全文获取类型
收费全文 | 4046篇 |
免费 | 617篇 |
国内免费 | 633篇 |
专业分类
化学 | 2436篇 |
晶体学 | 81篇 |
力学 | 1071篇 |
综合类 | 24篇 |
数学 | 392篇 |
物理学 | 1292篇 |
出版年
2024年 | 27篇 |
2023年 | 54篇 |
2022年 | 150篇 |
2021年 | 165篇 |
2020年 | 216篇 |
2019年 | 175篇 |
2018年 | 187篇 |
2017年 | 151篇 |
2016年 | 215篇 |
2015年 | 200篇 |
2014年 | 234篇 |
2013年 | 321篇 |
2012年 | 228篇 |
2011年 | 232篇 |
2010年 | 204篇 |
2009年 | 227篇 |
2008年 | 206篇 |
2007年 | 227篇 |
2006年 | 243篇 |
2005年 | 213篇 |
2004年 | 188篇 |
2003年 | 191篇 |
2002年 | 148篇 |
2001年 | 90篇 |
2000年 | 108篇 |
1999年 | 93篇 |
1998年 | 72篇 |
1997年 | 81篇 |
1996年 | 67篇 |
1995年 | 57篇 |
1994年 | 58篇 |
1993年 | 36篇 |
1992年 | 43篇 |
1991年 | 42篇 |
1990年 | 24篇 |
1989年 | 15篇 |
1988年 | 22篇 |
1987年 | 24篇 |
1986年 | 16篇 |
1985年 | 12篇 |
1984年 | 8篇 |
1983年 | 2篇 |
1982年 | 14篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1978年 | 3篇 |
排序方式: 共有5296条查询结果,搜索用时 15 毫秒
1.
Dr. Yulia Y. Enakieva Dr. Anna A. Sinelshchikova Prof. Mikhail S. Grigoriev Prof. Vladimir V. Chernyshev Dr. Konstantin A. Kovalenko Prof. Irina A. Stenina Prof. Andrey B. Yaroslavtsev Prof. Yulia G. Gorbunova Prof. Aslan Y. Tsivadze 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(45):10552-10556
The design of new solid-state proton-conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF ( IPCE-1Ni ), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55×10−3 S cm−1 at 75 °C and 80 % relative humidity). 相似文献
2.
Thomas Marmin Prof. Yves L. Dory 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(27):6707-6711
Cyclohexane and cyclotri-β-alanyl have been used as scaffolds for the design of new C3-symmetric rings incorporating conjugated alkenes and dienes. All three C3-symmetric lactams share the same triangular shape and their crystal system is trigonal. They all belong to the R3 space group, R3m, R3 and R3c, for the increasingly large 12-, 18- and 24-membered rigid rings, respectively. All lactams stack on top of each other, through H-bonds and van der Waals noncovalent interactions, leading to endless supramolecular cylinders and tubes. The largest member of the family leads to tubes, the central pores of which is wide enough to let water in. A common feature of all the lactams is their very large dipole, of around 9 D, according to DFT calculations. Surprisingly, all the resulting cylinders and tubes pack side by side in the crystals, with all the dipoles pointing to the same direction. As a result, all three crystals are anisotropic and appear to be the first members of a new kind of highly polar crystals. 相似文献
3.
Formation of porous polymer morphology by microsyneresis during divinylbenzene polymerization
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Libuše Hanková Ladislav Holub Karel Jeřábek 《Journal of Polymer Science.Polymer Physics》2015,53(11):774-781
This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781 相似文献
4.
5.
A. V. Semykin I. A. Kazarinov E. A. Khomskaya 《Russian Journal of Electrochemistry》2006,42(6):643-648
The hydrogen ionization process is studied experimentally on an industrial sintered nickel oxide electrode in models of sealed nickel-metal hydride batteries. It is shown that the hydrogen ionization rates that are reached during overcharge by high current densities in conditions of forced gas delivery into the electrode pores (up to 40 mA cm?2) exceed the self-discharge rate of a nickel-hydrogen battery by two orders of magnitude. Up to 70% of hydrogen delivered into the compact assembly block undergoes ionization during forced charge of models of sealed nickel-metal hydride batteries with a closed hydrogen cycle. Two independent methods (potentiostatic and manometric) are used to determine the relationship between rates of hydrogen ionization with the degree of the electrode filling with gas and perform estimation of the process intensity at a unit reaction surface. It is established that, in conditions of forced gas delivery, practically all the hydrogen oxidation current is generated at the surface of the nickel oxide electrode beneath thin films of an electrolyte solution at the rate of 4–5 mA cm?2. It is shown that the hydrogen oxidation rate on a nickel oxide electrode filled in part by gas is independent of the electrode potential, probably because of a tangible contribution made by diffusion limitations to the overall hampering of the process. 相似文献
6.
We propose a framework, based on classical mixture theory, to describe the isothermal flow of an incompressible fluid through a deformable inelastic porous solid. The modeling of the behavior of the inelastic solid takes into account changes in the elastic response due to evolution in the microstructure of the material. We apply the model to a compression layer problem. The mathematical problem generated by the model is a free boundary problem. 相似文献
7.
D.W. Mueller JrA.L. Crosbie 《Journal of Quantitative Spectroscopy & Radiative Transfer》2002,74(1):43-68
Three-dimensional radiative transfer in an anisotropic scattering medium exposed to spatially varying, collimated radiation is studied. The generalized reflection function for a semi-infinite medium with a very general scattering phase function is the focus of this investigation. An integral transform is used to reduce the three-dimensional transport equation to a one-dimensional form, and a modified Ambarzumian's method is applied to formulate a nonlinear integral equation for the generalized reflection function. The integration is over both the polar and azimuthal angles; hence, the integral equation is said to be in the double-integral form. The double-integral, reflection function formulation can handle a variety of anisotropic phase functions and does not require an expansion of the phase function in a Legendre polynomial series. Complicated kernel transformations of previous single-integral studies are eliminated. Single and double scattering approximations are developed. Numerical results are presented for a Rayleigh phase function to illustrate the computational characteristics of the method and are compared to results obtained with the single-integral method. Agreement between the two approaches is excellent; however, as the transform variable increases beyond five the number of quadrature points required for the double-integral method to produce accurate solutions significantly increases. A new interpolation scheme produces accurate results when the transform variable is large. 相似文献
8.
9.
A. Bourgeat O. Gipouloux E. Marui‐Paloka 《Mathematical Methods in the Applied Sciences》2004,27(4):381-403
In this paper, we study the global behaviour of an underground waste disposal in order to have an accurate upscaled model suitable for the computations involved in safety assessment processes. We start from a detailed model describing the transport of pollutant leaking from a high number of units. Using the method of homogenization, going to the limit, we obtain first a macroscopic model where the sources are now appearing globally. Then we compute a first‐order matched asymptotic expansion and we give the error estimates for this approximation. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
10.
M. A. Efendiev J. Fuhrmann S. V. Zelik 《Mathematical Methods in the Applied Sciences》2004,27(8):907-930
For the Boussinesq approximation of the equations of coupled heat and fluid flow in a porous medium we show that the corresponding system of partial differential equations possesses a global attractor. We give lower and upper bounds of the Hausdorff dimension of the attractor depending on a physical parameter of the system, namely the Rayleigh number of the flow. Numerical experiments confirm the theoretical findings and raise new questions on the structure of the solutions of the system. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献