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《Journal of Coordination Chemistry》2012,65(10):1821-1828
The sixth supramolecular isomer of Cu(I) and 3,5-di-2-pyridyl-1,2,4-triazolate (2-pytz), [Cu2(2-pytz)2] n (1), via in situ solvothermal ligand reaction, has been synthesized and characterized as a rare meso-helical chain. Complex 1 exhibits high thermal stability (until 400°C) confirmed by thermogravimetric analysis and has potential applications as an optical material. This research makes the maximum number of genuine supramolecular isomers with structural characterization, found for coordination polymers, six. 相似文献
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