Sr2RuO4的热电势

Sr2RuO4是第一个无CuO面的层状强关联氧化物超导体.测量了9至260K温度范围内Sr2RuO4的热电势,观测到在此温度范围内其热电势为正值.用两种载流子模型对实验数据进行了拟合,并且与Hall系数的实验结果进行了比较,发现低温下两种载流子对热电势和Hall系数的贡献比较类似,但在高温区空穴对热电势的贡献很大而相应地对Hall系数的贡献不占主要地位. 关键词： Sr2RuO4 热电势     

深紫外无机非线性光学晶体硼铍酸锶及其分子工程学探索方法

阐述了紫外无机非线性光学晶体分子工程学探索方法的基本特点，具体分析深紫外无机非线性光学晶体硼铍酸锶（ＳＢＢＯ）以氟硼铍酸钾（ＫＢＢＦ）为主要参考晶体的分子设计方法，随后根据晶体结构研究、单晶培养、和非线性光学性能测定等实验结果讨论ＳＢＢＯ作为新型深紫外无机晶体的主要优点，即它既具有更短的紫外吸收边（接近１５５ｎｍ）和较大的非线性光学系数（ｄ２２（ＳＢＢＯ）＝０６×ｄ２２（ＢＢＯ）＝１３８ｐｍ／Ｖ），同时晶体无明显层状习性，并肯有良好的化学稳定性和机械性能     

Theoretical STM images of alkaline-earth metal adsorbed Si(1 1 1)3 × 2 surfaces

We have performed total-energy calculations to study theoretical scanning tunneling microscopy (STM) images of the Si(1 1 1)3 × 2 surfaces induced by the adsorption of alkaline-earth metals (AEMs). Previously, in a series of works on Ba/Si(1 1 1) system, we have found that the observed Si(1 1 1)3 × 1-Ba LEED phase indeed has a 3 × 2 periodicity with a Ba coverage of 1/6 ML and the HCC substrate structure. Based on results of the Ba case, we proposed that the HCC structure is also adopted for other AEM atoms, which was confirmed by our recent work. In this paper, we mainly report the STM simulations for different AEM systems to compare with existing experimental data. We discuss the difference in the detailed STM images for different AEM adsorbates. Especially, the difference in filled-state images between Mg and other AEM atoms is attributed to the strong Mg-Si interaction.     

超导氧化物La1.85Sr0.15CuO4/超高分子量聚乙烯复合材料的输运性质

采用热压法获得了具有不同混合比例的超导氧化物La1.85Sr0.15CuO4/超高分子量聚乙烯导电复合材料,并利用x射线衍射、扫描电子显微镜和标准四引线方法对复合材料的结构和低温电输运性质进行测量.实验结果显示,超导氧化物La1.85Sr0.15CuO4颗粒随机分布在聚合物本体中,相互间没有连接构成网络结构.在正常态下,复合材料的电阻-温度变化曲线给出类半导体行为.但对应于超导氧化物La1.85Sr0.15CuO4的超导转变温度Tc处,复合材料的电阻-温度变化曲线出现了极小值.室温下电阻率ρ随外加电场强度E的变化曲线测量结果表明,ρ-E曲线为一线形关系,随着电场强度E增加,电阻率ρ下降.文中对可能存在的导电机制进行分析,结果表明隧道贯穿模型可以很好地解释复合材料的导电机制.另外,外加电场强度E对复合材料的电输运特性有明显的影响.     

Sr1-xLaxTiO3的高温高压合成及XPS研究

 利用高温高压方法合成了有稀土元素La掺杂的钙钛矿氧化物Sr_1-xLa_xTiO₃。XRD测试表明，在x≤0.5时，样品基本为单相，呈立方相；晶胞体积随x的增加而增加，在x=0.4时开始减小。XPS测量发现，样品中存在Ti离子的变价。讨论了Ti离子价态的变化对晶格参数的影响。     

Eu3+掺杂的Sr2CeO4荧光材料的燃烧法合成及其性能研究

以尿素作燃料,Sr,Ce和Eu的硝酸盐作反应物,采用燃烧法得到了稀土Eu3 掺杂的Sr2CeO4前驱体粉末.将前驱体在一定温度下烧结3 h,合成了红色荧光材料.经过对材料进行X射线衍射(XRD)分析,确定了烧结温度在1050～1200℃时,能够得到纯度较高的产品.用扫描电镜(SEM)观察到样品烧结后的形貌为不规则的椭圆形,粒径范围在1～3 μm之间.样品的发射光谱和激发光谱表明,Eu3 在Sr2CeO4基质中有很高的猝灭浓度(10%,摩尔分数),随着Eu3 掺杂浓度的增加,可以使蓝白光调整到红白光,进而到红光.     

Growth and Characterization of Crystal Nd_(0.06)Y_(0.94)Sr_6Sc(BO_3)_6

<正>The crystal of Nd0.06Y0.94Sr6Sc(BO3)6 with the dimensions up to 35 mm × 28 mm × 13 mm was grown by a top-seeded solution growth method from Li6B4O9 flux. The grown crystal was characterized by X-ray powder diffraction. The optical absorption of the crystal shows that it has a strong absorption band at 8070 A, and the absorption coefficient is 2.17cm-1 with a FWHM of 41 A, which can match with the wavelength of the diode-laser (LD) and is suitable for the LD pumping. Based on the Judd-Ofelt theory, the three parameters of line oscillator strength Ω(λ) (λ = 2, 4 and 6) of the Nd3+ion in the crystal were calculated as follows: Ω2= 1.194 × 10-20, Ω4= 4.186 × 10-20 and Ω6 = 3.351 × 10-20cm2, which are relatively larger. The results indicate that the crystal Nd0.06Y0.94Sr6Sc(BO3)6 may be a kind of high-efficient laser material for diode-pumped.     

Cationic complexes of Eu(III) and Sr(II) with diphosphine dioxides in organic extracts

IR spectroscopy was used to study the structure and composition of Eu(III) and Sr(II) complexes formed by cation-exchange extraction of these metals from their aqueous nitrate solutions with dichlorethane solutions of mixtures of chlorinated cobalt(III) dicarbollide (CCD) as a superacid with diphenyldiphosphine dioxides containing a methyl (Me-DPDO), ethyl (Et-DPDO), or polyoxyethylene bridge between two phosphorus atoms of phosphine oxide groups. At molar ratios DPDO/CCD ≤ 1, [Eu(H₂O)_nL₄]³⁺ complexes are formed in organic phases, whereas with an excess of DPDO relative to CCD, Eu(NO₃)L ₄ ²⁺ complexes are formed, where L = Me-or Et-DPDO. Polyoxyethylenediphosphine dioxide forms anhydrous complexes of composition Eu:L = 1:1 and 1:2 with Eu(III) and outer-spheric complexes of composition Sr:L = 1:1 and 1:2 with Sr(II), where the organic ligand molecules envelop the hydrated Sr(H₂O) _n ²⁺ cation. The peculiarities of extraction of the complexes are explained based on data about their composition and structure.     

掺银的Sm0.5Sr0.5CoO3中温固体氧化物燃料电池复合阴极材料的制备与性能研究

采用硝酸盐分解方法在Sm0.5Sr0.5CoO3 (SSC)中掺入少量的银 (Ag), 形成可用于SOFC的多孔阴极材料 (SSC-Agx). 通过X射线衍射测试确定了材料的物相组成; 用SEM观测了中温电解质Ce0.8Sm0.2O1.9表面涂层电极的微结构; 利用电化学极化曲线和阻抗谱研究了这些材料中低温 (500～800 ℃)电化学性能, 确定掺Ag量和烧结温度对阴极电化学性能的影响. 结果表明, SSC在中温区掺20% Ag时具有最佳的电化学性能, 在600 ℃阴极总阻抗是SSC的1/11, 在750 ℃为SSC的1/4, SSC中掺Ag是提高阴极在中温区电化学性能的有效途径.     

REE AND Sr, Nd, Pb ISOTOPIC GEOCHEMISTRY OF HUANGYISHAN BASALT, KUANDIAN, LIAONING, NORTHEAST CHINA

In the light of major element geochemistry, mineral chemistry and REE and isotopic data, the small but apparent isotopic differences between the Cenozoic volcanic rocks east and west of the Tancheng-Lujiang fault are believed to be caused by the mixing and metasomatism of crustal and mantle material in tho mantle source region in response to Pacific plate subduction. The presence of phlogopite and pargasite in mantle xenoliths lends strong support to mantle metasomatism.