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排序方式: 共有1130条查询结果,搜索用时 15 毫秒
1.
Dong Zheng Fu-Quan Wang Yuan-Guang Li Liang-Hong Guo Jing Cheng 《Analytica chimica acta》2004,508(2):225-231
Optimized combination of chemical agents was selected for sensitive electrochemical detection of dissolved ruthenium tris-(2,2′-bipyridine) (Ru-bipy). The detection was based on the chemical amplification mechanism, in which the anodic current of a redox-active analyte was amplified by a sacrificial electron donor in solution. On indium-doped tin oxide (ITO) electrodes, electrochemical reaction of the analyte was reversible, but that of the electron donor was greatly suppressed. Several transition metal complexes, such as ferrocene and tris-(2,2′-bipyridine) complexes of osmium, iron and ruthenium, were evaluated as model analyte. A correlation between the amplified current and the standard potential of the complex was observed, and Ru-bipy generated the largest current. A variety of organic bases, acids and zwitterions were assessed as potential electron donor. Sodium oxalate was found to produce the largest amplification factor. With Ru-bipy as the model analyte and oxalate as the electron donor, the analyte concentration curve was linear up to 50 μM, with a lower detection limit of approximately 50 nM. Preliminary work was presented in which a Ru-bipy derivative was attached to bovine serum albumin and detected electrochemically. Although the combination of Ru-bipy, oxalate and ITO electrode has been used before for electrochemiluminescent detection of Ru-bipy and oxalate, as well as electrochemical detection of oxalate, its utility in amplified voltammetric detection of Ru-bipy as a potential electrochemical label has not been reported previously. 相似文献
2.
Yu. Satov B. Sharkov H. Haseroth Yu. Smakovski K. Makarov S. Kondrashev V. Roerich A. Stepanov H. Kugler R. Scrivens O. Camut A. Shumshurov A. Balabaev A. Charushin 《Journal of Russian Laser Research》2004,25(3):205-216
Experimental and numerical calculation results devoted to development of an optical system for an ion source based on a repetition rate CO2 laser are described. The laser chain consists of a master oscillator, gas absorber cells, and a four-pass amplifier. The optical system provides smooth laser pulses with variable duration and high spatial quality that ensures efficiency for plasma heating and ion generation. The parameters of the plasma ion component measured in the CERN laboratory are applied for a lead target illumination. 相似文献
3.
介绍了一台10mm口径两级双程离轴放大系统,实现了对5mm×5mm口径光束的激光放大,耦合系统采用高功率LDA紧密侧面直接抽运棒状Nd:YLF方式。分析并实验研究了在不同抽运电流、放大脉冲与放大器LDA抽运时刻的不同延时及不同注入能量条件下,放大系统及光束每次放大时放大特性的规律。实验得到:在放大系统5mm×5mm软光阑处注入1.58mJ能量时,放大系统可输出129.2mJ能量,能量提取效率达到19.5%,满足该系统的设计指标。 相似文献
4.
光参量啁啾脉冲放大(OPCPA)在饱和放大区存在一个增益稳定点,据此设计了一个输出稳定的三级OPCPA系统;第一、二、三级分别选用准相位匹配的周期极化钛氧磷酸钾(PPKTP)晶体、LBO晶体和KDP晶体作为增益介质。饱和放大时,增益随泵浦光强度变化时的增益输出稳定性明显改善,在泵浦光强度抖动低于6%的情况下,各级光参量放大器OPA输出的增益抖动小于1%。前级采用准相位匹配的PPKTP晶体作为增益介质,在远低于破坏阈值的30MW/cm2的泵浦功率密度下,可得到2×105的饱和放大增益和20%的能量转换效率。 相似文献
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The influence of the parameter of amplitude-phase coupling for nonlinear amplification on the phase-frequency characteristics of an injection laser in the regime of pumping current modulation has been investigated theoretically. The parameter is defined as the coefficient of proportionality between changes in the real and imaginary parts of the refractive index during variation of the density of photons in the cavity. The substantial dependence of the coefficient of phase modulation on the parameter of the amplitude-phase coupling for nonlinear amplification at small modulation frequencies is shown. A technique to determine the indicated parameter based on the frequency dependence of the ratio between the coefficients of phase and amplitude modulation is suggested. 相似文献
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Heat transfer in a resist-coated silicon wafer using a bake process is theoretically evaluated by modeling the three-dimensional diffusion process, focusing on the controllability of the lithographic performance of chemically amplified resists. Six models of various ambient conditions are used. The proximity gap between the hotplate and the wafer is found to have a dominant influence on the heat transfer process for the whole system. Because the atmosphere near the wafer acts as a thermal diffusion buffer layer, no temperature gradient occurs in the resist, even when it is subjected to convective heat transfer from the resist surface. Experimental results obtained by X-ray lithography confirm the calculation results. 相似文献
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10.
Hong-jun Liu Wei Zhao Guo-fu Chen Yi-shan Wang Lian-jun Yu Chi Ruan Xue-feng Li 《Optics & Laser Technology》2004,36(4):3482-314
Experimental investigations of a type-I noncollinear phase-matched optical parametric amplification based on lithium triborate, which was pumped by a 5-ns second-harmonic pulses from a Q-switched Nd:YAG, seeded by a cw Ti:sapphire laser at 800 nm, was presented. The experiments generated 2-ns signal output pulses at 800 nm, the maximum signal output pulse energy reached 19 μJ, the corresponding parametric gain was 44 dB. Furthermore, the experiments demonstrate that the 65 nm-FWHM parametric fluorescence gain spectrum could also be observed. A quantitative account of the ultrabroadband parametric fluorescence gain spectrum was given with our theory. The experimental measurements are in agreement with theoretical calculations. 相似文献