A simple,rapid and sensitive method based on modified multiwalled carbon nanotube for preconcentration and determination of lead ions in aqueous media in natural pHs

In this study, multiwalled carbon nanotube (MWCNT) was modified by the pyridine group using a silane agent and characterized by infrared spectroscopy (IR), thermal analysis (TG/DTA), and elemental analysis (CHN) and scanning electron microscopy (SEM). The application of this sorbent was investigated in determination of lead ions in aqueous samples, using flame atomic absorption spectrometry (FAAS). Through this study, different parameters such as pH and sample flow rate on adsorption process and eluent concentration, volume and flow rate were optimized. The limit of detection (LOD), the relative standard deviation and the recovery of the method were 2 ng mL^?1, 1.3% and 99.7%, respectively. Two standard reference materials (NIST 1571 and NIST 1572) were used to verify accuracy of this method. Finally, the sorbent was successfully applied for extraction and determination of low levels of Pb(II) ions in aqueous samples.     

Facile fabrication of fast recyclable and multiple self‐healing epoxy materials through diels‐alder adduct cross‐linker

A reversibly cross‐linked epoxy resin with efficient reprocessing and intrinsic self‐healing was prepared from a diamine Diels‐Alder (DA) adduct cross‐linker and a commercial epoxy oligomer. The newly synthesized diamine cross‐linker, comprising a DA adduct of furan and maleimide moieties, can cure epoxy monomer/oligomer with thermal reversibility. The reversible transition between cross‐linked state and linear architecture endows the cured epoxy with rapid recyclability and repeated healability. The reversibly cross‐linked epoxy fundamentally behaves as typical thermosets at ambient conditions yet can be fast reprocessed at elevated temperature like thermoplastics. As a potential reversible adhesive, the epoxy polymer with adhesive strength values about 3 MPa showed full recovery after repeated fracture‐thermal healing processes. The methodology explored in this contribution provides new insights in modification of conventional engineering plastics as functional materials. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2094–2103     

Cleaving functors and controlled wild algebras

We show that the cleaving functors introduced in [Bautista et al., Invent. Math. 81 (1985) 217] as a tool for proving infinite representation type of finite-dimensional algebras can also be used to establish controlled wildness. The main application is that an algebra is controlled wild if there is an indecomposable projective module with a Loewy factor having a homogeneous direct summand which is of length at least 3. As a second application we derive Han's covering criterion.     

SEPARATING SCN~- FROM DESULPHURIZATION WASTE SOLUTION OF COCKING PLANT BY D241 RESIN

1. INTRODUCTION In the process of coking plant, about 30%~35% sulfur is transformed to H2S and some other sulfide, which form impurity in coal gas together with NH3 and HCN. Only 0.1% H2S containing in air can lead to die, so it is very important to carry on desulphurization and decyanation with coal gas [1~3]. Currently desulphurization and decyanation craft technique have Dry Oxidation Technology, Wet Oxidation Technology and Liquid Absorption Technology [2] three main kinds. The…     

Equivalences of comodule categories for coalgebras over rings

In this article we defined and studied quasi-finite comodules, the cohom functors for coalgebras over rings. Linear functors between categories of comodules are also investigated and it is proved that good enough linear functors are nothing but a cotensor functor. Our main result of this work characterizes equivalences between comodule categories generalizing the Morita-Takeuchi theory to coalgebras over rings. Morita-Takeuchi contexts in our setting is defined and investigated, a correspondence between strict Morita-Takeuchi contexts and equivalences of comodule categories over the involved coalgebras is obtained. Finally, we proved that for coalgebras over QF-rings Takeuchi's representation of the cohom functor is also valid.     

中国股市长记忆的修正R/S分析

本文在比较各种长记忆检验方法优缺点的基础上,采用修正的R/S分析检验我国沪深两股市日收益和日绝对收益序列的长记忆性。结果表明在0.05的显著水平下,两股市的日收益序列均无长记忆,但深圳成指日收益序列的记忆长度比上证综指日收益序列的记忆长度长;以日绝对收益序列为代表的波动序列具有较强的长记忆性。     

A Modified Quasi-Newton Method for Structured Optimization with Partial Information on the Hessian

This paper develops a modified quasi-Newton method for structured unconstrained optimization with partial information on the Hessian, based on a better approximation to the Hessian in current search direction. The new approximation is decided by both function values and gradients at the last two iterations unlike the original one which only uses the gradients at the last two iterations. The modified method owns local and superlinear convergence. Numerical experiments show that the proposed method is encouraging comparing with the methods proposed in [4] for structured unconstrained optimization Presented at the 6th International Conference on Optimization: Techniques and Applications, Ballarat, Australia, December 9–11, 2004     

离子交换富集-导数火焰原子吸收法测定自来水中Cu,Fe和Zn

本文研究了用 2 0 1× 7阳离子交换树脂对自来水中的微量元素进行交换富集 ,采用微量脉冲进样 导数火焰原子吸收法测定富集后溶液中的Cu ,Fe和Zn ,该方法灵敏度分别为 0 2 9,0 5 9和 0 0 6 μg·L- 1 ,精密度分别为 4 2 8% ,1 95 %和 2 2 8% ,检测限分别为 1 2 8,5 85和 0 6 8μg·L- 1 ,回收率分别为 91 13% ,10 1 34%和99 84 % ,本方法大大减少了需样量 ,简便快速 ,灵敏度高。     

一致Banach空间中非扩张映象的弱收敛定理

设犈是一致凸Ｂａｎａｃｈ空间，满足Ｏｐｉａｌ条件或具有Ｆｒｅｃｈｅｔ可微范数，犆是犈的非空闭凸子集，且犜：犆→犆是非扩张映象．又设对任何初始数据狓１ ∈犆，序列｛狓狀｝由下列修改了的Ｉｓｈｉｋａｗａ迭代程序生成：狓狀＋１ ＝狋狀犜狀（狊狀犜狀狓狀＋ （１－狊狀）狓狀）＋ （１－狋狀）狓狀，　狀≥１， （Ｉ）其中，数列｛狋狀｝与｛狊狀｝满足下列条件（ｉ）和（ｉｉ）之一：（ｉ）狋狀∈ ［犪，犫］且狊狀∈ ［０，犫］；（ｉｉ）狋狀∈ ［犪，１］且狊狀∈ ［犪，犫］，这里，常数犪，犫满足０＜犪≤犫＜１．作者证明了，犜有不动点的充要条件是，｛狓狀｝ 弱收敛且｛‖狓狀－犜狓狀‖｝收敛到０．而且，由此即知，若犜有不动点，则｛狓狀｝弱收敛到犜的一个不动点．