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Wen-Wen Zi Zihao Gao Prof. Jun Zhang Bao-Xun Zhao Xian-Shu Cai Prof. Hong-Bin Du Prof. Fei-Jian Chen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(10):3976-3979
Extra-large-pore zeolites for processing large molecules have long been sought after by both the academia and industry. However, the synthesis of these materials, particularly extra-large-pore pure silica zeolites, remains a big challenge. Herein we report the synthesis of a new extra-large-pore silica zeolite, designated NUD-6, by using an easily synthesized aromatic organic cation as structure-directing agent. NUD-6 possesses an intersecting 16×8×8-membered ring pore channel system constructed by four-connected (Q4) and unusual three-connected (Q3) silicon species. The organic cations in NUD-6 can be removed in nitric acid to yield a porous material with high surface area and pore volume. The synthesis of NUD-6 presents a feasible means to prepare extra-large pore silica zeolites by using assembled aromatic organic cations as structure-directing agents. 相似文献
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