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Marie-Joëlle Menu Yves Dartiguenave Michèle Dartiguenave Antoine Baceiredo Guy Bertrand 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):327-334
Abstract Heating of bis[bis(diisopropylamino)phosphanyl]diazomethane 7. in refluxing benzene for 48 hours, quantitatively led to the corresponding 1.2λ3-azaphosphetane 9 as only one diastereoisomer. This result is explained in terms of carbene insertion into a methin-CH bond of an isopropyl substituent. The regiospecificity and the stereospecificity of the ring closure is discussed. Treatment of 9 with elemental sulfur afforded the corresponding 1.2.2λ3-azathiophosphetane 10 which has been characterized b X ray crystallo raphy: C25H56N4P2S2, space group P2(l)/n, a = 13.628 (3) Å, 6 = 19.369 (5) Å, c 112.485 (4) Å, V = 3073 (3) Å3. 相似文献
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