Phase transition of polycarbonate in blends with liquid crystal

Phase transition temperatures of polycarbonate film consisting of micron-sized liquid crystalline droplets were investigated using differential scanning calorimetry (DSC) and thermo-optical analysis (TOA) methods. Both a decrease in (T _g ) and (T _m ) of the polycarbonate with an increase of liquid crystal (LC) content in the sample were observed. The decrease ofT _g is related to the plastifying effect of a low molecular weight LC substance remaining soluble in the polycarbonate matrix. A fraction of the liquid crystal contained in the droplets was estimated on the basis of theT _g decrease.     

Synthesis,experimental and in silico studies of N‐fluorenylmethoxycarbonyl‐O‐tert‐butyl‐N‐methyltyrosine,coupled with CSD data: a survey of interactions in the crystal structures of Fmoc–amino acids

Recently, fluorenylmethoxycarbonyl (Fmoc) amino acids (e.g. Fmoc–tyrosine or Fmoc–phenylalanine) have attracted growing interest in biomedical research and industry, with special emphasis directed towards the design and development of novel effective hydrogelators, biomaterials or therapeutics. With this in mind, a systematic knowledge of the structural and supramolecular features in recognition of those properties is essential. This work is the first comprehensive summary of noncovalent interactions combined with a library of supramolecular synthon patterns in all crystal structures of amino acids with the Fmoc moiety reported so far. Moreover, a new Fmoc‐protected amino acid, namely, 2‐{[(9H‐fluoren‐9‐ylmethoxy)carbonyl](methyl)amino}‐3‐{4‐[(2‐hydroxypropan‐2‐yl)oxy]phenyl}propanoic acid or N‐fluorenylmethoxycarbonyl‐O‐tert‐butyl‐N‐methyltyrosine, Fmoc‐N‐Me‐Tyr(t‐Bu)‐OH, C₂₉H₃₁NO₅, was successfully synthesized and the structure of its unsolvated form was determined by single‐crystal X‐ray diffraction. The structural, conformational and energy landscape was investigated in detail by combined experimental and in silico approaches, and further compared to N‐Fmoc‐phenylalanine [Draper et al. (2015). CrystEngComm, 42 , 8047–8057]. Geometries were optimized by the density functional theory (DFT) method either in vacuo or in solutio. The polarizable conductor calculation model was exploited for the evaluation of the hydration effect. Hirshfeld surface analysis revealed that H…H, C…H/H…C and O…H/H…O interactions constitute the major contributions to the total Hirshfeld surface area in all the investigated systems. The molecular electrostatic potentials mapped over the surfaces identified the electrostatic complementarities in the crystal packing. The prediction of weak hydrogen‐bonded patterns via Full Interaction Maps was computed. Supramolecular motifs formed via C—H…O, C—H…π, (fluorenyl)C—H…Cl(I), C—Br…π(fluorenyl) and C—I…π(fluorenyl) interactions are observed. Basic synthons, in combination with the Long‐Range Synthon Aufbau Modules, further supported by energy‐framework calculations, are discussed. Furthermore, the relevance of Fmoc‐based supramolecular hydrogen‐bonding patterns in biocomplexes are emphasized, for the first time.     

基于主成分回归分析和偏最小二乘回归法的樱桃糖度检测的研究

选用烟台大樱桃为研究对象,采用便携式光谱仪对樱桃糖度进行检测,利用极差标准归一化方法和小波滤波,对其可见-近红外光谱数据进行预处理,分别运用主成分回归分析(PCR)法和偏最小二乘回归(PLSR)法建立了樱桃糖度定量分析模型,并对两种模型进行了比较。实验结果表明:在600~1 100nm波段范围内对樱桃糖度进行检测是可行的,并且PLSR模型的性能优于PCR模型。     

供应链系统转变为供需网系统研究

为帮助传统企业顺利转变为供需网企业,提出了供应链系统向供需网系统的转变研究.该研究利用企业节点数据化,通过企业节点的改造及供应链节点与供需网的连接操作达到系统转变的目的.在sc节点数据结构及自身系统功能模块改造的基础上,着重思考了供应链节点连入SDN中的算法思想.通过非线性择优连接方法避免了造成系统易攻击性的枢纽节点的出现.给出了连接算法流程,并以一个示例演示了此连接算法,从中也验证了非线性择优连接的有效性.     

双零色散光子晶体光纤中超连续谱的产生及控制

 通过数值模拟飞秒脉冲在具有双零色散波长的光子晶体光纤中的传输过程,详细分析了超连续谱的产生和控制机制.结果表明：中心波长处于反常色散区的泵浦脉冲在高阶非线性和高阶色散等作用的调制下,将演化为基孤子和正常色散区的两个色散波|该色散波进而经与之相位匹配的基孤子相干加强而使频谱展宽形成超连续谱,同时两个色散波上出现了干涉引起的振荡现象.进一步对比三种结构的光子晶体光纤中超连续谱的特点,定量分析了两色散波对超连续谱的限制作用,阐述了结构参量对超连续谱的影响.基于上述结论,结合对色散波的中心波长与光子晶体光纤的色散曲线、结构参量之间关系的分析,提出了设计光子晶体光纤的结构来控制超连续谱的方法.作为例证,通过优化光子晶体光纤结构理论上实现了频谱分量覆盖可见光区的平坦超连续谱.     

A Point Balance Algorithm for the Spherical Code Problem

The Spherical Code (SC) problem has many important applications in such fields as physics, molecular biology, signal transmission, chemistry, engineering and mathematics. This paper presents a bilevel optimization formulation of the SC problem. Based on this formulation, the concept of balanced spherical code is introduced and a new approach, the Point Balance Algorithm (PBA), is presented to search for a 1-balanced spherical code. Since an optimal solution of the SC problem (an extremal spherical code) must be a 1-balanced spherical code, PBA can be applied easily to search for an extremal spherical code. In addition, given a certain criterion, PBA can generate efficiently an approximate optimal spherical code on a sphere in the n-dimensional space ⁿ. Some implementation issues of PBA are discussed and putative global optimal solutions of the Fekete problem in 3, 4 and 5-dimensional space are also reported. Finally, an open question about the geometry of Fekete points on the unit sphere in the 3-dimensional space is posed.     

谱相关的原理、功能与α截面谱表示

讨论了Gardner原始文献未论述的谱相关的数学起源与物理功能问题.指出谱相关的物理功能为一个广义2倍频与自混频器.讨论了信号谱相关的优势与局限.给出了Gardner原始文献所遗漏的循环频率α截面的谱相关表示.给出了无线电信号谱相关物理功能的计算实例 关键词： 谱相关 可调和 循环平稳过程的自相关 物理功能     

BEPCⅡ超导腔高次模阻抗抑制优化研究

BEPCⅡ500MHz超导腔是BEPCⅡ储存环的关键设备,腔中高次模的分布和阻抗将很大程度上直接影响束流的稳定.因此,研究BEPCⅡ超导腔的高次模分布和高次模吸收器的吸收效果对实现BEPCⅡ指标至关重要.为此,通过改变高次模吸收器的位置、铁氧体吸收材料的长度、厚度以及腔的渐变过渡波导的角度等对BEPCⅡ超导腔高次模阻抗抑制进行了模拟优化研究,从而找到并确定了吸收器对高次模阻抗抑制的最优值.同时,为证实模拟计算结果的正确性,对BEPCⅡ超导模型腔进行了高次模分布和吸收测量,得到了与计算一致的结果.结果表明,经过细致优化腔的高次模吸收器,腔中大部分高次模被深度吸收了,那些具有潜在危险的高次模阻抗值降到了阈值以下,满足BEPCⅡ束流阻抗要求     

Determination of electron density in an atomic plasma by least-squares fit to the Stark profile

The measurement of electron density by a unique, one-parameter least-squares fit to the Stark-broadened hydrogen emission line is presented. The curve-fit approach utilizes approximately 60–80 points, and provides improved precision in the measurement.A comparison of data obtained by measurement of the width at half-height and by least-squares analysis indicates that the half-width method exhibits substantial systematic errors, generally over-estimating electron density by a factor of 2–3.     

Spin-dependent proximity effects in ferromagnetic semiconductor/superconductor structures

Proximity effects in normal metal/insulator/ferromagnetic semiconductor/superconductor (NM/I/FS/SC) and NM/I/SC/FS junctions are studied based on an extended Blonder-Tinkham-Klapwijk (BTK) theory. It is found that the magnitude of the proximity effects depends to a great extent on the mismatches of the effective mass and band between the FS and SC. For NM/I/FS/SC junction, the transition of the tunneling conductance from “0” to “π” state is determined by the mass, magnetic exchange energy in FS and the thickness of FS. For NM/I/SC/FS junctions, the conductance spectrum is spin-dependent, indicating a local coexistence of weak ferromagnetism and s-wave superconductivity.