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1.
Hong Zheng Wei Yu Hon-bin Zhang Chi-xing Zhou 《高分子科学》2006,(1):1-11
Finite element method is used to simulate the high-speed melt spinning process,based on the equation system proposed by Doufas et al.Calculation predicts a neck-like deformation,as well as the related profiles of velocity,diameter, temperature,chain orientation,and crystallinity in the fiber spinning process.Considering combined effects on the process such as flow-induced crystallization,viscoelasticity,filament cooling,air drag,inertia,surface tension and gravity,the simulated material flow behaviors are consistent with those observed for semi-crystalline polymers under various spinning conditions.The structure change of polymer coils in the necking region described by the evolution of conformation tensor is also investigated.Based on the relaxation mechanism of macromolecules in flow field different types of morphology change of polymer chains before and in the neck are proposed,giving a complete prospect of structure evolution and crystallization of semi-crystalline polymer in the high speed fiber spinning process. 相似文献
2.
In this paper, we succeed in fabricating high-temperature fiber of polysulfonamide/ZnO. Polysulfonamide/ZnO nanocomposite was prepared by in-situ polymerization. Some studies and characterization of Polysulfonamide/ Zinc oxide nanocomposite with ZnO 0.5% have been done. It includes ηr,, Crystal degree and thermal property. Experiment's results showed that, ZnO as filler can improve crystal degree of polysulfonamide fiber. The crystal degree has been bnproved, from lower than 20% up to 27%. ηr of polysulfonamide/ Zinc oxide nanocomposite solution with ZnO 0.5% is 2.03. The maxinum weight loss of the nanocomposite occurred at 453.5 ℃. 相似文献
3.
I give a stationary solution of Einstein's equations representing a rotating cloud of dust. The solution is asymptotically
flat, and has no curvature singularities. However, embedded in the cloud is a rotating surface layer of negative mass which
precisely cancels the mass of the dust cloud. The solution throws light on the van Stockum class of rotating dust solutions,
of which it is a member. 相似文献
4.
Ivchenko N Hughes CE Levitt MH 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,164(2):286-293
Cogwheel phase-cycling schemes are applied to sideband suppression and sideband separation experiments in solid-state NMR. It is shown that cogwheel phase cycles lead to the elimination of most pulse imperfection effects, while using far fewer experimental signal acquisitions than conventional phase-cycling methods. 相似文献
5.
本文对中心带轴匀速旋转圆盘在均布压力作用下的受力及变形问题进行了摄动分析,得到了受载条件为J^2/JH<<1时,圆盘应力及形变的渐近解。其形变渐近解为Whitaker函数形式比较表明,渐近解与Chebyshev数值解有较好的一致性。 相似文献
6.
Species of the genus Cystoseira are particularly hard to discriminate, due to the complexity of their morphology, which can be influenced by their phenological state and ecological parameters. Our study emphasized on the relevance of two kinds of analytical tools, (1) LC/ESI-MSn and (2) 1H HR-MAS NMR, also called in vivo NMR, to identify Cystoseira specimens at the specific level and discuss their taxonomy. For these analyses, samples were collected at several locations in Brittany (France), where Cystoseira baccata, C. foeniculacea, C. humilis, C. nodicaulis and C. tamariscifolia were previously reported. To validate our chemical procedure, the sequence of the ITS2 has been obtained for each species to investigate their phylogenetic relationships at a molecular level. Our study highlighted the consistency of the two physico-chemical methods, compared to “classical” molecular approach, in studying taxonomy within the genus Cystoseira. Especially, LC/ESI-MSn and phylogenetic analyses converged into the discrimination of two taxonomical groups among the 5 species. The occurrence of some specific signals in the 1H HR-MAS NMR spectra and/or some characteristic chemical compounds during LC/ESI-MSn analysis could be regarded as discriminating factors. LC/ESI-MSn and 1H HR-MAS NMR turned out to be two relevant and innovative techniques to discriminate taxonomically this complex genus. 相似文献
7.
This paper deals with the mechanics involved in a spinning wheel of which the pivot is not fixed as usual but is forced to rotate along the circumference of a circle on the horizontal plane. The usual Euler equations are extended so that, in addition to the three well-known rotations (Euler angles), they also include a fourth one related to the rotation of the motor that induces the forced precession. This study aims at offering a first insight in one of the renowned Laithwaite's experiments. The derived theoretical expressions are accompanied by computer simulation. 相似文献
8.
This work is an investigation on the roots of chaotic attitudinal motion in a class of asymmetrical gyrostat satellites. The result shows that for a class of Kelvin type gyrostat satellite, there is an equivalent rigid spinning satellite with the same attitude dynamics. Finding some constants of motion and eliminating the cyclic coordinates, the rotational kinetic energy is changed to a quadratic form and using Jordan canonical form of the associated inertia tensor and transforming the coordinate system, the Hamiltonian has been changed to those of a rigid satellite. The Hamiltonian has been split into integrable and non-integrable parts. Using Deprit canonical transformation and Andoyer variables the integrable part has been reduced to a one-dimensional form. The reduced Hamiltonian shows that the regular dynamics of the satellite can be chaotic, under the influence of gravitational effects. To demonstrate various attitudinal dynamics of the satellite, a second-order Poincaré map is employed. This research shows firstly, that the attitudinal dynamics of Kelvin type gyrostat satellites and rigid satellites follow the same dynamical patterns, secondly, for non-linear analysis of dynamics of gyrostat satellite based on the perturbation methods, there is a preferable form for Hamiltonian of the system in the near-integrable fashion and thirdly the chaotic motion is originated from the gravitational field effects that can be suppressed by increasing the attitudinal energy of the satellite in comparison with the translational energy. 相似文献
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10.
In this paper we study the steady state deflection and reverse snapping phenomenon of a spinning non-flat disk. Both the initial and the deformed shapes of the disk are allowed to have axisymmetrical and unsymmetrical components. For the analysis of a rotating axisymmetrical disk, we conclude that there is no need to include the unsymmetrical assumed modes in the solution because all the unsymmetrical steady state deformations are unstable. In addition, the stability of the axisymmetrical positions will not be affected by the inclusion of the unsymmetrical assumed modes. In the case when the initial shape of the disk contains a dominant axisymmetrical component and a smaller unsymmetrical component, attention is focused on the effect of this unsymmetrical component on the overall deformation and stability of the spinning disk. It is found that the unsymmetrical component with one nodal diameter tends to slightly defer the occurrence of the reverse snapping phenomenon. On the other hand, all other unsymmetrical components with more than one nodal diameter tend to reduce dramatically the reverse snapping speed. Experiment is conducted on a non-flat brass disk containing an axisymmetrical component and an unsymmetrical component with two nodal diameters. The experimental measurement confirms the theoretical prediction. 相似文献