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单态铝酸根离子与单态硅酸根离子反应的研究 总被引:1,自引:0,他引:1
研究了碱性条件下单态铝酸根离与单态硅酸根离子的反应。实验结果表明,生成的硅铝酸盐沉淀与溶液中的Al,Si以及OH^-浓义有关。反应过程中存在过饱和现象,反应体系的OH^-浓度反应物Si/Al比影响过饱和时间和过饱和区。 相似文献
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聚酰亚胺/二氧化硅纳米尺度复合材料的研究 总被引:72,自引:0,他引:72
通过正硅酸乙酯(TEOS)在聚酰胺酸(PAA)的N,N’ 二甲基乙酰胺(DMAc),溶液中进行溶胶 凝胶反应,制备出不同二氧化硅含量的聚酰亚胺/二氧化硅(PI/SiO2)复合薄膜材料.二氧化硅含量低于10wt%的样品是透明浅黄色薄膜;二氧化硅含量高于10wt%的样品是不透明棕黄色薄膜.利用红外光谱、扫描电镜、热失重分析、动态力学分析、热膨胀系数测试和应力 应变测试等方法研究了此类材料的结构与性能.结果表明,PI/SiO2纳米复合材料具有较聚酰亚胺更高的热稳定性和更高的模量;线膨胀系数显著降低;拉伸强度和断裂伸长随二氧化硅含量而变化,分别在10wt%和30wt%附近出现最大值 相似文献
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Rb7[SiO4][VO4]: an Ortho‐Silicate‐Vanadate(V) Rb7[SiO4][VO4] has been obtained from a redox reaction between CdO and vanadium metal in the presence of Rb2O and SiO2 at 600 °C in an Ag container as yellow‐greenish transparent single crystals. The crystal structure determination (IPDS data: P21/c, a = 637.6(1) pm, b = 1039.7(1) pm, c = 2076.8(4) pm, β = 93.21(2)°, Z = 4, wR2 = 0.1319) reveals the presence of isolated complex anions, [SiO4]4— and [VO4]3—. 相似文献
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Nancy J. McMillan Russell S. Harmon Frank C. De Lucia Andrzej M. Miziolek 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007,62(12):1528-1536
Laser-induced breakdown spectroscopy (LIBS) provides an alternative chemical analytical technique that obviates the issues of sample preparation and sample destruction common to most laboratory-based analytical methods. This contribution explores the capability of LIBS analysis to identify carbonate and silicate minerals rapidly and accurately. Fifty-two mineral samples (18 carbonates, 9 pyroxenes and pyroxenoids, 6 amphiboles, 8 phyllosilicates, and 11 feldspars) were analyzed by LIBS. Two composite broadband spectra (averages of 10 shots each) were calculated for each sample to produce two databases each containing the composite LIBS spectra for the same 52 mineral samples. By using correlation coefficients resulting from the regression of the intensities of pairs of LIBS spectra, all 52 minerals were correctly identified in the database. If the LIBS spectra of each sample were compared to a database containing the other 51 minerals, 65% were identified as a mineral of similar composition from the same mineral family. The remaining minerals were misidentified for two reasons: 1) the mineral had high concentrations of an element not present in the database; and 2) the mineral was identified as a mineral with similar elemental composition from a different family. For instance, the Ca–Mg carbonate dolomite was misidentified as the Ca–Mg silicate diopside. This pilot study suggests that LIBS has promise in mineral identification and in situ analysis of minerals that record geological processes. 相似文献
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A spectrophotometric flow-injection method for the determination of silicate based on the formation of an ion pair between molybdosilicic acid and Rhodamine B is proposed. It allows silicate to be determined over the concentration range 0.17–2.0 mg 1?1 at a sampling rate of 40 h?1, is reasonably precise and is highly tolerant to ions that commonly occur in waters. It has been applied with satisfactory results to the determination of silicate in various types of water. 相似文献
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《Analytical letters》2012,45(11):1985-1992
Abstract Hollow cathode glow discharge atomic emission spectrometry has been applied to the determination of silicon coupled with a novel gaseous hydride generation technique, involving drying of an aqueous solution of silicate (sample) and mixing with powdered LiAlH4. Sample introduction into the glow discharge chamber was performed via a pinhole at the center of the cathode which was connected to the hydride generator. The detection limit for silicon was 6μg at 288.1 nm and 30 μg at 251.6 nm. 相似文献