A comparative study of injection techniques in high-performance liquid chromatography

Summary The performance of injection valves with both curtain- and single-flow column couplings has been evaluated using reverse-phase octadecylsilane columns and a standard test mixture. The results are compared with those obtained from septum and stopped-flow syringe injections.Stopped-flow valve injection has been examined similarly. Configurations and couplings which give optimum efficiency and reproducibility are recommended.     

Experimental investigation of fully developed falling film flow in the presence of conduction pumps

Conduction pumping is appropriate way for liquid pumping due to its benefits like being noise free and easy controlling. In the present work fully developed falling film flow in the presence of conduction pumps has been experimentally investigated. Two different arrangements were selected and Transformer oil was used. Results indicated that, applying electric field would decrease thickness of falling film in wide range of Re number. The variation of wave's frequency and velocity regarding to Re number is also presented and compared for arrangements. Conduction pumps increased wave's frequency at low Re numbers conversely decreased it at high Re numbers.     

Metal–Organic Framework Membrane Nanopores as Biomimetic Photoresponsive Ion Channels and Photodriven Ion Pumps

Biological ion channels and ion pumps with sub-nanometer sizes modulate ion transport in response to external stimuli. Realizing such functions with sub-nanometer solid-state nanopores has been an important topic with wide practical applications. Herein, we demonstrate a biomimetic photoresponsive ion channel and photodriven ion pump using a porphyrin-based metal–organic framework membrane with pore sizes comparable to hydrated ions. We show that the molecular-size pores enable precise and robust optoelectronic ion transport modulation in a broad range of concentrations, unparalleled with conventional solid-state nanopores. Upon decoration with platinum nanoparticles to form a Schottky barrier photodiode, photovoltage across the membrane is generated with “uphill” ion transport from low concentration to high concentration. These results may spark applications in energy conversion, ion sieving, and artificial photosynthesis.     

光纤中基于双布里渊增益线的受激布里渊散射快光

为了解决受激布里渊散射快光在高吸收区产生损耗的问题,通过分析普通单模光纤中双线泵浦产生的双布里渊增益线特性及在增益峰间实现脉冲的超光速传输理论,利用有限元法数值模拟了双布里渊增益线处受激布里渊散射引起的快光特性。结果表明,当频率分离因子大于0.596时,可以观察到双增益峰;当频率分离因子在1~5.25范围内时,两个泵浦波产生的双增益峰之间可以明显地产生快光;当频率分离因子为1.75时,在双布里渊增益线之间的最大时间提前可达25 ps。当频率分离因子为2.42时,三阶色散所对应的归一化色散长度为无穷大,三阶色散可以得到完全补偿;当频率分离因子大于2.464时,脉冲展宽因子趋近于1,可以实现无畸变传输,但时间提前量小于13.52 ps。本文的研究结论对于在布里渊增益区实现快光具有一定的理论意义,并对设计基于受激布里渊散射快光器件具有理论指导作用。     

Metal–Organic Framework Membrane Nanopores as Biomimetic Photoresponsive Ion Channels and Photodriven Ion Pumps

Biological ion channels and ion pumps with sub‐nanometer sizes modulate ion transport in response to external stimuli. Realizing such functions with sub‐nanometer solid‐state nanopores has been an important topic with wide practical applications. Herein, we demonstrate a biomimetic photoresponsive ion channel and photodriven ion pump using a porphyrin‐based metal–organic framework membrane with pore sizes comparable to hydrated ions. We show that the molecular‐size pores enable precise and robust optoelectronic ion transport modulation in a broad range of concentrations, unparalleled with conventional solid‐state nanopores. Upon decoration with platinum nanoparticles to form a Schottky barrier photodiode, photovoltage across the membrane is generated with “uphill” ion transport from low concentration to high concentration. These results may spark applications in energy conversion, ion sieving, and artificial photosynthesis.     

Performance of a small air-lift pump

Pumping of liquids using two-phase flow has been examined experimentally in small air-lift pumps with 12—19 mm bore plexiglass tubes. An air injection system was devised to create and maintain ‘perfect’ slug flow in the vertical riser tube. An equation has been derived, based on momentum conservation considerations, which correlates well with the measurements obtained. Slip variation, or liuid holdup, between the two phases and the formation of the ‘entrance’ section part of the pump (suction pipe) were taken into consideration. Unlike its predecessors, this equation predicts the reversal in the pump performance curve observed experimentally.     

船舶液压推进的可行性探讨

通过对液压推进系统的能量传递方式，扭矩特性和转速控制的分析，介绍了液压推进的优点，对液压推进的可行性作了初步探讨。     

Head-flow and npsh performance of an axial piston pump working with organic fluids at different temperatures

A modified version of the standard axial piston pump, normally used with fuels, has been tested with organic fluids R11 and R113. Head-flow characteristics, volumetric and global efficiency, and npsh curves, have been determined at different speeds and fluid temperatures and the results compared with those obtained with kerosene. Pump efficiencies remain satisfactory with high density, very low viscosity and high vapour pressure fluids. In the absence of cavitation, pump performance seems to be a function of kinematic viscosity, while the npsh curves appear to be a complex function of density, viscosity and vapour pressure     

Effecfs of Cross-Correlation Between Real Noise in Transient Process of Single-Mode and Imaginary Parts of Colored Pump Laser

A two-dimensional single-mode laser model with cross-correlation between the real and imaginary parts of the colored quadric pump noise is investigated. A novel laser amplitude Langevin equation is obtained, in which the cross-correlation λp between the real and imaginary parts of the pump noise appears. The mean, variance, and skewness of first-passage-time are calculated. It is shown that the mean, variance, and skewness of first-passage-time are strongly affected by λp.     

Prediction of the performance of air-lift pumps

Equations are developed for predicting the performance of air-lift pumps. The form of the equations allows simple expressions to be obtained for conditions at the ‘maximum flow rate condition’