界面作用对HDPE/POEg/CaCO_3三元复合材料韧性的影响

通过界面改性,制备了以CaCO3为核,马来酸酐接枝乙烯-辛烯共聚物弹性体(POEg)为壳的高密度聚乙烯(HDPEg)/弹性体(POE)/CaCO3的三元复合材料.由于“核-壳”结构的形成,弹性体和CaCO3表现出协同的增韧作用.同未经表面处理的CaCO3复合材料相比,在相同的CaCO3含量的情况下,表面处理的CaCO3由于与弹性体形成更强的界面粘结,使得三元复合材料的“脆-韧”转变发生在较低的弹性体含量.     

Polymer dispersions from catalytic polymerization in aqueous systems

By contrast to traditional free radical emulsion polymerization, catalytic polymerization allows for polymer microstructure control. In terms of polymerizable monomers, both techniques are largely complementary. Since the beginning of this decade, an increasing number of reports on polyolefin, polybutadiene, polyalkenamer, polynorbornene, polyketone, and polyacetylene dispersions prepared by catalytic polymerization in disperse aqueous systems has appeared. This contribution reviews the preparation of these dispersions, their colloidal properties, particle formation mechanisms, particle morphologies, and polymer microstructures.     

实用化超导材料研究进展与展望

超导技术是21世纪具有重大经济和战略意义的高新技术,在国民经济诸多领域具有广阔的应用前景,如在超导弱电应用中的超导量子干涉器、滤波器;在超导强电应用中的电缆、限流器、电机、储能系统、变压器、磁体技术、医疗核磁共振成像、高能物理实验和高速交通输运等。实用化超导材料是超导技术发展的基础。目前,国际上发现的实用化超导材料主要有低温超导线材、铋系高温超导带材、YBCO涂层导体、MgB₂线带材以及新型铁基超导线带材。文章在简要介绍超导材料发展历程的基础上,重点综述了上述实用化超导材料制备及加工、性能和应用方面的最新研究进展,并对相关领域存在的问题及今后的发展作出展望。     

Fast Analytical Temperature Rising Elution Fractionation (ATREF) Method

Conventional analytical temperature rising elution fractionation (ATREF) is performed using slowly crystallized polymers in about 16 h. In this work, we developed a fast ATREF method in which the polymer sample is directly injected on the column at room temperature, thus reducing the analysis time to about 1 h. The method was tested using four metallocene polyethylenes with unimodal short chain branching distributions and different densities, previously analyzed by ATREF using a cooling rate of 0.1°C/min. The obtained results demonstrate that the fast ATREF method is very effective and accurate in evaluating short chain branching distribution for polyolefins having unimodal distributions.     

Lithium-ion battery separators: Recent developments and state of art

Lithium-ion battery separators are receiving increased consideration from the scientific community. Single-layer and multilayer separators are well-established technologies, and the materials used span from polyolefins to blends and composites of fluorinated polymers. The addition of ceramic nanoparticles and separator coatings improves thermal and mechanical properties, as well as electrolyte uptake and ionic conductivity. The state-of-art separators are actively involved in the cell chemistry through specific functional groups on their surface. Among the numerous properties, safety features and long cycle life are high-priority requirements for next-generation lithium-ion batteries.     

一种新的高温超导磁体电磁结构优化设计方法

本文阐述了用于高温超导磁体电磁结构优化设计的一种新方法,与一般优化方法不同之处在于其不用定义磁体的初始结构形状,采用该方法可以得到满足规格和性能要求的较佳磁体结构.通过此方法优化设计了一个中心磁场为3T的Bi系高温超导磁体,其设计结果与满足同样要求且经过优化的单螺管高温超导磁体的设计结果作了对比,由结果表明该方法具有很好的优化效果.     

X7R型MLCC流延瓷膜显微结构的AFM研究

片式电容是由电介质陶瓷薄膜和内电极相互重叠而成的多层独石结构,又称多层陶瓷电容器(mul-tilayer ceram ic capacitors,简称MLCC)。具有体积小、内部电感低、绝缘电阻高及漏电流小、介质损耗低、价廉等优点,被广泛应用于各种电子整机中的振荡、耦合、滤波和旁路电路,尤其是高     

改进实验仪器测量Bi／Ag线材的超导转变温度

对实验室现有的仪器进行改进并测量了Bi／Ag高温超导线材的Tc，结果为104．1K。     

利用高压热处理技术提高Bi-2223/Ag高温超导带材临界电流

提高临界电流密度(Jc)对促进Bi-2223/Ag高温超导带材的应用有着重要意义.在常压热处理条件下所制备的带材中存在大量的裂纹、孔洞和第二相颗粒等,这些因素都会对带材的超导连接性能产生破坏作用.我们成功建立了一套可用氧气氛的热等静压设备,工作气压和温度可同时达到15MPa和850°C.通过引入裂纹愈合热处理过程,我们成功对带材进行了高压热处理,所得样品中第二相颗粒和裂纹数量大幅度降低,77K、自场下的临界电流相比常压热处理样品提高了20%左右.     

热致相分离法制备聚烯烃微孔膜研究进展

非极性及弱极性的结晶高聚物常温下无合适的良溶剂,所以无法使用传统的非溶剂致相分离法制取微孔膜,而近年来发展的热致相分离法解决了这一问题。研究发现聚乙烯、聚丙烯、乙烯．乙烯醇共聚物、乙烯．丙烯酸共聚物、聚(4-甲基-1-戊烯)等聚烯烃是可采用热致相分离法制备微孔膜的材料。本文综述了近年来在热致相分离法制备聚烯烃微孔膜方面的研究进展,重点介绍各种制膜材料(聚合物、稀释剂、萃取剂和助剂)与各种制膜工艺对制得的聚烯烃微孔膜孔径、膜通量和非对称结构等的影响。