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排序方式: 共有310条查询结果,搜索用时 593 毫秒
1.
The moisture barrier property of AlxOy coated poly(ethylene terephthalate) (PET), poly(ethylene naphthalate) (PEN) and poly(carbonate) (PC), have been investigated. The differences in the morphology of the AlxOy sputtered grown on these substrate were investigated using atomic force microscopy (AFM). The initial growth of the AlxOy followed closely the topology of the substrate and an amplified roughness was observed. In the fully grown AlxOy, the comparative roughness followed that of the substrates. It has been found that a single layer AlxOy improved the moisture barrier of PET by an order of magnitude, PC by two orders of magnitude while no improvement was observed for PEN. UV-ozone treatment on PC further improved the moisture barrier, while no improvement was observed for PET and PEN. The comparative effects of the substrate surface roughness and surface energy on the moisture barrier are discussed. 相似文献
2.
气相色谱质谱联用仪与微机的数据传输和处理 总被引:1,自引:0,他引:1
报道了一种用于气相色谱质谱联用仪和微机之间实现数据传输和处理的方法。方法可更有效地利用质谱仪采集的数据,解决了工作站处理数据的局限性。经数据格式转换,原始数据可以在微机上实现色谱峰再现,从而为色谱条件的优化和定量数据处理创造了条件。 相似文献
3.
Yimin Jin J. Bonilla Ye-Gang Lin J. Morgan Linda McCracken J. Carnahan 《Journal of Thermal Analysis and Calorimetry》1996,46(3-4):1047-1059
Two poly(butylene terephthalate)/polycarbonate (PBT/PC) blends with different formulations were analyzed by modulated DSC (MDSC) and conventional DSC to determine differences in crystallization behavior. A significant difference (30°C in cold crystallization temperature) between the two samples was detectable by MDSC while no significant difference was seen by conventional DSC. That indicatesthe total heat flow from MDSC is not always equivalent to the heat flow from conventional DSC as we have assumed or seen before. The reason has not been fully understood, but may be related to unusual nucleation and crystallization induced by modulation. Alternative conventional DSC methods were developed and compared to the MDSC results.Dedicated to Professor Bernhard Wunderlich on the occasion of his 65th birthdayThe authors like to thank Drs. Bernhard Wunderlich and Robert Gallucci for helpful discussion, David Shaker and Mary Parsonage for some DSC experiments. Technical support from TA Instruments is also greatly appreciated. 相似文献
4.
The first part of the paper deals with a critical discussion of the methodical basis of essential work of fracture (EWF) concept with respect to the specimen geometry (especially the notch depth) and application to polymers. In the second part, an in situ testing device, which combines a tensile testing machine with an optical strain-field measuring system, has successfully demonstrated possibility of characterization of fracture behaviour of polystyrene-polybutadiene block copolymers and block copolymer/homopolymer blends as examples of nanostructured polymer materials. It has been shown that knowledge of the time evolution of the strain field close to the crack tips leads to a simple verification of the basic precondition for the applicability of the EWF concept, the precondition “plastic zone coalescence-before-stable crack propagation”. 相似文献
5.
为实现PTS系列频率综合器的微机控制,设计了一种简单的控制电路。在微机的控制下,通过该电路与微机的并行通讯口,用C语言编写的控制程序可以很方便的控制频率综合器的输出频率。控制程序采用菜单操作,电路所需的+5V电源由微机提供,整个控制系统简单实用,值得推广。 相似文献
6.
7.
PC/PBT共混体系的研究:Ⅰ.PC,PBT熔融共混时的酯交换反应 总被引:9,自引:0,他引:9
采用红外光谱、核磁共振等测试手段,系统地研究了PC、PBT熔融共混时的酯交换反应,发现PBT中残余的Ti催化剂会对酯交换反应起催化作用。通过加入能和Ti催化剂络合添加剂,可以控制酯交换程度,这为控制PC/PBT合金的性能提供了一个非常有效的方法。 相似文献
8.
PBT/PC共混体系流变性能与形态结构研究 总被引:1,自引:0,他引:1
采用毛细管流交仪测定了PBT/PC共混物的表观粘度、剪切应力,观察了不同共混物组成和不同温度下共混物的流变行为,并借助扫描电镜对共混物和微观形态结构进行分析。结果表明:PBT/PC熔体共混物的流变行为接近假塑性流体.温度对共混物的流变行为影响很大,共混物的熔体粘度在PBT/PC为90/10和60/40时呈双极值.共混物为两相结构,PC含量为4-50%时呈两互锁结构。 相似文献
9.
Marcos Mandaji Tiago Buckup Rafael Rech Ricardo Rego Bordalo Correia Tarso Ledur Kist 《Talanta》2007,71(5):1998-2002
The performance of fluorescence detectors in capillary electrophoresis is maximized when the excitation light intensity is modulated in time with optimal frequencies. This is especially true when photomultiplier tubes are used to detect the fluorescent light. The photomultiplier tube amplified raw output signal can in principle be captured directly by a personal computer sound card (PCSC) and processed by a lock-in emulated by software. This possibility is demonstrated in the present work and the performance of this new setup is compared with a traditional data acquisition system. The results obtained with this “PCSC and lock-in emulated by software” were of the same quality or even better compared to that obtained by conventional time integrators (Boxcars) and data acquisition boards. With PCSC the limits of detection (LOD) found for both naphthalene-2,3-dicarboxaldehyde-derivatized tyrosine and alanine were 3.3 and 3.5 fmol (injection of 5 nL of samples at 0.66 and 0.70 μmol/L), respectively. This is at least three times better compared to conventional systems when light emitting diodes (LEDs) are used as the excitation source in fluorescence detectors. The PCSC linear response range was also larger compared to conventional data acquisition boards. This scheme showed to be a practical and convenient alternative of data acquisition and signal processing for detection systems used in capillary electrophoresis. 相似文献
10.
Harald Høiland 《Journal of solution chemistry》1977,6(5):291-297
The isentropic coefficients of compressibility of the homologous series of alcohols and diols R
n
CH2OH (n=2–6), CH3CHOHR
n
(n=1–5), 1,2-propanediol, 1,3- 1,4- and 2,3-butanediol, 1,5-pentanediol, and 1,7-heptanediol dissolved in propylene carbonate have been measured at 25°C. Isentropic partial molal compressibilities and group partial molal compressibilities at infinite dilution have been evaluated. The isentropic partial molal compressibilities of these alcohols and diols have been compared with the corresponding values in water. This comparison shows that the values in propylene carbonate are higher than in water by a factor of 10 due to an increased compressibility of the solvation sheath around nonpolar groups in PC. 相似文献