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排序方式: 共有61条查询结果,搜索用时 15 毫秒
1.
Facile fabrication of fast recyclable and multiple self‐healing epoxy materials through diels‐alder adduct cross‐linker
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Xiao Kuang Guoming Liu Xia Dong Xianggui Liu Jianjun Xu Dujin Wang 《Journal of polymer science. Part A, Polymer chemistry》2015,53(18):2094-2103
A reversibly cross‐linked epoxy resin with efficient reprocessing and intrinsic self‐healing was prepared from a diamine Diels‐Alder (DA) adduct cross‐linker and a commercial epoxy oligomer. The newly synthesized diamine cross‐linker, comprising a DA adduct of furan and maleimide moieties, can cure epoxy monomer/oligomer with thermal reversibility. The reversible transition between cross‐linked state and linear architecture endows the cured epoxy with rapid recyclability and repeated healability. The reversibly cross‐linked epoxy fundamentally behaves as typical thermosets at ambient conditions yet can be fast reprocessed at elevated temperature like thermoplastics. As a potential reversible adhesive, the epoxy polymer with adhesive strength values about 3 MPa showed full recovery after repeated fracture‐thermal healing processes. The methodology explored in this contribution provides new insights in modification of conventional engineering plastics as functional materials. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2094–2103 相似文献
2.
K. Madhavan B. S. R. Reddy 《Journal of polymer science. Part A, Polymer chemistry》2006,44(9):2980-2989
A series of poly(dimethylsiloxane‐urethane) elastomers based on hexamethylenediisocyanate, toluenediisocyanate, or 4,4′‐methylenediphenyldiisocyanate hard segment and polydimethylsiloxane (PDMS) soft segment were synthesized. In this study, a new type of soft‐segmented PDMS crosslinker was synthesized by hydrosilylation reaction of 2‐allyloxyethanol with polyhydromethylsiloxane, using Karstedt's catalyst. The synthesized soft‐segmented crosslinker was characterized by FT‐IR, 1H, and 13C NMR spectroscopic techniques. The mechanical and thermal properties of elastomers were characterized using tensile testing, thermogravimetric analysis, differential scanning calorimetry (DSC), and dynamical mechanical analysis measurements. The molecular structure of poly(dimethylsiloxane‐urethane) membranes was characterized by ATR‐FTIR spectroscopic techniques. Infrared spectra indicated the formation of urethane/urea aggregates and hydrogen bonding between the hard and soft domains. Better mechanical and thermal properties of the elastomers were observed. The restriction of chain mobility has been shown by the formation of hydrogen bonding in the soft and hard segment domains, resulting in the increase in the glass‐transition temperature of soft segments. DSC analysis indicates the phase separation of the hard and soft domains. The storage modulus (E′) of the elastomers was increasing with increase in the number of urethane connections between the hard and soft segments. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2980–2989, 2006 相似文献
3.
Katsuhisa Mizoguchi Mitsuru Ueda 《Journal of polymer science. Part A, Polymer chemistry》2008,46(15):4949-4958
A negative‐type photosensitive poly(phenylene ether) (PSPPE) based on poly(2,6‐dimethyl‐1,4‐phenylene ether) (PPE), a novel crosslinker 4,4′‐methylene‐bis [2,6‐bis(methoxymethyl)phenol] (MBMP) having good compatibility with PPE, and diphenylidonium 9,10‐dimethoxy anthracene‐2‐sulfonate (DIAS) as a photoacid generator (PAG) has been developed. This resist consisting of PPE (73 wt %), MBMP (20 wt %) and DIAS (7 wt %) showed a high sensitivity (D0.5) of 58 mJ/cm2 and a contrast (γ0.5) of 9.5 when it was exposed to i‐line (365 nm wavelength light), postexposure baked at 145 °C for 10 min, and developed with toluene at 25 °C. A fine negative image featuring 6 μm line‐and‐space pattern was obtained on the film exposed to 300 mJ/cm2 of i‐line by a contact‐printed mode. The resulting polymer film cured at 300 °C for 1 h under nitrogen had a low dielectric constant (ε = 2.46) comparable to that of PPE and a higher Tg than that of PPE. In addition, the cured PSPPE film was pretty low water absorption (<0.05%) as same as PPE. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4949–4958, 2008 相似文献
4.
多醛基海藻酸钠交联剂的制备及性能 总被引:1,自引:0,他引:1
采用水/乙醇为反应溶剂,用高碘酸钠氧化海藻酸钠,制备了多醛基海藻酸钠(multi-aldehyde sodium alginate,MASA)。采用费林试剂、盐酸羟胺-NaOH电位滴定法、乌氏粘度计、与明胶的交联反应分别对氧化后的海藻酸钠进行表征。结果发现,氧化的海藻酸钠溶液可与费林试剂反应生成砖红色沉淀;海藻酸钠的氧化度随高碘酸钠用量及反应时间的增加而增加。投料比为80%时,氧化度最高可达约80%,收率约58.7%。MASA的粘度随反应时间、高碘酸钠浓度的增加而急剧下降。氧化度分别为20%、40%、60%的MASA,37℃下可使明胶在5min内生成凝胶。因此,水/乙醇作为反应介质、通过控制氧化剂的用量和反应时间,可以得到产率较高、分子量及氧化度可控的多醛基海藻酸钠多糖交联剂。 相似文献
5.
Chisato Katahira Nobuya Morishita Jun‐Ichi Ikeda Pang Boey Lim Mitsuteru Inoue Yuri Iwasaki Hiroyuki Aota Akira Matsumoto 《Journal of polymer science. Part A, Polymer chemistry》2010,48(20):4445-4455
Our previous mechanistic discussion of the free‐radical crosslinking monoallyl/diallyl copolymerizations was extended to the cationic crosslinking monoepoxide/diepoxide copolymerizations, typically including 1,2‐epoxycyclohexane (ECH) as a monoepoxide and bis[3,4‐epoxycyclohexylmethyl] adipate (BECHMA) as a diepoxide crosslinker. In the cationic polymerization, oligomer is usually obtained because of the occurrence of characteristic chain‐forming reactions. Therefore, cationic crosslinking monoepoxide/diepoxide copolymerizations could be in the category of the network formation through free‐radical crosslinking monoallyl/diallyl copolymerizations. Thus, the gelation behavior was discussed by comparing the actual gel points with the theoretical ones; the greatly delayed gelation from theory was observed. Then, the resulting network polymer precursors (NPPs) were characterized by SEC‐MALLS‐viscometry to clarify the cationic crosslinking ECH/BECHMA copolymerization mechanism. Notably, the correlation lines of molecular weight versus elution volume were specific for the NPPs obtained at a high conversion close to the gel point as compared with those obtained by the free‐radical crosslinking monoallyl/diallyl copolymerization. This may be ascribed to the occurrence of intramolecular and intermolecular chain transfer reactions characteristic of cationic polymerization; the chain transfer reactions involve the intramolecular and intermolecular nucleophilic attack of ether oxygen or terminal hydroxyl oxygen in the NPPs to a terminal growing cation that leads to the formation of not only the loop‐ but also the crosslink‐structures containing NPPs, providing fragile ultrahigh‐molecular‐weight NPP in the SEC columns. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
6.
Toshihiko Omote Syun'ichi Hayashi Kazuhisa Ishii Kazuhiko Naitoh Tsuguo Yamaoka 《先进技术聚合物》1993,4(4):277-287
A polyimide (6F-THP) with a tetrahydropyranyl group (THP) in its side chain has been synthesized. The THP group exhibits a high acidolysis rate in this polymer's film. This rate was faster than that of a tertbutoxycarbonyl group (t-BOC), which has been previously reported [1]. Furthermore, the deprotected fluorinated polyimide (6FDA-AHHFP) became soluble in an aqueous base due to the presence of a hydroxyl group attached to the phenyl group of the diamine segment. The polyimide thus provides high performance as a photopolymer when used in conjunction with a photoacid generator after the post-exposure baking process (PEB). The photoacid generators used in this study were p-nitrobenzyl-9,10-dimethoxyanthoracene-2-sulfonate (NBAS) and diphenyliodonium-9,10-dimethoxyanthoracene-2-sulfonate (DIAS). The quantum yields of photodissociation and photoacid generation were also measured. The photoacid-generating quantum yields closely corresponded to the photosensitivities of the photoreactive polyimide system. It was confirmed that the THP group was easily deprotected even in the 6F-THP film with p-toluenesulfonic acid as a model acid catalyst. The activation energy of the THP deprotection reaction was determined to be 12.8 kcal/mol (19.5 kcal/mol in the case of t-BOC). The relationships between the THP deprotecting rate constant (kd) and acid molecular size and between kd and polyimide structure were further investigated. 相似文献
7.
María del Mar Castro López M.C. Cela PérezMaría Sonia Dopico García José Manuel López VilariñoMaría Victoria González Rodríguez Luis F. Barral Losada 《Analytica chimica acta》2012
Molecularly imprinted polymer (MIP) for solid extraction and preconcentration of catechins have been successfully prepared by a thermal polymerization method using quercetin as template, 4-vinylpyridine as functional monomer and ethylene glycol dimethacrylate as crosslinker. A solution mixture of acetone and acetonitrile was used as porogen. Systematic investigations of the influence of monomer, cross-linker, porogen, as well as polymerization conditions on the properties of the MIPs were carried out. The quercetin MIPs were evaluated according to their selective recognition properties for quercetin, structurally related compounds (catechin, epigallocatechin gallate and epicatechin) and a unrelated compound of similar molecular size (α-tocopherol). Good binding was observed for quercetin, catechin and epigallocatechin gallate with an optimized MIP in a solid phase extraction system. Adsorption and kinetic characteristics were evaluated for catechins which indicated that the synthesized polymer had high adsorption capacity and contained homogeneous binding sites. Chemical and morphological characterization of the MIP was investigated by FTIR, SEM and BET, which confirmed a high degree of polymerization. Finally, the MIP was successfully applied to the clean-up and preconcentration of catechins from several natural samples. 相似文献
8.
9.
L. A. White C. E. Hoyle S. Jonsson L. J. Mathias 《Journal of polymer science. Part A, Polymer chemistry》2002,40(5):694-706
An investigation of the free‐radical bulk photopolymerization of 1‐vinyl‐2‐pyrrolidinone (NVP) with an NVP‐based crosslinker, 1,6‐(bis‐3‐vinyl‐2‐pyrrolidinonyl)hexane (BNVP), and an NVP‐based comonomer, 3‐hexyl‐1‐vinyl‐2‐pyrrolidinone (VHP), was carried out. The enthalpies of polymerization were determined for NVP and VHP to be 30.8 and 35.7 kJ/mol, respectively. The rates of polymerization were determined for NVP/VHP and NVP/BNVP systems at various temperatures. These photopolymerization studies revealed that the overall rates of polymerization of these 3‐alkylated‐2‐pyrrolidinone derivatives increased with substitution onto the pyrrolidinone ring. A series of pyrrolidinone‐based additives in bulk NVP were used in model photopolymerizations of NVP for the evaluation of plasticizer effects. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 694–706, 2002; DOI 10.1002/pola.10142 相似文献
10.
The aim of this study was to characterize an aqueous polymer isocyanate (API) type adhesive made from natural rubber latex (NRL) and lignin as base polymers, and to evaluate bond performance of the adhesive as laminated wood adhesive. The base polymers of the adhesive were prepared by blending NRL, polyvinyl alcohol (PVA), and lignin isolated from black liquor of alkaline pretreatment of oil palm empty fruit bunch (OPEFB) and sugarcane bagasse (SB) with compositions of 25/25/0, 25/20/5, 25/15/10, 25/10/15, 25/5/20, and 25/0/25 (w/w/w). The isocyanate crosslinker was added at the level of 15% of the weight of base polymer. The glass transition temperature (Tg), heat degradation, and the homogenity of the adhesive blend were analyzed. The adhesive was used for producing laminated wood (20×8 cm2). Results showed that the addition of lignin in the base polymer blends of API adhesive did not significantly affect the Tg of the adhesives. However, it affected the thermal decomposition and bond performance of the adhesives. There were more residues and less homogenous adhesive solution due to the addition of lignin in the base polyemr blends of API adhesives. The addition of lignin in the base polymer blends caused significant decrease in bond performance of the adhesive applied in glue laminated wood. 相似文献