全文获取类型
收费全文 | 62篇 |
免费 | 1篇 |
国内免费 | 1篇 |
专业分类
化学 | 60篇 |
物理学 | 4篇 |
出版年
2021年 | 1篇 |
2019年 | 1篇 |
2014年 | 1篇 |
2013年 | 1篇 |
2011年 | 1篇 |
2010年 | 2篇 |
2009年 | 5篇 |
2008年 | 2篇 |
2007年 | 4篇 |
2006年 | 3篇 |
2005年 | 4篇 |
2004年 | 4篇 |
2002年 | 1篇 |
2001年 | 1篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 2篇 |
排序方式: 共有64条查询结果,搜索用时 31 毫秒
1.
2.
A fully automated flow-through microcolumn fractionation system with on-line post-extraction derivatization is proposed for monitoring of orthophosphate in solid samples of environmental relevance. The system integrates dynamic sequential extraction using 1.0 mol l−1 NH4Cl, 0.1 mol l−1 NaOH and 0.5 mol l−1 HCl as extractants according to the Hieltjes-Lijklema (HL) scheme for fractionation of phosphorus associated with different geological phases, and on-line processing of the extracts via the Molybdenum Blue (MB) reaction by exploiting multisyringe flow injection as the interface between the solid containing microcolumn and the flow-through detector. The proposed flow assembly, capitalizing on the features of the multicommutation concept, implies several advantages as compared to fractionation analysis in the batch mode in terms of saving of extractants and MB reagents, shortening of the operational times from days to hours, highly temporal resolution of the leaching process and the capability for immediate decision for stopping or proceeding with the ongoing extraction. Very importantly, accurate determination of the various orthophosphate pools is ensured by minimization of the hydrolysis of extracted organic phosphorus and condensed inorganic phosphates within the time frame of the assay. The potential of the novel system for accommodation of the harmonized protocol from the Standards, Measurement and Testing (SMT) Program of the Commission of the European Communities for inorganic phosphorus fractionation was also addressed. Under the optimized conditions, the lowest detectable concentration at the 3σ level was ≤0.02 mg P l−1 for both the HL and SMT schemes regardless of the extracting media. The repeatability of the MB assay was better than 2.5% and the dynamic linear range extended up to 7.0 mg P l−1 in NH4Cl and NaOH media and 15 mg P l−1 whenever HCl is utilized as extractant for both the HL and SMT protocols. 相似文献
3.
4.
5.
6.
7.
Summary Indirect conductimetric detection of nonelectrolytes was investigated in microcolumn liquid chromatography. The mobile phase contained an electrolytic substance which maintained a high background and analytes were indirectly detected owing to a depression of the background signal. The dynamic reserve, defined as the ratio of the background to its noise level, was 9.3×104, and the detection limits at S/N=3 were 10–32 ng for alcohols examined. 相似文献
8.
9.
The feasibility of a microcolumn electrophoresis technique was investigated with a 100 mm length, 2 mm I.D. fused-silica microcolumn packed with uniform quartz microncrystals prepared by hydrothermal synthesis. To evaluate the separation technique, tryptophan, phenylalanine and tyrosine were primarily separated by the microcolumn electrophoresis and detected at 216 nm without derivatization by an ordinary spectrophotometer. The separation conditions of the amino acids were optimized. With 1.5 mmol/L disodium phosphate buffer solution (pH 11.5) containing 25% (v/v) methanol and 10% (v/v) acetonitrile, the three amino acids were separated and the separation efficiency of tryptophan was 4.5 × 104 plates/m. The limits of detection were 0.035, 0.22 and 0.20 μmol/L, respectively. The sample capacity of the electrophoretic microcolumn achieved 35 μL. The proposed method was used to determine these amino acids in compound amino acid injection samples without derivatization. For the simplicity and portability of the microcolumn electrophoresis, it is studied as one of the high-performance separation techniques for an in situ and real-time electrokinetic flow analysis system. For its high detection sensitivity and large sample capacity, it can be developed for preparative electrophoresis. 相似文献
10.
Summary A packed capillary LC column, featuring 225,000 theoretical plates, was used to resolve numerous polyaromatic isomers (six to nine-ring structures) from an extract of carbon black. Although mass-spectral investigations carried out on the trapped components provide ony tentative identification of large aromatic molecules, improved isomeric resolution through the use of LC microcolumns is a signjifiocant improvement over hitherto used-methods.Dedicated to Profesor A. Zlatkis on the occasion of huis 60th birthday. 相似文献