consumption 75 μg for nitrate/nitrite and 0.6 mg for iron(II)/iron(III) per determination; and 2.4 ml waste generation per determination were also achieved. 相似文献
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It has been developed an automatic stop-flow procedure for sequential photometric determination of anionic and cationic surfactants in a same sample of water. The flow system was based on multicommutation process that was designed employing two solenoid micro-pumps and six solenoid pinch valves, which under microcomputer control carry out fluid propelling and reagent solutions handling. A homemade photometer using a photodiode as detector and two light emitting diodes (LEDs) with emission at 470 nm (blue) and 650 nm (red) as radiation sources, which was tailored to allow the determination of anionic and cationic surfactants in waters. The procedure for anionic surfactant determination was based on the substitution reaction of methyl orange (MO) by the anionic surfactant sodium dodecylbenzene sulfonate (DBS) to form an ion-pair with the cetyl pyridine chloride (CPC). Features such as a linear response ranging from 0.35 to 10.5 mg L−1 DBS (R = 0.999), a detection limit of 0.06 mg L−1 DBS and a relative standard deviation of 0.6% (n = 11) were achieved. For cationic surfactant determination, the procedure was based on the ternary complex formation between cationic surfactant, Fe(III) and chromazurol S (CAS) using CPC as reference standard solution. A linear response range between 0.34 and 10.2 mg L−1 CPC (R = 0.999), a detection limit of 0.05 mg L−1 CPC and a relative standard deviation of 0.5% (n = 11) were obtained. In both cases, the sampling throughput was 60 determinations per hour. Reagents consumption of 7.8 μg MO, 8.2 μg CPC, 37.2 μg CAS and 21.6 μg Fe(III) per determination were achieved. Analyzing river water samples and applying t-test between the results found and those obtained using reference procedures for both surfactant types provide no significant differences at 95% confidence level. 相似文献
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提出了一系列的安全、方便、可靠、在线和可连续操作的热解吸/色谱分析柱制备S2OF10纯品、指数稀释法配制S2OF10标准样品、应用定量校正系数测定样品中痕量S2OF10的方法和技术。分别采用气相色谱、红外光谱、气相色谱/质谱等方法对色谱制备的S2OF10纯品进行了纯度分析和测定。配制S2OF10标准气体的体积分数范围为8.0×10-7~2.6×10-4。气相色谱测定S2OF10的定量校正系数为0.197,测定方法的相对误差范围为1.8%~20%。 相似文献
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利用可调谐激光器作为光源,以溯源于低温绝对辐射计的标准传递探测器作为激光束功率测量探测器,采用激光点阵扫描方法在太阳辐射计有效孔径光阑面形成均匀照度场,精确测量太阳辐射计870 nm无偏直射通道中心波长处绝对辐照度响应度。利用灯-单色仪系统扫描获得该通道相对光谱辐照度响应度,最终在实验室条件下获得该通道绝对光谱辐照度响应度,联合大气层外太阳照度谱数据通道内积分得到该通道大气层外响应常数V0值,与NASA的GSFC中心的2009年定标结果差异仅为3.75%,定标不确定度达到2.06%,验证了这一新技术的原理可行性。 相似文献
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