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Dr. Xu Chen Kaushalendra Patel Prof. Dr. Ilan Marek 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(3):e202212425
An efficient method for the stereoselective construction of tertiary C−O bonds via a stereoinvertive nucleophilic substitution at the quaternary carbon stereocenter of cyclopropyl carbinol derivatives using water, alcohols and phenols as nucleophiles has been developed. This substitution reaction proceeds under mild conditions and tolerates several functional groups, providing a new access to the stereoselective formation of highly congested tertiary homoallyl alcohols and ethers. 相似文献
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