全文获取类型
收费全文 | 3662篇 |
免费 | 242篇 |
国内免费 | 572篇 |
专业分类
化学 | 1798篇 |
晶体学 | 24篇 |
力学 | 305篇 |
综合类 | 38篇 |
数学 | 778篇 |
物理学 | 1533篇 |
出版年
2024年 | 6篇 |
2023年 | 76篇 |
2022年 | 73篇 |
2021年 | 74篇 |
2020年 | 81篇 |
2019年 | 114篇 |
2018年 | 95篇 |
2017年 | 96篇 |
2016年 | 77篇 |
2015年 | 81篇 |
2014年 | 135篇 |
2013年 | 341篇 |
2012年 | 213篇 |
2011年 | 218篇 |
2010年 | 197篇 |
2009年 | 210篇 |
2008年 | 210篇 |
2007年 | 226篇 |
2006年 | 237篇 |
2005年 | 224篇 |
2004年 | 182篇 |
2003年 | 147篇 |
2002年 | 148篇 |
2001年 | 121篇 |
2000年 | 113篇 |
1999年 | 111篇 |
1998年 | 104篇 |
1997年 | 53篇 |
1996年 | 68篇 |
1995年 | 77篇 |
1994年 | 49篇 |
1993年 | 36篇 |
1992年 | 30篇 |
1991年 | 37篇 |
1990年 | 24篇 |
1989年 | 26篇 |
1988年 | 23篇 |
1987年 | 24篇 |
1986年 | 15篇 |
1985年 | 15篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 12篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1979年 | 8篇 |
1977年 | 4篇 |
1975年 | 5篇 |
1974年 | 6篇 |
1973年 | 10篇 |
排序方式: 共有4476条查询结果,搜索用时 15 毫秒
1.
The behaviors of ferromagnetic transition metals of the first period: Fe, Co and Ni are examined within density functional theory calculations in two dimensional carbon extended networks using model structure LiC6. Around geometry optimized structures, the energy-volume equations of states considering non magnetic and spin polarized configurations established ferromagnetic ground states with magnetizations –reduced with respect to the metals’– of 2 μB for FeC6 and 1 μB for CoC6 while no magnetic solution could be identified for NiC6. In the D6h point group of the P6/mmm space group lm decomposition of the d states results with increasing energy into doublet state E1g with d(x2-y2) and d(xy); singlet state A1g d(z2) and doublet state E2g d(xz) and d(yz) lying on EF and responsible of the onset of magnetic moments. This was mirrored via molecular orbital approach with a construct of Fe embedded between two extended carbon networks thus validating the model structure proposed for TC6 compounds. The 100% polarization in one spin channel allows proposing potential uses in spintronics applications. 相似文献
2.
《Comptes Rendus Mecanique》2019,347(4):318-331
In this essay we explore analogies between macroscopic patterns, which result from a sequence of phase transitions/instabilities starting from a homogeneous state, and similar phenomena in cosmology, where a sequence of phase transitions in the early universe is believed to have separated the fundamental forces from each other, and also shaped the structure and distribution of matter in the universe. We discuss three distinct aspects of this analogy: (i) Defects and topological charges in macroscopic patterns are analogous to spins and charges of quarks and leptons; (ii) Defects in generic 3+1 stripe patterns carry an energy density that accounts for phenomena that are currently attributed to dark matter; (iii) Space-time patterns of interacting nonlinear waves display behaviors reminiscent of quantum phenomena including inflation, entanglement and dark energy. 相似文献
3.
Gas-phase 21Ne nuclear magnetic resonance spectra were measured at the natural abundance of 21Ne isotope for samples consisting of pressurized neon up to 60 bar at room temperature and applying the magnetic field of the strength B0 = 11.7574 T. It showed that the nuclear magnetic resonance frequency is linearly dependent on the density of gaseous neon. The resonance frequency was extrapolated to the zero-density point, and it permitted the determination of the 21Ne nuclear magnetic moment, μ(21Ne) = 0.6617774(10) μN. The present value of μ(21Ne) is not influenced by the bulk magnetic susceptibility of neon and interactions between neon atoms; therefore, it is more precise and reliable than the previous result obtained for μ(21Ne). 相似文献
4.
ZHAO Shan-Rong CHEN Kai-Xian JIANG Hua-Liang WANG Qin-Mi JI Ru-YunShanghai Institute of Materia Medica Chinese Academy of Sciences Shanghai China 《中国化学》1997,15(1):84-89
We have used quantum mechanical method to study the transition states(TSs) of uridine phosphorolysis reaction. Comparing the four different reaction pathways and the five transition states obtained, we conclude that enzymatic uridine phosphorolysis takes place mainly according to acid-catalyzed SN2 mechanism. The proposed reaction pathway is consistent with many experimental results. 相似文献
5.
设计合成了用以检测过渡金属离子的荧光化学敏感器体系,它们是由1,8-萘二酰亚胺为荧光团,多胺衍生物为金属离子受体组成.在室温下对其光物理性质的研究中发现,在没有加入过渡金属离子时,由于体系内存在有效的光诱导电子转移过程使得荧光团的荧光被淬灭.加入过渡金属离子后,金属离子受体中的氮原子和过渡金属离子之间的配位作用阻断了光诱导电子转移过程,体系的荧光增强.不同的金属离子受体表现出了和过渡金属离子不同的配位识别能力,并且通过荧光的变化传递出受体-金属离子作用的信息. 相似文献
6.
气垫导轨在刚体转动惯量测定实验中的应用 总被引:1,自引:0,他引:1
本文介绍了一种测量刚体转动惯量的新方法。即把气垫导轨和刚体转动仪结合起来来测量刚体的转动惯量,使传统的气垫导轨实验和刚体转动惯量测定实验得以更新,提高了实验测量的精度,拓展了实验内容。 相似文献
7.
利用解析和数值方法研究了在具有横向折射率周期性调制的克尔型非线性介质中光学格子孤子的传输,得到了孤子参数的演化方程以及格子孤子的形成和稳定传输的条件.结果表明:当光束的入射角小于某临界角度时,光束可被类似波导形式的路径俘获而稳定传输,该临界角随折射率调制周期、调制深度的增加而增大,且光束越窄临界值越大.此外,线性空间啁啾虽然对光束传输的中心位置没有任何影响,但会导致光束发散从而破坏格子孤子的形成和稳定传输,对此提出了采用特定功率取值来补偿啁啾作用从而形成格子孤子的方案.
关键词:
光孤子
光学格子
光传输
矩方法 相似文献
8.
We present a simplified relativistic configuration interaction method (SRCI), by which all the energy levels and oscillator strengths in each transition array can be calculated. There exist generalized quasi-sum relations for the calculated oscillator strengths in the relevant transition arrays by the SRCI and by an unresolved transition array model (UTA). Based on UTA and the detailed configuration accounting (DCA), with a fully relativistic treatment incorporated with the quantum defect theory, the X-ray absorption spectra for any middle- and high-Z plasmas or composite plasmas can be calculated with much less computational efforts. The gross features of calculated spectra by DCA-UTA are in agreement with the relevant experimental measurements, except some detailed structures in some narrow spectral ranges. Such detailed structures can be calculated by SRCI incorporated with DCA-UTA. As an illustrative example, the absorption spectra of Ge plasmas are calculated by DCA-UTA-SRCI and are in agreement with the experimental opacity data. Therefore, the theoretical method (DCA-UTA-SRCI) verified by experimental measurements will not only be a basic tool to provide “precision” opacity data for the inertial confinement fusion research (ICF) and studies in stellar physics but also can be used to analyze the relevant diagnostic measurements for ICF plasmas. 相似文献
9.
We obtain exponential upper bounds for tails of distributions of generalized L-statistics based on a sample from an exponential distribution. We prove the asymptotic normality of generalized L-statistics based on a sample from the uniform distribution on [0,1] and of L-statistics with decomposed kernels (without any restrictions on the sample distribution type). 相似文献
10.