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1.
《Indagationes Mathematicae》2021,32(1):55-85
We show that the differential structure of the orbit space of a proper action of a Lie group on a smooth manifold is weakly reflexive. This implies that the orbit space is a differentiable space in the sense of Smith, which ensures that the orbit space has an exterior algebra of differential forms, that satisfies Smith’s version of de Rham’s theorem. Because the orbit space is a locally closed subcartesian space, it has vector fields and their flows. 相似文献
2.
Liu Xianlong 《数理统计与管理》1998,(6)
本文从理论上讨论了费歇判别与回归模型的等价,指出了利用费歇判别值对企业的综合经济效益进行排序是不合理的,并提出了改进的综合评价方法 相似文献
3.
Simple two-parameter Hückel and Pitzer equations were used for the calculation of the activity coefficients of aqueous hydrochloric acid at 25°C up to a molality of 2.0 mol-kg–1. The data obtained by Harned and Ehlers(12,13) from galvanic cells without liquid junction were used in the analysis and the parameters obtained were compared to those obtained from all reliable data presented in the literature for HCl at this temperature. A good agreement between the parameters was always observed. The activity coefficients obtained by the new equations were compared to those suggested by Robinson and Stokes,(8) Hamer and Wu,(1) and Pitzer and Mayorga,(9) and good agreement was also found. The data from the most important literature data sets for HCl were also predicted using the new activity coefficient equations, and the magnitude of the resulting errors was close to the precision of the measurements, the errors forming an almost random pattern for all data sets. 相似文献
4.
The stoichiometric pK
1
*
and pK
2
*
for the ionization of sulfurous acid has been determined from emf measurements in NaCl solutions with varying concentrations of added MgCl2 (m=0.1, 0.2 and 0.3) from I=0.5 to 6.0 molal at 25°C. These experimental results have been treated using both the ion pairing and Pitzer's specific ion-interaction models. The Pitzer parameters for the interaction of Mg2+ with SO2 and HSO
3
–
yielded =0.085±0.004, (0) = 0.35±0.02, (1) = 1.2±0.04, and C = –0.072±0.007. The Pitzer parameters (0) = –2.8±0.4, (1) = 12.9±2.9 and (2) = –2071±57 have been determined for the interactions of Mg2+ with SO
3
2–
. The calculated values of pK
1
*
and pK
2
*
using Pitzer's equations reproduce the measured values to within ±0.04 pK units. The ion pairing model with log KMgSO3=2.36±0.02 and logMgSO3 = 0.1021, reproduces the experimental values of pK
2
*
to ±0.01. These results demonstrate that treating the data by considering the formation of MgSO3 yields a better fit of the experimental measurements with fewer adjustable parameters. With these derived coefficients obtained from the Pitzer equations and the ion pairing model, it is possible to make reliable estimates of the activity coefficients of HSO
3
–
and SO
3
2–
in seawater, brines and marine aerosols containing Mg2+ ions. 相似文献
5.
合成了新型手性Salen配体(H3L)及新型手性Salen双核锌配合物(主体).通过研究主体对咪唑类客体及氨基酸酯类客体的分子识别行为,测定了这些配位反应的缔合常数.主体对咪唑类客体分子识别的缔合常数顺序为:K(Im) >K(2-MeIm) >K(2-Et-4-MeIm).主体对氨基酸酯类客体分子识别的缔合常数顺序为:K(LeuOCH3) >K(ValOCH3) >K(AlaOCH3) >K(SerOCH3),配位数均为2.主体与D、 L型氨基酸酯分子识别反应在不同温度下的缔合常数结果表明,随着温度的升高,对映选择性下降.实验发现反应体系中存在焓熵补偿关系. CD光谱的研究结果也反映了主体对不同客体识别能力的差异. 相似文献
6.
The ion product of water and the dissociation constants of carbonic acid have been determined in 0.1, 1.0, 3.0, and 5.0M NaClO4 at 25°C. The ion product of water K
w
'
has been evaluated by emf measurements with a combined glass electrode in NaClO4 solutions containing 0.001–0.1M HCLO4 or NaOH. The product K
H
'
K
l
'
K
2
'
of the Henry constant for CO2 and the dissociation constants for H2CO3 have been determined by titration of carbonate solutions equilibrated with pCO2 =10–3.52 atm, and K
2
'
has been evaluated by potentiometric titration and by measuring the H+ concentration at fixed HCO
3
–
and CO
3
2-
concentrations. The ion interaction (Pitzer) equations are applied to describe the constants K
w
'
, K
2
'
and K
H
'
H
1
'
K
2
'
as a function of the NaClO4 concentration. The experimental data are used to evaluate the mixing parameters
i/ClO
4 and
i/ClO
4
-/Na+ fori = OH
-,HCO
3
-
andCO
3
2- 相似文献
7.
Electromotive force measurements were carried out on the system KCl–KNO3–H2O at constant total ionic strengths of 0.5, 1.0, 2.0 and 3.0 mol-kg–1 and at 25, 35 and 45°C using a cell consisting of a potassium ionselective electrode and a Ag/AgCl electrode. The Harned coefficients and the Pitzer binary and ternary interaction parameters for the system have been evaluated at each temperature. The osmotic coefficients, excess free energies of mixing and heats of mixing of the system have been predicted at each of the experimental temperatures and ionic strengths. The solubility data at 25°C are also interpreted. 相似文献
8.
The stoichiometric solubility constant of eitelite (NaMg
0.5
CO
3
+2H+ ⇄ Na++0.5Mg
2+
+CO
2
(g)+H
2
O, log*K
pso
I
=14.67±0.03 was determined at I=3 m (mol kg−1) (NaClO
4
) and 25°C. The stability of magnesium (hydrogen-)carbonato complexes in this ionic medium was explicitely taken into account.
Consequently, trace activity coefficients of free ionic species, calculated from the Pitzer model with ion-interaction parameters
from the literature, were sufficient for an evaluation of the thermodynamic solubility constants and Gibbs energies of formation
for eitelite (−1039.88±0.60), magnesite (−1033.60±0.40), hydromagnesite (−1174.30±0.50), nesquehonite (−1724.67±0.40), and
brucite (−835.90±0.80 kJ-mol
−1
). The increasing solubilities of nesquehonite and eitelite at higher sodium carbonate molalities were explained by invoking
a magnesium dicarbonato complex (Mg2++2CO
3
2−
⇄ Mg(CO3)
2
2−
, log βz = 3.90 ± 0.08). A set of ion-interaction parameters was obtained from solubility and dissociation constants for carbonic
acid in 1 to 3.5 m NaClO
4
media
which reproduce these constants to 0.02 units in log K. The following Pitzer parameters are consistent with the previously
studied formation of magnesium (hydrogen-)carbonato complexes in 3m NaClO
4
. The model and Gibbs functions of solid phases derived here reproduce original solubility data (−log [H+], [Mg
2+
]
tot
) measured in perchlorate medium within experimental uncertainty.
Presented at the XXII International Conference on Solution Chemistry, July 14–19, 1991, Linz, Austria. 相似文献
9.
Boris Pejin Kristina Tešanović Dragica Jakovljević Sonja Kaišarević Filip Šibul Milena Rašeta 《Natural product research》2019,33(5):750-754
The polysaccharide (PSH) extracts from the edible mushroom species Coprinus comatus and Coprinellus truncorum were screened in liquid for their acetylcholinesterase inhibitory (AChE) activity. Both extracts were found to display inhibition of the aforementioned enzyme reaching similar IC50 values of 0.62 ± 0.07 and 0.61 ± 0.03 mg/mL, respectively. According to the means of FTIR spectroscopy, these PSH extracts mostly contained β-glucans. However, the presence of some proteins and polyphenolics as minor ingredients were also detected. Compared with existing literature data for anti-AChE activity of the sugar samples, the findings within this study may be treated as a profound bioactivity. Consequently, this study puts some light on the possible use of the screened macrofungi in the palliative treatment of Alzheimer’s disease. 相似文献
10.