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排序方式: 共有152条查询结果,搜索用时 15 毫秒
1.
反对数微分简易示波伏安法的研究 总被引:2,自引:0,他引:2
在获得微分简易地波伏安图的实验线路中,增加了反对数装置,提出了反对数微分简易示波伏安法。该方法被应用于铝合金中微量铜和分子筛中微量钴的测定,获得了满意结果。 相似文献
2.
The thermodynamic model of inorganic arsenic was validated by comparing the predicted As(III) concentration with the experimentally determined one in several river waters samples of the Basque Country (Spain) collected in two sampling campaigns: spring and autumn 2000. This model takes into account the acid-base equilibria of As(III) and As(V) together with the redox equilibria between the H3AsO3 and H3AsO4 species. A correct prediction of As(III) concentration requires the knowledge of the total concentration of arsenic, pH, redox potential (referred to hydrogen electrode), and ionic strength values of the solution. The estimation of the activity coefficients of the arsenic species was performed by means of the Modified Bromley’s Methodology (MBM).In order to perform the experimental As(III) determination, an analytical method was implemented by using an ion exchange separation of As(III)/As(V) on a continuous FIA-IE-HG-AAS system. The total arsenic concentration was determined together with total concentration of the main alkaline or alkaline-earth metals and anions in the natural waters. Temperature compensated measurements of the pH and redox potentials were made in-situ at the sampling sites.For both seasonal campaigns, the agreement between predicted and experimental As(III) is really high for those samples belonging to non polluted river waters. 相似文献
3.
苯巴比妥的二次微分简易示波伏安法测定 总被引:5,自引:0,他引:5
利用苯巴比妥的示波特性 ,分别建立了在0.2mol/LKOH和1.0×10-4mol/LCd2 +-0.1mol/L硼砂底液中直接和间接测定苯巴比妥的二次微分简易示波伏安法 ;直接测定和间接测定的线性范围分别为1.0×10 -5mol/L~1.0×10 -4mol/L和4.0×10 -6mol/L~8.0×10 -5mol/L ;检出限分别为8×10 -6mol/L和2×10 -6mol/L;在直接测定中 ,对6.000×10 -5mol/L苯巴比妥进行10次测定的RSD为4.5 % ;间接测定中 ,对2.000×10 -5mol/L苯巴比妥进行10次测定的RSD为2.6 % ;这一研究表明对于一些在示波分析中灵敏度不高或本身没有示波活性的药物 ,可以利用其与金属离子生成沉淀的方法间接测定 ,从而提高药物测定的灵敏度、拓宽示波分析应用领域 相似文献
4.
磷肥中有效磷的示波滴定 总被引:2,自引:0,他引:2
根据Pb2+能与PO_4 ̄(3-)定量形成沉淀,过量的Pb2+在NaClO3-六次甲基四胺底液示波图上有敏锐切口的性质,报告了磷肥中有效磷含量测定的示波滴定新方法。该法与通用方法相比较,具有操作简便、测定快速、终点直观的优点。 相似文献
5.
6.
We have measured, by means of NMR titrations, the binding constants for the complexes between hosts N,N′-bis(6-methylpyridin-2-yl)-1,3-benzenedicarboxamide (7) and 4-chloro-N,N′-bis(6-methylpyridin-2-yl)-2,6-pyridinedicarboxamide (8, hydrated) with biotin methyl ester (1), N,N′-dimethylurea (2), 2-imidazolidone (3), N,N′-trimethylenurea (4), barbital (5) and tolbutamide (6) as guests. Molecular Mechanics calculations (Monte Carlo Conformational Search, AMBER and OPLS force fields, MacroModel v.8.1) on the complexes formed between the foregoing guests and hosts 7 and 8, comparatively with 4-oxo-N,N′-bis(6-methylpyridin-2-yl)-1,4-dihydro-2,6-pyridinedicarboxamide (9a) have been carried out in order to determine the correlation between experimental and theoretical results and to understand the behaviour of the designed new hosts. Finally we have performed single point DFT [B3LYP/6-31G(d,p)] calculations on the optimised Molecular Mechanics geometries for the complexes between hosts 7-9 and water. 相似文献
7.
《Analytical letters》2012,45(2):67-77
Abstract Some phenols, amines and active methylene group compounds have been determined by photometric titration with standard solutions of diazonium salts, using extractive end point detection where the azo dyestuff formed is insoluble in aqueous solutions. Two break points were observed in the titration of bifunctional compounds. 相似文献
8.
《Analytical letters》2012,45(1):19-22
Abstract Observations are made on the end point of the photometric EDTA titration of nickel in the presence of large amounts of cobalt using murexide as indicator. Difficulties with the end point are believed due to an ionic strength effect and may be remedied by dilution of the sample to be titrated. 相似文献
9.
Shin-ichi Kondo Kimihiro Endo Jun Iioka Keisuke Sato Yuka Matsuta 《Tetrahedron letters》2017,58(43):4115-4118
We have successfully prepared 5-(2-phenylethynyl)isophathalilc acid as a signaling unit and the corresponding derivatives for an anion receptor 2 and a barbiturate receptor 4. Receptor 2 showed characteristic UV–vis changes and dramatic fluorescence quenching upon the addition of anions and receptor 4 showed UV–vis and an OFF-ON fluorescence changes upon the addition of dibutylbarbituric acid based on the diphenylethyne moiety. 相似文献
10.
From the early precipitation-based techniques, introduced more than a century ago, to the latest development of enzymatic bio- and nano-sensor applications, the analysis of phytic acid and/or other inositol phosphates has never been a straightforward analytical task. Due to the biomedical importance, such as antinutritional, antioxidant and anticancer effects, several types of methodologies were investigated over the years to develop a reliable determination of these intriguing analytes in many types of biological samples; from various foodstuffs to living cell organisms. The main aim of the present work was to critically overview the development of the most relevant analytical principles, separation and detection methods that have been applied in order to overcome the difficulties with specific chemical properties of inositol phosphates, their interferences, absence of characteristic signal (e.g., absorbance), and strong binding interactions with (multivalent) metals and other biological molecules present in the sample matrix. A systematical and chronological review of the applied methodology and the detection system is given, ranging from the very beginnings of the classical gravimetric and titrimetric analysis, through the potentiometric titrations, chromatographic and electrophoretic separation techniques, to the use of spectroscopic methods and of the recently reported fluorescence and voltammetric bio- and nano-sensors. 相似文献