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排序方式: 共有401条查询结果,搜索用时 15 毫秒
1.
Zhaohui Wang 《Thermochimica Acta》2004,414(1):31-33
Microcalorimetric measurements of excess molar enthalpies, at 298.15 K, are reported for the four binary systems formed by mixing 1-hexene with the cycloalkanes: cyclohexane and methylcyclohexane, and with the aromatic hydrocarcons: benzene and toluene. Smooth Redlich-Kister representations of the results are presented. It was found that the Liebermann-Fried model also provided good representations of the results. 相似文献
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Toluene was methylated with methanol and disproportionated using catalysts containing different Pt contents (0.2, 0.4 and 0.6%) supported on H‐ZSM‐5 or H‐mordenite (H‐M) zeolites in a fixed‐bed flow‐reactor operated atmospherically at temperatures of 300–500 °C in a flow of hydrogen. Platinum dispersion in the zeolite supports and acid sites strength distribution were evaluated using hydrogen chemisorption (1:1 stoichiometry) and ammonia temperature programmed desorption (TPD) in a differential scanning calorimeter (DSC). Toluene methylation was much faster on all catalysts than toluene disproportionation (DISP). Both reactions were more accelerated using H‐ZSM‐5 containing catalysts than H‐M containing catalysts. The yield of xylenes, and in particular para‐xylene, was significantly influenced by the yield of trimethylbenzenes (TMBs) in product. The selectivities for para‐, ortho‐ and meta‐xylenes production were found largely dependent on the Pt content in the catalysts, particularly when supported on H‐ZSM5‐zeolite. However, using Pt/H‐M catalysts, these selectivities were not strictly controlled by Pt content in the catalysts. 相似文献
5.
Yong-liang Zhu Bin Wang Jian Yu Zhao-xia Guo 《高分子科学》2007,(3):291-296
PEG (Polyethylene Glycol)-grafted nano-titania has been obtained in a one-step procedure using hexamethylene diisocyanate as the coupling agent and dibutyltin dilaurate as the catalyst in toluene at 80℃ and characterized qualitatively by FTIR and quantitatively by elemental analysis and thermogravimetric analysis. A comparison of nano-titania with two other commonly used inorganic nanoparticles, nano-silica and nano-alumina, is made, revealing that reactivity order is nano- silica 〉 nano-alumina 〉 nano-titania in view of PEG grafting. Possible mechanism of PEG grafting is also discussed. 相似文献
6.
气相色谱法测定废水中的烷基汞 总被引:4,自引:1,他引:4
以巯基棉(SCF)为吸附剂,用柱上富集技术,浓缩富集水中的烷基汞(氯代甲基汞,氯代乙基汞)。用少量的2mol/LHCl洗脱,用甲苯作萃取剂从洗脱液中萃取烷基汞。对于简单水体,该有机相可直接用于气相色谱测定;对于复杂水体,采用反萃取的方法测定,即可进一步浓缩,又可减少背景峰。用玻璃填充柱-电子捕获检测器响应的气相色谱法测定,最低检测限为8.6×10 ̄(-12)g,可检测到废水中0.34ng/L的单一烷基汞(2.5L水样)。对样品的保存条件也作了探索。 相似文献
7.
Liao Shijie Ying Weiyong Fang Dingye Kameyama Hideo 《Reaction Kinetics and Catalysis Letters》2005,85(1):205-213
Summary Catalytic combustion of toluene, propylene and CO over Pt/Al2O3 /Al catalyst was investigated. Strong inhibition effects are observed when the mixture of toluene, propylene and CO is oxidized. A reaction mechanism of catalytic combustion over Pt/Al2O/Al is proposed. The results from kinetic models are in good agreement with the experimental data. 相似文献
8.
R. F. Storey J. S. Wiggins A. D. Puckett 《Journal of polymer science. Part A, Polymer chemistry》1994,32(12):2345-2363
Bioabsorbable poly(ester-urethane) networks were synthesized from ethyl 2,6-diisocyanatohexanoate (L -lysine diisocyanate) (LDI) and a series of polyester triols. LDI was synthesized by refluxing L-lysine monohydrochloride with ethanol to form the ester, which was subsequently refluxed with 1,1,1,3,3,3-hexamethyldisilazane to yield a silazane-protected intermediate. This product was then phosgenated using triphosgene. Polyester triols were synthesized from D,L-lactide, ?-caprolactone, or comonomer mixtures thereof, using glycerol as initiator and stannous octoate as catalyst. Polyurethane networks were cured using [NCO]/[OH] = 1.05 and stannous octoate (0.05 wt %) for 24 h at room temperature and pressure and 24 h at 50°C and 0.1 mm Hg. LDI-based polyurethane networks were totally amorphous and possessed very low sol contents. Networks based on poly (D,L-lactide) triols were rigid (Tg ∽ 60°C) with ultimate tensile strengths of ~ 40–70 MPa, tensile moduli of ~ 1.2–2.0 GPa, and ultimate elongations of ~ 4–10%. Networks based on ?-caprolactone triols were low-modulus elastomers with tensile strengths and moduli of ~ 1–4 MPa and ~ 3–6 GPa, respectively, and ultimate elongations of ~ 50–300%. Networks based on copolymers displayed physical properties consistent with monomer composition and were tougher than the networks based on the homopolymers. Tensile strengths for the copolymers were ~ 3–25 MPa with ultimate elongations up to 600%. Hydrolytic degradation under simulated physiological conditions showed that D ,L -lactide homopolymer networks were the most resistant to degradation, undergoing virtually no change in mass or physical properties for 60 days. ?-Caprolactone-based networks were resistant to degradation for 40 days, and high-lactide copolymer-based networks suffered substantial losses in physical properties after only 3 days. © 1994 John Wiley & Sons, Inc. 相似文献
9.
《Journal of Saudi Chemical Society》2020,24(9):673-682
A single dielectric barrier discharge (DBD) low-temperature plasma reactor was set up, and toluene was selected as the representative substance for volatile organic compounds (VOCs), to study the reaction products and degradation mechanism of VOCs degradation by low-temperature plasma. Different parameters effect on the concentration of O3 and NOx during the degradation of toluene were studied. The exhaust in the process of toluene degradation was continuously detected and analyzed, and the degradation mechanism of toluene was explored. The results showed that the concentration of O3 increased with the increase of the power density and discharge voltage of the plasma device. However, as the initial concentration of toluene increased, the concentration of O3 basically keep steady. The concentration of NOx in the by-products increased with the discharge voltage, power density, and initial concentration of toluene in the plasma device, and the concentration of NO2 was much higher than the concentration of NO. The degradation process of toluene was detected and analyzed. The results showed that the degradation mechanism of toluene by plasma includes high energy electron bombardment reaction, active radical reaction and ion molecule reaction. Among them, the effect of high-energy electrons on toluene degradation is the largest, followed by the effect of free radicals, in which oxygen radicals participated in the reaction mainly through the formation of C–O bond, CO bond, (CO)–O– bond and –OH radical, while nitrogen radicals participate in the reaction mainly through the formation of C–NH2, (CNH)- bond, CN bond and C–NO2 bond. The results can provide some data supports for the study of low-temperature plasma degradation of VOCs. 相似文献
10.
The main purpose of this paper is to present accurate infrared integrated intensities of liquid toluene, C6H5CH3, at 25 °C. Also presented are the decadic molar absorption coefficients, Em, the real and imaginary dielectric constants, ε′ and ε″, and the real and imaginary molar polarizabilities, ′m and ″m. Integrated intensities were determined as Cj, the area under bands in the spectrum, for all bands between 4800 and 440 cm−1. The contributions from the different bands were separated by fitting the spectrum with classical damped harmonic oscillator bands. The uncertainties in the integrated intensities of most bands are estimated to be 5–10%, with the uncertainties in very weak bands and in shoulders possibly up to 100%. The intensity that should be assigned to the fundamentals is more difficult to estimate due to Fermi resonance with overtone and combination bands, and a best estimate is given. The integrated intensities of the fundamental vibrations and the corresponding transition dipole moments are summarized and are compared with literature values for the gas. 相似文献