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1.
Jeffrey N Brown 《Analytica chimica acta》2003,486(2):159-169
A new application of reversed-phase octadecyl (C18) solid phase extraction disks has been developed to separate the colloidally-associated polycyclic aromatic hydrocarbons (PAHs) from those that were truly dissolved in the samples of fresh water. A correction for the retention of small amounts of colloidal material on the C18 disks was required, which would have otherwise lead to minor underestimates in the degree of partitioning between the two phases. Using the humic substance Aldrich Humic Acid (AHA) as a model colloid and the 16 PAHs on the US Enrivonmental Protection Agency priority pollutant list, the partitioning coefficients of the PAHs between the colloidal and truly dissolved phases were shown to be proportional to the hydrophobicity of the PAHs, as measured by their octanol water partition coefficients (Kow). The values for the partition coefficients obtained (cKdoc′) were similar to those previously reported in the literature using alternative methods, confirming that the technique was producing acceptable results. The technique allows the in situ partitioning of PAHs between the truly dissolved and colloidal phases in fresh water bodies to be determined. It will provide an invaluable cross-check of the laboratory-based methods which often require substantial manipulation of the sample and potentially alter the partitioning between the phases. 相似文献
2.
The enthalpies and free energies of proton affinity (PA) were calculated by the PM3 method for 27 thiophenoxide anions. For thiophenols, linear correlation has been found between the PAs and the values of pK
a
measured by different authors in aqueous acetone, aqueous ethanol, and methanol media. The dependences found permit one to predict a priori the protolytic properties of thiophenols. The differential effects of aqueous ethanol media with different ethanol contents on thiophenol acidity were evaluated based on quantum-chemical data.Original Russian Text Copyright © 2004 by A. N. Pankratov and A. V. Shalabai__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 800–806, September–October, 2004. 相似文献
3.
Studies on the complexation of copper(II) by phenolic acids, as ligand models of humic substances were done by potentiometry. The acids under study were: 3,4-dihydroxyhydrocinnamic acid or hydrocaffeic acid (1), 3,4-dihydroxyphenylacetic acid (2) and 3,4-dihydroxybenzoic acid or protocatechuic acid (3). Acidity constants of the ligands and the formation constants of metal-ligand complexes were evaluated by computer programs. The carboxylic group of the phenolic acids has different pKa1 values, being the dissociation constants intrinsically related with the distance between the function and the aromatic nucleus. The results obtained allow concluding that acidity constants of the catechol moiety of the compounds are similar with pKa2 and pKa3 values between 9.47-9.41 and 11.55-11.70. The complexation properties of the three ligands towards copper(II) ion are quite similar, being the species found not different either in nature or stability. Although the model ligands have some structural differences no significant differences were found in their complexation properties towards copper(II). So, it can be postulated that complexation process is intrinsically related with the presence of a catechol group. 相似文献
4.
The structural composition of Nordic aquatic reference fulvic acid was investigated using chemical and thermal degradation methods: alkaline CuO oxidation and analytical pyrolysis after tetramethylammonium hydroxide (TMAH) pretreatment. Off-line procedures of the TMAH treatments were carried out under both air and helium atmospheres, with the aim of clarifying the effect of oxygen. Irrespective of the fact that the chemical and thermal degradation methods gave qualitatively quite similar basic products (mainly phenols and phenolic acids together with aromatic and aliphatic carboxylic acids), they also revealed their unique selectivity and efficiency for releasing different kinds of structural constituents. The results verify the formation of additional carboxyl functionality in the CuO oxidation. However, some similar oxidative reactions also appeared to take place during the pretreatment procedures of strongly basic TMAH, especially under an air atmosphere. The use of inert and protective atmosphere during the TMAH pretreatment is therefore recommended for producing more relevant structural information about the complex composition of humic substances. 相似文献
5.
Uyguner CS Hellriegel C Otto W Larive CK 《Analytical and bioanalytical chemistry》2004,378(6):1579-1586
Humic substances are precursors of carcinogenic trihalomethanes (THMs) formed during disinfection by chlorination in water treatment processes. In an effort to understand the relationship between trihalomethane formation potential (THMFP) and physicochemical properties of humic substances, UV-visible absorbance, fluorescence in emission and synchronous scan modes, and NMR spectra were measured for several aquatic fulvic and humic acids. For comparison, a soil fulvic acid was also examined using these methods. The feasibility of the gradient modified spin-echo (GOSE) NMR experiment to selectively measure singlet resonances arising from isolated protons was examined. In addition, diffusion coefficients were measured for DMSO solutions of the fulvic acids using BPPLED and GOSE-edited pulse sequences. Although none of the methods tested produced results that correlated with THMFP, the GOSE intensities determined for different regions of the NMR spectra did reflect the relative abundance of different types of functional groups produced by lignin oxidation. In addition, the GOSE-edited diffusion results suggest that the isolated protons, those most reactive to chlorination, are more likely contained in the larger molecular weight fractions of fulvic acids. 相似文献
6.
Danielle Giron S. Monnier M. Mutz P. Piechon T. Buser F. Stowasser K. Schulze M. Bellus 《Journal of Thermal Analysis and Calorimetry》2007,89(3):729-743
Adequate very sensitive quantification methods are needed for the development and are also now required for the monitoring
of undesirable solid form(s) as routine tests. The pre-requisite for quantitation are selectivity, sensitivity and most important
the purity of standards and their proper storage, what is a challenge for metastable forms.
Several analytical techniques are available such as X-ray diffraction, spectroscopy, thermal analysis and microcalorimetry.
The different steps of the validation of the analytical methods and problems to be solved are discussed. Examples illustrate
the different techniques and compare their possible advantages and limits. The relative standard deviation of measurements
should allow for checking the homogenization procedure of mixtures for calibration. The validation should be carried out following
ICH guidelines for validation of analytical methods. Comparison of different techniques in adequate concentration range add
confidence in the analytical results. 相似文献
7.
The elemental analysis and morphology of individual particles indicate that the dominant suspended particles in river water are kaolin covered with hydrated iron(III) oxide which strongly sorbs humic substances. Suspended particles, about 1 mg, collected from 250 ml of water by centrifugation, are treated with 0.7 ml of 0.1M sodium hydroxide to desorb humic substances. Approximately 60% of copper and 30% of lead on or in suspended particles exist as humic complexes. 相似文献
8.
氧弹燃烧灰化法测定有机物中磷 总被引:1,自引:0,他引:1
用氧弹燃烧法灰化有机物进行元素测定,操作简便,快速,无污染,该方法用于有机物中磷的分析,结果可靠。 相似文献
9.
Summary Different methods for removing interference by humic substances in the analysis of polar pollutants have been compared in
the analysis of environmental water by solid-phase extraction (SPE) with a chemically modified polymeric resin coupled on-line
to liquid chromatography with UV detection.
The methods were based on the use of chemical reagents. The best method was found to be addition of sodium sulphite to humic-containing
water before SPE. The appropriate amount of sulphite depends on the amount of humic substances dissolved in the sample—for
analysis of 50 mL tap and Ebro river water, respectively, 250 μL and 500 μL 10 % Na2SO3 solution had to be added. In both cases, the recovery values after chemical treatment were similar to those when a Milli-Q-quality
water standard was analysed. 相似文献
10.
The effect of ionizing radiation on microbiological decontamination of medical herbs and biologically active compounds 总被引:1,自引:0,他引:1
W. Migdal B. Owczarczyk B. Kedzia E. Holderna-Kedzia E. Segiet-Kujawa 《Radiation Physics and Chemistry》1998,52(1-6):91-94
Several thousand tons of medical herbs are produced annually by pharmaceutical industry in Poland. This product should be of highest quality and microbial purity. Recently, chemical methods of decontamination are recognized as less safe, thus irradiation technique was chosen to replace them in use. In the Institute of Nuclear Chemistry and Technology the national program on the application of irradiation to the decontamination of medical herbs is in progress now. The purpose of the program is to elaborate, on the basis of research work, the facility standards and technological instructions indispensable for the practice of radiation technology. 相似文献