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2.
Al.Th. Kermanidis D.G. Stamatelos G.N. Labeas Sp.G. Pantelakis 《Theoretical and Applied Fracture Mechanics》2006,45(2):148-158
The synergetic effect of corrosion and corrosion induced hydrogen embrittlement damage processes which occur at local scale has been found to result in a dramatic macroscopic tensile ductility loss of the 2024 aluminum alloy. In the present work, the tensile behaviour of corroded 2024 T351 specimens has been estimated on the basis of FE analysis by taking into account the local material properties in the damaged areas. A parametric study is involved to account for the effect of thickness in the results. Calculated tensile properties obtained with the analysis agree well with experimental data. 相似文献
3.
Influence of annealing and chain defects on the melting behaviour of poly(vinylidene fluoride) 总被引:2,自引:0,他引:2
C. Marega 《European Polymer Journal》2003,39(8):1713-1720
The melting behaviour of poly(vinylidene fluoride) (PVDF) was investigated by differential scanning calorimetry (DSC) and small- and wide-angle X-ray scattering in order to study the influence of the chain defects content and of the temperature of annealing on the crystallization and melting behaviour.All the DSC scans show a double endotherm and the analysis of the data suggests that the low temperature endotherm is due to the melting of a population of thin lamellae, whose thickness increases during the annealing, but a high content of chain defects prevents the lamellar thickening and the main effect in this case is the crystallization of thin lamellae from a portion of polymer which did not crystallize during the quenching from the melt. Furthermore, the two melting endotherms, which are observed, can be partially ascribed to a melting-recrystallization process.Furthermore, stepwise isothermal cooling was performed in a differential scanning calorimeter followed by melting scans of fractionated PVDF samples to point out the possible presence of a series of endothermic peaks. 相似文献
4.
Mixed integer programming (MIP) models are extensively usedto aid strategic and tactical decision making in many businesssectors. Solving MIP models is a computationally intensive processand there is a need to develop solution approaches that enablelarger models to be solved within acceptable timeframes. Inthis paper, we describe the implementation of a two-stage parallelbranch and bound (PB & B) algorithm for MIP. In stage 1of the algorithm, a multiple heuristic search is implementedin which a number of alternative search trees are investigatedusing a forest search in the hope of finding a good solutionquickly. In stage 2, the search is reorganized so that the branchesof a chosen tree are investigated in parallel. A new heuristicis introduced, based on a best projection criterion, which evaluatesalternative B & B trees in order to choose one for investigationin stage 2 of the algorithm. The heuristic also serves as away of implementing a quality load balancing scheme for stage2 of the algorithm. The results of experimental investigationsare reported for a range of models taken from the MIPLIB libraryof benchmark problems. 相似文献
5.
Homogeneously prepared tosylcelluloses (TC) with degrees of substitution (DS) of DSTos 0.1–1.8 were used as intermediates for the synthesis of methylaminocelluloses (MAC) by nucleophilic substitution with methylamine. TC with DSTos up to 1.1 were shown to be valuable intermediates for selective synthesis of MAC with DSMA varying from 0.1 to approximately 1. No nucleophilic substitution was observed at higher DSTos. At the chosen reaction conditions (60 °C, 48 h) residual tosyl moieties remained unchanged and little hydrolysis took place. The samples obtained were characterized by means of elemental analysis, FTIR and 13C CP/MAS NMR spectroscopy. 13C CP/MAS NMR spectroscopy was found to be an efficient tool for quantification of DSMA. Furthermore, the swelling behaviour in water was investigated and preliminary tests concerning the bilirubin adsorption capacity of MAC were carried out. 相似文献
6.
在氨性介质中(pH=9.0),钴(Ⅱ)-丁二酮单肟烟酰腙(DMNH)-亚硝酸盐体系可产生灵敏度很高的催化波。从体系的伏安行为可知,吸附于汞电极上的是混配的配盐NH_4[Co(Ⅱ)(DMNH)·(NO_2)_2],在-1.0 V(相对SCE)处,Co(Ⅱ)被还原至Co(0),DMNH被还原成自由基,由于NO_2~-的存在,自由基可参与再生反应而形成催化波。羟氨的存在可使产生催化波的最佳pH值移至8.2.用此体系进行了生物样品中钴的测定,其检出限为1×10~(-10)mol/L。 相似文献
7.
Fe–Al alloys around the concentration of 30 at. % Al present re-entrant spin-glass behaviour at low temperatures. This behaviour is not completely understood and Mössbauer spectroscopy, combined with other experimental techniques, is useful to describe and explain this behaviour. Results show that the Mössbauer spectra coincide with the magnetic behaviour showed in literature and they can be explained as a magnetic cluster system whose magnetic clusters are getting smaller when the temperature is decreasing. When the temperature is reaching to the spin-glass transition at 92 K the spins in the paramagnetic matrix are moving slower and below this transition the spins are completely frozen. 相似文献
8.
M. A. Macrì C. Del Gratta L. Di Donato S. Di Luzio G. L. Romani S. Della Penna A. Pasquarelli 《Il Nuovo Cimento D》1994,16(5):425-432
Summary A preliminary study is here reported on a new potential marker for biomagnetic measurements. The marker consists of superparamagnetic
polymer microspheres which were detected in the presence of external steady magnetic fields by means of an r.f.-SQUID magnetometer.
The particles were prepared in samples differing in the concentration value and immersed in a homogeneous magnetic field of
variable intensity. A simple model was taken into account for the distribution of the microspheres in the samples, so that
the theoretical values were compared to the marker field values measured by the biomagnetic sensor. The overall sensitivity
of the experimental apparatus and the minimum concentration value of the marker were then estimated. 相似文献
9.
一类非经典扩散方程整体解的存在唯一性及长时间行为 总被引:5,自引:0,他引:5
本文讨论非经典扩散方程第一初边值问题整体解的存在唯一性及长时间行为,建立了一系列新的结果,较好地改进许多已有的结论. 相似文献
10.