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Marion Millot Marie Martin‐de‐Lassalle Marylne Chollet‐Krugler Yves Champavier Lengo Mambu Jos‐Albert Chulia Marie‐Aleth Lacaille‐Dubois 《Helvetica chimica acta》2016,99(2):169-173
Two new sesterterpenes, 1 and 2 , have been isolated from the lichen Leprocaulon microscopicum. In addition to classic chromatographic methods, a liquid‐liquid chromatography technique, namely centrifugal partition chromatography (CPC) was applied for the purification of compound 2 . The structures were determined by analyses of mass spectrometry and 1D‐ and 2D‐NMR data. The relative configuration of the isolated compounds was assigned on the basis of 2D‐NOESY experiments. The two compounds possess a rare pentacyclic carbon skeleton typical for lichen metabolism, and quite unusual in the vegetal kingdom. 相似文献
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