全文获取类型
收费全文 | 3906篇 |
免费 | 161篇 |
国内免费 | 193篇 |
专业分类
化学 | 3519篇 |
晶体学 | 5篇 |
力学 | 235篇 |
综合类 | 13篇 |
数学 | 165篇 |
物理学 | 323篇 |
出版年
2024年 | 1篇 |
2023年 | 66篇 |
2022年 | 74篇 |
2021年 | 65篇 |
2020年 | 105篇 |
2019年 | 91篇 |
2018年 | 66篇 |
2017年 | 114篇 |
2016年 | 80篇 |
2015年 | 99篇 |
2014年 | 104篇 |
2013年 | 148篇 |
2012年 | 185篇 |
2011年 | 181篇 |
2010年 | 157篇 |
2009年 | 184篇 |
2008年 | 141篇 |
2007年 | 191篇 |
2006年 | 221篇 |
2005年 | 253篇 |
2004年 | 198篇 |
2003年 | 167篇 |
2002年 | 125篇 |
2001年 | 93篇 |
2000年 | 98篇 |
1999年 | 121篇 |
1998年 | 130篇 |
1997年 | 108篇 |
1996年 | 88篇 |
1995年 | 63篇 |
1994年 | 63篇 |
1993年 | 37篇 |
1992年 | 33篇 |
1991年 | 34篇 |
1990年 | 33篇 |
1989年 | 25篇 |
1988年 | 40篇 |
1987年 | 28篇 |
1986年 | 37篇 |
1985年 | 63篇 |
1984年 | 35篇 |
1983年 | 23篇 |
1982年 | 31篇 |
1981年 | 21篇 |
1980年 | 15篇 |
1979年 | 18篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1971年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有4260条查询结果,搜索用时 15 毫秒
1.
2.
Triazines are widely used in agriculture around the world as selective pre‐ and post‐emergence herbicides for the control of broad leaf and grassy weeds. With high toxicity and persistence, triazines can contaminate the environment and crops, so the development of rapid and sensitive methods for the determination of different triazines is necessary. Capillary electrophoresis comprises a group of techniques used to separate chemical mixtures. Analytical separation is based on different electrophoretic mobilities. This review focuses on the analysis of triazine herbicides with different modes of capillary electrophoresis, including capillary zone electrophoresis, micellar electrokinetic capillary electrophoresis, capillary electrochromatography and nonaqueous capillary electrophoresis. Determinations of triazines in various matrices such as surface water, groundwater, vegetables, soil and grains are emphasized. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
3.
Dr. Jun Zeng Dr. Zhichao Wang Dr. Xin Huang Dr. Sabine S. Eckstein Prof. Dr. Xiaohui Lin Prof. Dr. Hailong Piao Prof. Dr. Cora Weigert Dr. Peiyuan Yin Prof. Dr. Rainer Lehmann Prof. Dr. Guowang Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(21):5427-5432
Mass spectrometry (MS) driven metabolomics is a frequently used tool in various areas of life sciences; however, the analysis of polar metabolites is less commonly included. In general, metabolomic analyses lead to the detection of the total amount of all covered metabolites. This is currently a major limitation with respect to metabolites showing high turnover rates, but no changes in their concentration. Such metabolites and pathways could be crucial metabolic nodes (e.g., potential drug targets in cancer metabolism). A stable-isotope tracing capillary electrophoresis–mass spectrometry (CE-MS) metabolomic approach was developed to cover both polar metabolites and isotopologues in a non-targeted way. An in-house developed software enables high throughput processing of complex multidimensional data. The practicability is demonstrated analyzing [U-13C]-glucose exposed prostate cancer and non-cancer cells. This CE-MS-driven analytical strategy complements polar metabolite profiles through isotopologue labeling patterns, thereby improving not only the metabolomic coverage, but also the understanding of metabolism. 相似文献
4.
Separation of 23 dansylated amino acids by micellar electrokinetic chromatography at low temperature
Summary The baseline separation of 23 dansylated amino acids (including 3 didansylated species) is reported. Lowering of the analysis
temperature and fine control of the surfactant concentration were essential in obtaining this result. Calibration graphs with
good linearity were obtained. 相似文献
5.
毛细管气相色谱法测定中药中有机氯农药残留量 总被引:4,自引:0,他引:4
建立了江西省两种中药中有机氯农药残留量的气相色谱分析方法。样品以丙酮提取,在NaCl存在下,以正已烷进行液—液分配,提取液用H2SO4净化,采用DB—1701毛细管柱,GC—ECD检测有机氯农药残留量。最低检测限为1.0×10-3-5.0×10-3mg/kg,添加回收率为85.7%-115.2%,应用于实际样品中有机氯农药残留量的检测,获得了较为满意结果。 相似文献
6.
A time-dependent model corresponding to an Oldroyd-B viscoelastic fluid is considered, the convective terms being disregarded.
Global existence in time is proved in Banach spaces provided the data are small enough, using the implicit function theorem
and a maximum regularity property for a three fields Stokes problem. A finite element discretization in space is then proposed.
Existence of the numerical solution is proved for small data, so as a priori error estimates, using again an implicit function
theorem.
Supported by the Swiss National Science Foundation. Fellowship PBEL2–114311. 相似文献
7.
8.
B. V. Derjaguin 《Progress in Surface Science》1992,40(1-4):240-251
A review is presented about research on surface forces and surface interactions conducted over the past half-century, with some emphasis on the pioneering contributions of the Department of Surface Phenomena at the Institute of Physical Chemistry of the USSR Academy of Sciences. 相似文献
9.
CLIFFORDMARTINGALESΦ-EQUIVALENCEBETWEENS(f)ANDf¥LONGRULIN;QIANTAO(InstituteofMathematics,AcademiaSinica,Beijing100080,China.)... 相似文献
10.
Henrik Stetkær 《Journal of Functional Analysis》2007,252(1):1-33
We extend results on square integrable representations of a locally compact group to subrepresentations of a representations induced from a character of a closed subgroup. We do so working in the framework of quotient representations of ∗-algebras. 相似文献