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1.
Pierluigi Contucci Sandro Graffi Stefano Isola 《Journal of statistical physics》2002,106(5-6):895-914
For the long-range deterministic spin models with glassy behaviour of Marinari, Parisi and Ritort we prove weighted factorization properties of the correlation functions which represent the natural generalization of the factorization rules valid for the Curie–Weiss case. 相似文献
2.
M. Brando N. Büttgen V. Fritsch J. Hemberger H. Kaps H.-A. Krug von Nidda M. Nicklas K. Pucher W. Trinkl A. Loidl E.W. Scheidt M. Klemm S. Horn 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(3):289-298
We present susceptibility, microwave resistivity, NMR and heat-capacity results for Li1-xZnx(V1-yTiy)2O4 with 0 ?
x
? 0.3 and 0 ?
y
? 0.3. For all doping levels the susceptibility curves can be fitted with a Curie-Weiss law. The paramagnetic Curie-Weiss temperatures
remain negative with an average value close to that of the pure compound Θ≈ - 36 K. Spin-glass anomalies are observed in the susceptibility, heat-capacity and NMR measurements for both type of dopants.
From the temperature dependence of the spin-lattice relaxation rate we found critical-dynamic behavior in the Zn doped compounds
at the freezing temperatures. For the Ti-doped samples two successive freezing transitions into disordered low-temperature
states can be detected. The temperature dependence of the heat capacity for Zn-doped compounds does not resemble that of canonical
spin glasses and only a small fraction of the total vanadium entropy is frozen at the spin-glass transitions. For pure LiV2O4 the spin-glass transition is completely suppressed. The temperature dependence of the heat capacity for LiV2O4 can be described using a nuclear Schottky contribution and the non-Fermi liquid model, appropriate for a system close to
a spin-glass quantum critical point. Finally an (
x
/
y
,
T
)-phase diagram for the low-doping regime is presented.
Received 16 March 2001 and Received in final form 30 October 2001 相似文献
3.
Thermal behaviour and biochemical activity of potassium-silicate-phosphate glasses modified by addition of Ca, Mg, acting
as ecological fertilisers of controlled release rate of the nutrients for plants were studied. It has been found that the
biochemical activity of silicate-phosphate glasses depends on the nature and the number of components forming the glassy framework
and is related to the thermal stability of glass demonstrated by the formation of new compounds during the process of crystallisation.
It is proved that these seemingly different properties are determined by the same parameters which are the strengths bonds
of glass network-formers and modifiers as well as their chemical affinity.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
4.
Strain hardening of polycarbonate in the glassy state: Influence of temperature and molecular weight
L. E. Govaert T. A. Tervoort 《Journal of polymer science. Part A, Polymer chemistry》2004,42(11):2041-2049
This study is concerned with the temperature and molecular weight dependence of the strain-hardening behavior of polycarbonate. It is shown that the strain-hardening modulus reduces with increasing temperature and decreasing molecular weight. This result is interpreted in terms of temperature accelerated relaxation of the entanglement network. Moreover, it is shown that frozen-in orientations, induced by homogeneous deformations above the glass transition temperature, lead to anisotropic yield behavior that can be fully rationalized (and modelled) in terms of a superimposed stress contribution of the prestrained network. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2041–2049, 2004 相似文献
5.
Y. Oner O. Kamer Joseph H. Ross Jr. 《Journal of magnetism and magnetic materials》2006,300(2):373-381
We report resistivity and magnetization measurements on an amorphous Ni74Mn24Pt2 thin film in the temperature range of 3–300 K. Two significant features are apparent in both the magnetic susceptibility and electrical resistivity. A low-temperature (low-T) anomaly is observed at about 40 K, where a cusp appears in the resistivity, while a concomitant step-like increase in zero-field-cooled (ZFC) magnetization (M) appears with increasing temperature. The low-T anomaly is attributed to a crossover from a pure re-entrant spin-glass within individual domains to a mixed ferro-spin-glass regime at lower temperatures. By contrast, the high-temperature (high-T) anomaly, signaled by the appearance of hysteresis below 250 K, corresponds to the freezing of transverse spins in individual domains acting independently. Between the low-T and high-T anomalies a small but discernable magnetic hysteresis is observed for warming vs. cooling in the field-cooled (FC) case. This behavior clearly indicates the presence of domain structure in the sample, while the disappearance of this hysteresis at lower temperatures indicates the complete freezing of the spin orientation of these domains. According to these results, we have divided the magnetic state of this sample into three regions: at temperatures above 250 K, the sample behaves like a soft ferromagnet, exhibiting M vs. H loops with very small hysteresis (less than 5 Oe). As the temperature is lowered into the intermediate region (the range 40–250 K), spins become frozen randomly and progressively within the individual domains. These domains behave independently, rather than as a cooperative behavior of the sample. Weak irreversibility sets in, indicating the onset of transverse spin freezing within the domains. At temperatures below 40 K, the M vs. H loops exhibit larger hysteresis, for both the ZFC and FC cases, as in a pure spin-glass. We have also demonstrated giant noise in the resistivity at temperatures just below 250 K. Such noise can originate from fluctuations of the domains near the film surface because of competing effective bulk and surface anisotropy fields. The large observed amplitude may be explained by means of a large ferromagnetic anisotropy in the resistivity due to the large spin–orbit effect seen in NiMn systems. Finally, the low-T peak in the resistivity has been analyzed using Fisher and Langer's expression based on the Friedel Model proposed for critical transitions in transition metals (s–d systems). The fitted results are in satisfactory agreement with the predictions of this model. 相似文献
6.
The yet unknown intermetallic phase La5Al3Ni2 was obtained by partially crystallizing amorphous La50Al25Ni25 at 550 K (further heating above 600 K leads to irreversible disappearance of this phase), and its crystal structure was determined from X‐ray powder diffraction data. The crystal structure of the La5Al3Ni2 phase constitutes a new structure type (Cmcm, a = 14.231Å, b = 6.914Å, c = 10.460Å, oC40) and is built from [Al3Ni2] chains surrounded by La atoms. In the ternary system La‐Al‐Ni La5Al3Ni2 is located on the section La50Al50−nNin (0 ≤ n ≤ 50) with the binary compounds LaAl and LaNi as end members. Strikingly, also the crystal structures of the end members can be conceived as chain structures with Al and Ni chains surrounded by La, respectively. 相似文献
7.
J.E. Lorenzo H. Requardt 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(2):185-186
Eur. Phys. J. B 24, 315 (2001) Here we comment on a recently published paper on the presence of a phason contribution in the low temperature heat capacity data of the charge-density-wave compounds K0.3MoO3 and (TaSe4)2I. We have shown that the anomaly in the C
P
/
T
3
data reported by Odin et al. is straightforwardly interpreted in terms of low energy phonon modes resulting from the peculiar topology of these compounds.
Received 21 February 2002 Published online 19 July 2002 相似文献
8.
Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses 下载免费PDF全文
Er3+-doped tellurite glasses with molar compositions of
xNb2O5-(14.7-x)Na2O--10ZnO--5K2O--10GeO2--
60TeO2--0.3Er2O3
(x=0, 3, 5, 7 and 9) have been investigated for developing 1.5~μm
fibre and planar amplifiers. The effects of Nb2O5 on the thermal stability
and optical properties of Er3+-doped tellurite glasses have been discussed.
It is noted that the incorporation of Nb2O5 (x=5) increases the thermal
stability of tellurite glasses significantly. Er3+-doped niobium tellurite
glasses exhibit a large stimulated emission cross-section (7.2\times 10-21-
10.7×10-21~cm2 and the gain bandwidth, FWHM×\sigmae^{\rm peak} (274\times 10-28 - 480×10-28~cm3), which are
significantly higher than that of silicate and phosphate glasses. In addition, the
intensity of upconversion luminescence of the Er3+-doped niobium tellurite
glasses decreases rapidly with increasing Nb2O5 content. As a result,
Er3+-doped niobium tellurite glasses might be a potential candidate for
developing laser or optical amplifier devices. 相似文献
9.
熔制了掺铒碲铌玻璃样品(100-X)TeO2-XNb2O5(X=5,10,15,20mol%),测试了其密度、折射率、转变温度、析晶温度、维氏机械强度、吸收光谱、荧光光谱、荧光寿命等参量。利用Judd-Ofelt和McCumber理论分别计算了铒离子强度参量Ωt(t=2,4,6)和受激发射截面σemi的大小,研究了掺铒碲铌玻璃样品光谱参量对Nb2O5成分的依赖性,并与典型的碲锌钠玻璃(75TeO2-20ZnO-5Na2O)在热学、机械强度、光谱性质和放大品行四个方面进行了比较. 相似文献
10.
Summary Glass formation in nature and materials science is reviewed and the recent recognition of polymorphism within the glassy state,
polyamorphism, is discussed. The process by which the glassy state originates during the continuous cooling or viscous slowdown
process, is examined and the three canonical characteristics of relaxing liquids are correlated through the fragility. The
conversion of strong liquids to fragile liquids by pressure-induced coordination number increases is discussed, and then it
is shown that for the same type of system it is possible to have the same conversion accomplished via a first-order transition
within the liquid state. The systems in which this can happen are of the same type which exhibit polyamorphism, and the whole
phenomenology can be accounted for by a recent simple modification of the van der Waals model for tetrahedrally bonded liquids.
The concept of complex amorphous systems which can lose a significant number of degrees of freedom through weak first-order
transitions is then used to discuss the relation between native and denatured hydrated proteins, since the latter have much
in common with plasticized chain polymer systems. Finally, we close the circle by taking a short-time-scale phenomenon given
much attention by protein physicists,viz., the onset of an anomaly in the Debye-Waller factor with increasing temperature, and showing that for a wide variety of liquids,
including computer-simulated strong and fragile ionic liquids, this phenomenon is closely correlated with the experimental
glass transition temperature. This implies that the latter owes its origin to the onset of strong anharmonicity in certain
components of the vibrational density of states (evidently related to the boson peak) which then permits the system to gain
access to its configurational degrees of freedom. The more anharmonic these vibrational components, the closer to the Kauzmann
temperature will commence the exploration of configuration space and, for a given configurational microstate degeneracy, the
more fragile the liquid will be.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献