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1.
本文利用含氢有机硅化合物与含双键的氨基酸酯的加成反应,合成了5种新的有机硅氨基酸衍生物。介绍了一种合成N-烷基取代氨基酸酯的新方法。对新化合物进行了元素和光谱分析鉴定。  相似文献   
2.
库仑滴定法测定有机硅样品中的氮含量   总被引:3,自引:0,他引:3  
谢择民  王清正 《分析化学》1993,21(2):206-208
本文利用库仑滴定法研究了高分子和低分子硅氮化合物及含氮有机硅样品中氮含量的测定,并研究和讨论了影响测定结果准确性的因素。  相似文献   
3.
A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5)3) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The crystal structures of obtained compounds were studied by X-ray diffraction analysis (7 structures). The peculiarities of crystal packing were analyzed by means of DFT calculations.  相似文献   
4.
硅基甲硫醇R^1R^2CH3SiCH2SH与O,O-二烷基二硫代磷酸酯(RO)2P(S)SH及甲醛可顺利地发生类Mannich缩合反应,利用此反应和硅基甲硫醇与O,O-二乙基-S(2-溴乙基)二硫代磷酸酯的取代反应合成了37种新的含硅二硫代到酯化合物(RO)2P(S)S(CH2)nSCH2SiCH3R^1R^2(n=1,2),在初筛浓度下,该类化合物具有一定的杀虫,杀螨活性。  相似文献   
5.
The HfCl4 catalyzed polymerization of allyl(4-ethynylphenyl)dimethylsilane (1a) proceeded smoothly to give poly[dimethyl-(1,4-pentadienyl)phenylsilane] (2a), and the HfCl4 catalyzed reaction of 1-allyl-2-(4-ethynyphenyl)-1,1,2,2-tetramethyldisilane (1b) afforded poly[1,1,2,2-tetramethyl-1-(1,4-pentadienyl)-2-phenyldisilane] (2b). These polymerization reactions proceeded via the stereoselective trans-allylsilylation of the 4-ethynyl group attached to the aromatic ring.  相似文献   
6.
Summary In the present study the effects of addition of iron on the catalytic activity and Si tolerability of Pt/g-Al2O3in the total oxidation of volatile organic compounds were investigated. Preliminary results showed that there is a noticeable improvement effect on Si-tolerance of catalyst, particularly for short term poison exposure. Bulk analysis of deposited silicon on the catalyst surface indicated that both Pt/g-Al2O3and iron-doped pellets had roughly the same silicone uptakes. Deactivation of catalyst was reversible and much faster for iron doped sample. The promoting effects of iron were related to its electronegativity and, to blocking of fewer Pt sites when iron is present at the surface of the catalyst.  相似文献   
7.
有机硅改性丙烯酸酯共聚乳液合成方法及胶膜性能的研究   总被引:59,自引:0,他引:59  
用一次投料法、单体乳液滴加法和引发剂滴加法有机硅改性丙烯酸酯共聚乳液,聚合过程、胶粒形态及乳液稳定性的观测结果表明:单体乳液滴加法是合成该类乳液的最佳方法,研究了单体乳液滴加法中有机硅含量与聚合反及胶膜性能的关系,结果表明:有机硅含量在15%以下时,聚合反应可以顺利进行,胶膜性能不仅依赖于聚合时有机硅单体的总量,而且还依赖于有机硅单体中活性硅氧烷所占的比例。  相似文献   
8.
Abstract

The Schiff bases derived from the condensation of 2-aminobenzothiazole derivatives and 2-hydroxy-3-methoxybenzaldehyde and their silicon(IV) complexes with the general formula R2Si(L)Cl (R = Et, Bu, Ph, L = 2-(2-hydroxy-3-methoxy) benzylideneaminobenzo-thiazole) have been synthesized. These complexes have been characterized by elemental analysis, molar conductance, and spectroscopic studies including IR and NMR (1H, 13C, and 29Si) spectroscopy. The analytical data suggest trigonal bipyramidal geometry around the silicon atom in the resulting complexes. The ligands and their organosilicon complexes have also been evaluated for in vitro antimicrobial activity against bacteria (Staphylococcus aureus, Bacillus subtilis, and Escherichia coli) and fungi (Aspergillus niger and Candida albicans). The complexes were found to be more potent as compared to the ligands.

Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.  相似文献   
9.
Water-soluble double-coated magnetic nanoparticles (NPs) containing cytotoxic decyldimethyl(ββ-dimethylaminoethoxy)silane methiodide (AA) molecule sorbed at biocompatible magnetic particles, which consist of magnetite pre-coated with oleic acid (OA), have been prepared. X-ray line profile broadening analysis was used for crystallite size determination. The method of magnetogranulometry has been used for determination of diameter of iron oxide magnetic core and magnetic properties of NPs prepared. In vitro cytotoxicity on monolayer tumor cell lines HT-1080 (human fibrosarcoma), MG-22A (mouse hepatoma) and normal mouse fibroblasts (NIH 3T3) has been studied. It was revealed that all the water-based colloidal solutions obtained are non-toxic and possess high NO-induction ability.  相似文献   
10.
(2-Fluoro-5-pyridyl)dimethyl(oxiran-2-ylmethyl)silane (1a) and (2-chloro-5-pyridyl)dimethyl(oxiran-2-ylmethyl)silane (1b) were prepared in two-step syntheses, starting from allylchlorodimethylsilane. Compounds 1a and 1b were characterized by elemental analyses and NMR studies. With the synthesis of 1a and 1b, new potential building blocks for the synthesis of silicon-containing drugs have been made accessible.  相似文献   
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