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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(25):7297-7300
We report a redox‐neutral formylation of aryl chlorides that proceeds through selective 2‐functionalization of 1,3‐dioxolane through nickel and photoredox catalysis. This scalable benchtop approach provides a distinct advantage over traditional reductive carbonylation in that no carbon monoxide, pressurized gas, or stoichiometric reductant is employed. The mild conditions give unprecedented scope from abundant and complex aryl chloride starting materials. 相似文献
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Masumi Asakawa Peter&#x;R. Ashton Vincenzo Balzani Alberto Credi Christoph Hamers Gunter Mattersteig Marco Montalti Andrew&#x;N. Shipway Neil Spencer J.&#x;Fraser Stoddart Malcolm&#x;S. Tolley Margherita Venturi Andrew&#x;J.&#x;P. White David&#x;J. Williams 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》1998,110(3):357-361
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