全文获取类型
收费全文 | 8037篇 |
免费 | 809篇 |
国内免费 | 1022篇 |
专业分类
化学 | 7163篇 |
晶体学 | 150篇 |
力学 | 957篇 |
综合类 | 82篇 |
数学 | 177篇 |
物理学 | 1339篇 |
出版年
2024年 | 20篇 |
2023年 | 68篇 |
2022年 | 194篇 |
2021年 | 253篇 |
2020年 | 357篇 |
2019年 | 282篇 |
2018年 | 289篇 |
2017年 | 347篇 |
2016年 | 393篇 |
2015年 | 408篇 |
2014年 | 384篇 |
2013年 | 669篇 |
2012年 | 487篇 |
2011年 | 454篇 |
2010年 | 355篇 |
2009年 | 415篇 |
2008年 | 399篇 |
2007年 | 505篇 |
2006年 | 477篇 |
2005年 | 417篇 |
2004年 | 428篇 |
2003年 | 418篇 |
2002年 | 341篇 |
2001年 | 243篇 |
2000年 | 254篇 |
1999年 | 186篇 |
1998年 | 125篇 |
1997年 | 131篇 |
1996年 | 121篇 |
1995年 | 82篇 |
1994年 | 88篇 |
1993年 | 52篇 |
1992年 | 61篇 |
1991年 | 33篇 |
1990年 | 30篇 |
1989年 | 23篇 |
1988年 | 19篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 9篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 2篇 |
1971年 | 3篇 |
1959年 | 1篇 |
排序方式: 共有9868条查询结果,搜索用时 15 毫秒
1.
固体力学有限元体系的结构拓扑变化理论 总被引:2,自引:1,他引:1
本文是文[1]的继续.文[1]提出了杆件系统的结构拓扑变化理论和拓扑变化法本文将这一理论和方法推进到连续体有限元体系;且在此基础上揭示出有限元体系的一个新性质,称为基本位移之梯度的正交性定理,从而给出一套设计敏度的显式表达式,可直接用于计算. 相似文献
2.
LI Yu-qiong SUN Zhen-rong ZHANG Shi-an YANG Xi-hua WANG Zu-geng. Key Laboratory of Optical Magnetic Resonance Spectroscopy 《光谱学与光谱分析》2006,26(8):1395-1395
The authors achieved the temporal coherent control in an Er^3+ doped telluride glass, one kind of disordered solids. The upconversion at 670 nm was modulated and the dephasing time was simulated as 300 fs. Moreover, the photon echo signal gave the dephasing time due to the phonon interaction. The agreement between the two data indicates that the interaction between the wavepacket and the phonon leads to the fast disappearance of wavepackets interference, which is helpful for the tech- nique to be applied to the disordered solids. 相似文献
3.
Nuclear Magnetic Resonance (NMR) was used to investigate the extrusion behaviour of PTFE pastes in a ram extruder. By means
of 1H-NMR imaging (MRI) it is possible to determine the local proton density and therefore, the local fluid concentration. The
19F-MRI provides the local solid concentration. Thus the local saturation and the local porosity can be calculated with the
information of the local fluid and solid concentration. Furthermore displacement profiles can be derived from NMR images by
means of correlation techniques without any preparation or marking of the pastes.
Received: 8 May 2000 Accepted: 1 May 2001 相似文献
4.
Cosmic dust and our origins 总被引:1,自引:0,他引:1
J Mayo Greenberg 《Surface science》2002,500(1-3):793-822
The small solid particles in the space between the stars provide the surfaces for the production of many simple and complex molecules. Processes involving the effects of ultraviolet irradiation of the thin (hundredth micron) mantles are shown to produce a wide range of molecules and ions also seen in comets. Some of the more complex ones inferred from laboratory experiments are expected to play an important role in the origin of life. An outline of the chemical evolution of interstellar dust as observed and as studied in the laboratory is presented. Observations of comets are shown to provide substantial evidence for their being fluffy aggregates of interstellar dust as it was in the protosolar nebula, i.e. the interstellar cloud which collapsed to form the solar system. The theory that comets may have brought the progenitors of life to the earth is summarized. 相似文献
5.
The effect of the amount of desorbed water on the mechanical properties of composites based on low-density polyethylene and linen yarn production waste (LW) is analyzed by statistical methods. It is shown that the amount of absorbed water decreases during the desorption process at room temperature both for specimens modified and unmodified with diphenylmethane diisocyanate (DIC.) The most sensitive to the action of water is the elastic modulus, which decreases considerably under the effect of water and is fully restored in the desorption process. The tensile strain also increases with the amount of absorbed water. It is found that the elastic modulus of the unmodified composite correlates linearly with the amount of desorbed water. Between the amount of desorbed water and the tensile strain, as well the specific work of deformation, a negative linear correlation is revealed. After water desorption, all strength and deformation characteristics of both the modified and unmodified composites are fully recovered.__________Translated from Mekhanika Kompozitnykh Materialov, Vol. 41, No. 4, pp. 515–524, July–August, 2005. 相似文献
6.
Dimitar I. Pushkarov 《Central European Journal of Physics》2004,2(3):420-455
Basic ideas and results which characterize quantum diffusion of defects in quantum crystals like solid helium as a new phenomenon
are presented. Quantum effects in such media lead to a delocalization of point defects (vacancies, impurities etc.) and they
turn into quasiparticles of a new type—defectons, which are characterized not by their position in the crystal lattice but
by their quasimomentum and dispersion law. Defecton-defecton and defecton-phonon scattering are considered and an interpolation
formula for the diffusion coefficient valid in all interesting temperature and concentration regions is presented. A comparison
with the experimental data is made. Some alternative points of view are discussed in detail and the inconsistency of the Kisvarsanyi-Sullivan
theory is shown. 相似文献
7.
Tin and titanium ferrocyanides were studied as adsorbents for alkali metal ions, viz., 134Cs and 22Na, which represent radioactive wastes. The ferrocyanides were prepared in granular form. The tin version contained 11.2% water, while the titanium version contained 17.7% water. The exchange capacities for Cs+ and Na+ in the hydrated tin version were about 1.5 and 0.7 meq/g, respectively, while those in the titanium version were 2.2 and 1.2 meq/g, respectively. Drying at 250°C decimated those capacities. The diffusional time constant of Cs+ at 25°C, determined via Fick's second law, was of order of magnitude 1 × 10–3 s–1, though there were minor differences due to particle size and the form of ferrocyanide. Similarly, the effective diffusivity was of order of magnitude 1 × 10–8 cm2/s. The titanium version responded slightly faster than the tin version. Likewise, equilibrium measurements in mixtures with sodium nitrate, potassium nitrate, or uranium oxide, showed that the titanium version exhibited significantly greater selectivity for Cs+ than did the tin version. Unfortunately, tests of complete elution of the Cs+ from the ferrocyanides were mostly disappointing. Work continues on that subject. 相似文献
8.
室温或近室温固相反应要求绿色化、清洁化[1,2]。我们以KMnO4和MnCl2·4H2O为原料,用室温固相氧化还原反应制备氧化锰粉体时,得到了一种对H2O2分解具有较高催化活性的纳米KMn8O16粉体,用XRD、SEM、IR等技术对其进行了表征,发现研磨时间对粉体性能有显著影响。1 实验部分1 1 粉体的制备按摩尔比(2∶3)准确称取一定量的分析纯KMnO4和MnCl2·4H2O,分别置于玛瑙研钵中充分研细,再混合研磨,固相反应立即发生,体系颜色逐渐加深,并有刺激性气体产生,充分研磨后70℃恒温12h,固相产物依次经水洗至中性、醇洗、抽滤,真空干燥得黑色粉… 相似文献
9.
Cationic polymer as a kind of flocculant is widely applied in purification treatment of waste water. Because it has positive charge group, it is able to connect strongly the suspended matters, short cellulose and other microparticles. The research on synthesis of cationic polymer and application in treatment of waste water is very universal abroad. But domestic research on those is not general. The technology of synthesis of PEM is simple, and the production cost is low. It is easy to apply in treatment of waste water.Synthesis of PEM Emulsion FlocculantSome distilled water, PVA(poly(vinyl alcohol)), EA(ethyl acrylate), and K2S2O8(potassium persulfate) were put into reaction vessel. Kept stirring up under nitrogen. When heated the solution to 40℃, dropped the water solution of MTA[(2-methacryloxylethyl)trimethyl ammonium].Maintained the temperature at 70℃, reacted about 7-8 hours. Then got the PEM emulsion. Changed the ratio of EA and MTA. Obtained a series of PEM emulsions.Stability and Convertibility of PEM EmulsionThe test results showed that when the EA/MTA was 85/15, the PEM emulsion was most stable.When the total monomer quantity was 35%, the convertibility of PEM emulsion was the highest,i.e.98.6%.The MTA Copolymerization Ratio and Morphology of PEM EmulsionWhen the monomers EA/MTA=85/15 and total monomer quantity was 35%, the MTA copolymerization ratio of PEM emulsion was 95.15%(the highest), and the PEM emulsion was some microspheres with 100-180nm of diameter.The Test Results of PEM Emulsion in Treatment of Waste Water The PEM emulsion flocculant was applied in treatment of waste water of paper mill, and measured the precipitation time(t) and transmittancy(T). The test results were showed in table 1. The optimum value of PEM which was able to make the waste water of paper mill into clear water was 0.008%. 相似文献
10.
Grigor'ev S. A. Kalinnikov A. A. Porembskii V. I. Baranov I. E. Borisova E. V. Fateev V. N. 《Russian Journal of Electrochemistry》2004,40(11):1188-1192
A two-dimensional mathematical model for the transport of reactants in a fuel cell with a solid polymer electrolyte is developed. The model is used for analyzing spatial distributions of the concentration of reactants and current density over the cell. The effect of the catalytic-layer activity, reactant speed, bipolar-plate geometry, thickness and porosity of current collector and/or gas-diffusion sublayer, and the reaction mixture composition on the fuel cell efficiency is estimated theoretically and experimentally. 相似文献