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Summary Reaction of the rare earth chlorides with pyridinium chloride in tetrahydrofuran (THF) under anhydrous conditions gave nearly insoluble precipitates of the composition (pyH)3
RECl6·THF (RE=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Y, Er, Tm, Yb, and Lu). They were characterized by chemical analysis and IR spectroscopy; decompositionin vacuo was studied, yielding the hithero unknown complexes (pyH)3
RECl6 (RE=La, Ce, Pr, Sm, Tb, Ho, Y, Tm, and Lu). 相似文献
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Alex R. Petrov Noa K. Pruß Andrei V. Churakov Konstantin A. Rufanov Jrg Sundermeyer 《无机化学与普通化学杂志》2019,645(9):679-682
A convenient one‐pot synthetic protocol towards THF and DME solvates of lanthanum and other early lanthanide tribromides was developed using the water‐catalyzed reaction of lanthanide(III) oxides with highly reactive Me3SiBr in situ formed from commercially available disilane Si2Me6 and Br2. This practical route allows to obtain the target lanthanum tribromide solvates [LaBr3(thf)4] ( 1a ) and [LaBr3(dme)2]2 ( 1b ) as well as analogous early lanthanide molecular tribromide solvates [NdBr3(thf)4] ( 2a ), [NdBr3(dme)2] ( 2b ), [SmBr3(thf)2] ( 3a ), and [SmBr3(dme)2] ( 3b ) difficult to prepare by other solution‐based procedures. The molecular structure of 1b· 2CH2Cl2 was determined by an XRD study. 相似文献
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LI Yong-guo LIU Hong ZHANG Fang WANG Zheng-tao HU Zhi-bi 《高等学校化学研究》2006,22(4):500-504
IntroductionIncreased levels of cholesterol and triglycerides areknown to be the risk factors for developing coronary ar-tery disease. Lipid lowering agents that inhibit theHMG coenzyme A( HMG-CoA) reductase are nowprominent among the drugs for treating h… 相似文献
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[Tetrakis(acetonitrile)‐dibromo‐nickel(II)]‐di‐acetonitrile was obtained from a solution of nickel(II) dibromide in acetonitrile at 258 K. The crystal structure [monoclinic, P21/n (no.14), a = 1005.5(5), b = 831.3(5) , c = 1131.7(5) pm, β = 106.263(5)°, V = 908.1(8)·106 pm3, Z = 2, R1 for 1580 reflections with I0>2σ(I0): 0.0505] contains sixfold coordinated NiII atoms. Two trans coordinating bromide anions and four equatorial acetonitrile molecules form an elongated octahedron around the central NiII atom. [Ni(CH3CN)4Br2] octahedra are connected via hydrogen bonds to neighboring octahedra as well as to solvate acetonitrile molecules. 相似文献
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N. V. Avramenko E. B. Stukalin M. V. Korobov I. S. Neretin Yu. L. Slovokhotov 《Thermochimica Acta》2001,370(1-2):21-28
Thermodynamic properties of binary systems of C60 with 1,2- and 1,3-dibromobenzenes have been studied by means of differential scanning calorimetry (DSC). Solid solvates with the compositions C603(1,2-C6H4Br2); C602(1,3-C6H4Br2) and C600.6(1,3-C6H4Br2) have been found. The solvates have been characterised by their enthalpies and temperatures of incongruent melting transition and in part by X-ray powder data. It has been shown that positional isomers 1,2- and 1,3- of the substituted benzenes formed two series of “typical” phase diagrams. Solubility behaviour of C60 in positional isomers has been discussed. 相似文献
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Alexandr Jegorov Ladislav Cvak Roman Bednář Jan Čejka Michal Hušák Bohumil Kratochvíl Ivana Císařová 《Structural chemistry》2006,17(1):131-137
Crystal forms of N-[3-(dimethylamino)propyl]-N-(ethylcarbamoyl)-6-allyl-ergoline-8β-carboxamide (cabergoline) originating from various solvents have been examined by X-ray diffraction at 298 or 150 K. Crystal structures of cabergoline anhydrate, (form II, P212121) and solvates (all P212121) with tert-butyl methyl ether (form VIII), cyclohexane (form XV), toluene (form IX), p-xylene (form XVI), and 1,2,4-trimethylbenzene (form XVII) are described. Conformation of cabergoline in these forms was compared with crystal structures of forms I and VII of cabergoline (P21) described in the literature. Despite a high degree of molecular conformational freedom, cabergoline possesses similar conformation in forms I, II, VIII, IX, XV, XVI, and XVII. Molecular conformations, crystal packing and the effect of the solvent on the former two properties are examined. 相似文献
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