全文获取类型
收费全文 | 4073篇 |
免费 | 119篇 |
国内免费 | 362篇 |
专业分类
化学 | 3300篇 |
晶体学 | 13篇 |
力学 | 174篇 |
综合类 | 7篇 |
数学 | 92篇 |
物理学 | 968篇 |
出版年
2024年 | 12篇 |
2023年 | 171篇 |
2022年 | 106篇 |
2021年 | 121篇 |
2020年 | 134篇 |
2019年 | 94篇 |
2018年 | 84篇 |
2017年 | 104篇 |
2016年 | 108篇 |
2015年 | 131篇 |
2014年 | 166篇 |
2013年 | 234篇 |
2012年 | 196篇 |
2011年 | 278篇 |
2010年 | 238篇 |
2009年 | 320篇 |
2008年 | 249篇 |
2007年 | 299篇 |
2006年 | 240篇 |
2005年 | 233篇 |
2004年 | 200篇 |
2003年 | 112篇 |
2002年 | 84篇 |
2001年 | 68篇 |
2000年 | 74篇 |
1999年 | 46篇 |
1998年 | 70篇 |
1997年 | 81篇 |
1996年 | 60篇 |
1995年 | 31篇 |
1994年 | 27篇 |
1993年 | 24篇 |
1992年 | 17篇 |
1991年 | 14篇 |
1990年 | 18篇 |
1989年 | 17篇 |
1988年 | 10篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 11篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 13篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1974年 | 3篇 |
1973年 | 3篇 |
排序方式: 共有4554条查询结果,搜索用时 0 毫秒
1.
5-Perfluorophenyl 4,5-dihydro-1H-pyrazoles were synthesized from 1,3-dipolar cycloaddition reaction of perfluorobenyl 2,4,6-triisopropylbenzenesulfonylhydrazone and α,β-unsaturated carbonyl compounds or acrylonitrile in THF or water. It was worthy to note that better results were obtained when water was employed as the solvent, which was considered as an effective, economic and environmentally friendly method to synthesize these pyrazole derivatives. 相似文献
2.
Vincent Maurice 《Surface science》2005,581(1):88-104
STM, STS, LEED and XPS data for crystalline θ-Al2O3 and non-crystalline Al2O3 ultra-thin films grown on NiAl(0 0 1) at 1025 K and exposed to water vapour at low pressure (1 × 10−7-1 × 10−5 mbar) and room temperature are reported. Water dissociation is observed at low pressure. This reactivity is assigned to the presence of a high density of coordinatively unsaturated cationic sites at the surface of the oxide film. The hydroxyl/hydroxide groups cannot be directly identify by their XPS binding energy, which is interpreted as resulting from the high BE positions of the oxide anions (O1s signal at 532.5-532.8 eV). However the XPS intensities give evidence of an uptake of oxygen accompanied by an increase of the surface coverage by Al3+ cations, and a decrease of the concentration in metallic Al at the alloy interface. A value of ∼2 for the oxygen to aluminium ions surface concentration ratio indicates the formation of an oxy-hydroxide (AlOxOHy with x + y ∼ 2) hydroxylation product. STM and LEED show the amorphisation and roughening of the oxide film. At P(H2O) = 1 × 10−7 mbar, only the surface of the oxide film is modified, with formation of nodules of ∼2 nm lateral size covering homogeneously the surface. STS shows that essentially the valence band is modified with an increase of the density of states at the band edge. With increasing pressure, hydroxylation is amplified, leading to an increased coverage of the alloy by oxy-hydroxide products and to the formation of larger nodules (∼7 nm) of amorphous oxy-hydroxide. Roughening and loss of the nanostructure indicate a propagation of the reaction that modifies the bulk structure of the oxide film. Amorphisation can be reverted to crystallization by annealing under UHV at 1025 K when the surface of the oxide film has been modified, but not when the bulk structure has been modified. 相似文献
3.
The electron-stimulated desorption (ESD) of D− and H− ions from condensed D2O and H2O films is investigated. Three low-energy peaks are observed in the ESD anion yield, which are identified as arising from excitation of 2B1, 2A1 and 2B2 dissociative electron attachment (DEA) resonances. Additional structure is observed between 18 and 32 eV, which may be due to ion pair formation or to DEA resonances involving the 2a1 orbital. The ion yield resulting from excitation of the 2B1 resonance increases as the film is heated. We attribute the increase in the ion yield to thermally induced hydrogen bond breaking near the surface, which enhances the lifetimes of the excited states that lead to desorption. 相似文献
4.
一次消解测定蔬菜中多种重金属的简捷方法 总被引:1,自引:0,他引:1
针对一般实验室检测人员少,检测任务重的问题,研究了蔬菜通过一次湿化消解后,消解液可以测定多种重金属元素的方法,大大提高了效率,减轻了工作量. 相似文献
5.
P. Macko D. Romanini O.V. Naumenko A. Jenouvrier A. Campargue 《Journal of Molecular Spectroscopy》2004,227(1):90-108
The absorption spectrum of natural water vapour around 1.5 μm has been recorded with a typical sensitivity of 5 × 10−10 cm−1 by using a CW-cavity ring down spectroscopy set up based on fibred DFB lasers. A series of 31 DFB lasers has allowed a full coverage of the 6130.8-6748.5 cm−1 (1.63-1.48 μm) region corresponding to the H transparency band of the atmosphere. The line parameters (wavenumber and intensity) of a total of 5190 lines, including 4247 lines of water vapor, were derived by a one by one fit of the lines to a Voigt profile. Different isotopologues of water (H216O, H218O, H217O, and HD16O) present in natural abundance in the sample contribute to the spectrum. For the main isotopologue, H216O, 2130 lines were measured with line intensities as weak as 10−29 cm/molecule while only 926 lines (including a proportion of 30% inaccurate calculated lines) with a minimum intensity of 3 × 10−27 cm/molecule are provided by the HITRAN and GEISA databases. Our comparison in the whole 5750-7965 cm−1 region, has also evidenced that an error in the process of conversion of the intensity units from cm−2/atm to cm−1/(molecule × cm−2) at 296 K, has led to H216O line intensities values listed in the HITRAN-2000 database, systematically 8 % below the original FTS values. The rovibrational assignment was performed on the basis of the ab initio calculations by Schwenke and Partridge with a subsequent refinement and validation using the Ritz combination principle together with all previously measured water transitions relevant to this study. This procedure allowed determining 172, 139, 71, and 115 new energy levels for the H216O, H218O, H217O, and HD16O isotopologues, respectively. The results are compared with the available databases and discussed in regard of previous investigations by Fourier transform spectroscopy. The spectrum analysis has showed that most of the transitions which cannot be assigned to water are very weak and are due to impurities such as carbon dioxide and ammonia, leaving only about 3% of the observed transitions unassigned. The interest of a detailed knowledge of water absorption for trace detectors developed in the 1.5 μm range is underlined: for instance HDO contributes significantly to the considered spectrum while no HDO line parameters are provided by the HITRAN database. 相似文献
6.
Using the multipoles method, we formulate the problems of radiation (both heave and sway) of water waves by a submerged sphere
in deep as well as in uniform finite depth water with an ice-cover, with the ice-cover being modelled as an elastic plate
of very small thickness. In each case this leads to an infinite system of linear equations which are solved numerically by
standard techniques. The added-mass and damping coefficients for a heaving and swaying sphere are obtained and depicted graphically
against the wave number for various values of the radius of the submerged sphere and flexural rigidity of the ice-cover to
show the effect of the presence of ice-cover on these quantities. When the flexural rigidity is taken to be zero, the numerical
results for the added-mass and damping coefficient for water with a free surface are recovered. 相似文献
7.
This paper examines joint storage considerations when both commodities and resources can be stored, e.g., grain and water for irrigation. Results suggest that when separate agencies control public resource and commodity storage, suboptimal storage rules occur unless (i) each agency is sensitive to the policies of the other, (ii) commodity inventories are adjusted in response to prices, and (iii) resource inventories are adjusted in response to both commodity demand and resource supply conditions. For example, the common case where water storage depends on weather and reservoir conditions alone is not sufficiently general. The results imply that water management agencies that tend to be dominated by engineers and hydrological considerations need to incorporate economic considerations into decision processes. 相似文献
8.
The three-dimensional structure of the calcite (104)-water interface has been determined with surface X-ray scattering. Nine crystal truncation rods (including specular and non-specular rods) were measured providing both vertical and lateral sensitivity to the interfacial structure. The results reveal that calcite is nearly ideally terminated with a single surface hydration layer that includes two inequivalent water molecules having distinct heights of 2.3 ± 0.1 and 3.5 ± 0.2 Å, each with a well-defined lateral registry with respect to the calcite surface. No additional layering of water is observed beyond this surface hydration layer. Small displacements in the outer two calcium carbonate layers were also observed. These results are compared with previous experimental and computational results. 相似文献
9.
Doubly tunable sum frequency generation (SFG) spectra demonstrate that the water molecules at gold/electrolyte interface change their orientation with applied potential. At negative potentials, water molecules in the double layer align with their oxygen atom pointing to the solution. As potential became positive to be close to the potential of zero charge (PZC), the SFG signal decreased, suggesting the OH groups of the water molecule are either in random orientation or parallel to the electrode. As potential became more positive than the PZC, the SFG signal increased again with the oxygen-up orientation as same as in the negative potential region, indicating that water molecules interact with the adsorbed sulfate anions. The peak position of the SFG spectra indicates a relatively disordered state of water molecules at the gold electrode surface, in contrast to the previously observed ice-like structure of water at electrolyte/oxide interfaces. 相似文献
10.