Synthesis and characterization of VO–vanillin complex immobilized on MCM-41 and its facile catalytic application in the sulfoxidation reaction,and synthesis of 2,3-dihydroquinazolin-4(1H)-ones and disulfides in green media

In this work, a vanillin complex is immobilized onto MCM-41 and characterized by FT-IR, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, thermogravimetric analysis, and BET techniques. This supported Schiff base complex was found to be an efficient and recoverable catalyst for the chemoselective oxidation of sulfides into sulfoxides and thiols into their corresponding disulfides (using hydrogen peroxide as a green oxidant) and also a suitable catalyst for the preparation of 2,3-dihydroquinazolin-4(1H)-one derivatives in water at 90°C. Using this protocol, we show that a variety of disulfides, sulfoxides, and 2,3-dihydroquinazolin-4(1H)-one derivatives can be synthesized in green conditions. The catalyst can be recovered and recycled for further reactions without appreciable loss of catalytic performance.     

From a Nonlinear, Nonconvex Variational Problem to a Linear, Convex Formulation

   Abstract. We propose a general approach to deal with nonlinear, nonconvex variational problems based on a reformulation of the problem resulting in an optimization problem with linear cost functional and convex constraints. As a first step we explicitly explore these ideas to some one-dimensional variational problems and obtain specific conclusions of an analytical and numerical nature.     

Geometrical Molecular Structure Design Concept in Approach to Homo- and Heterometallic Precursors of Advanced Materials in Sol–Gel Technology

The article describes the principles of the Single Source Precursor approach to inorganic materials and introduces the Geometrical Molecular Structure Design Concept (MSDC) based on the choice of a proper molecular structure type for the desired precursor and completing it with ligands providing both the necessary number of donor atoms and the sterical protection of the chosen core. Application of MSDC is illustrated with examples taken from development of new approaches in the synthesis of oxide and sulfide catalysts and ferroelectric oxide materials.     

A note on minimization problems and multistep methods

Summary. We use the qualitative properties of the solution flow of the gradient equation to compute a local minimum of a real-valued function . Under the regularity assumption of all equilibria we show a convergence result for bounded trajectories of a consistent, strictly stable linear multistep method applied to the gradient equation. Moreover, we compare the asymptotic features of the numerical and the exact solutions as done by Humphries, Stuart (1994) and Schropp (1995) for one-step methods. In the case of -stable formulae this leads to an efficient solver for stiff minimization problems. Received July 10, 1995 / Revised version received June 27, 1996     

Strong approximation ofGSBV functions by piecewise smooth functions

Let Ω be an open and bounded subset ofR ⁿ with locally Lipschitz boundary. We prove that the functionsv∈SBV(Ω,R ^m ) whose jump setS _vis essentially closed and polyhedral and which are of classW ^{k, ∞} (S _v,R ^m) for every integerk are strongly dense inGSBV ^p(Ω,R ^m ), in the sense that every functionu inGSBV ^p(Ω,R ^m ) is approximated inL ^p(Ω,R ^m ) by a sequence of functions {v _k{_j∈N with the described regularity such that the approximate gradients ∇v _jconverge inL ^p(Ω,R ^nm ) to the approximate gradient ∇u and the (n−1)-dimensional measure of the jump setsS _{v j} converges to the (n−1)-dimensional measure ofS _u. The structure ofS _v can be further improved in casep≤2.

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Sunto Sia Ω un aperto limitato diR ⁿ con frontiera localmente Lipschitziana. In questo lavoro si dimostra che le funzioniv∈SBV(Ω,R ^m ) con insieme di saltoS _v essenzialmente chiuso e poliedrale che sono di classeW ^{k, ∞} (S _v,R ^m ) per ogni interok sono fortemente dense inGSBV ^p(Ω,R ^m ), nel senso che ogni funzioneu∈GSBV ^p(Ω,R ^m ) è approssimata inL ^p(Ω,R ^m ) da una successione di funzioni {v _j}_j∈N con la regolaritá descritta tali che i gradienti approssimati ∇v _jconvergono inL ^p(Ω,R ^nm ) al gradiente approssimato ∇u e la misura (n−1)-dimensionale degli insiemi di saltoS _{v j}converge alla misura (n−1)-dimensionale diS _u. La struttura diS _vpuó essere migliorata nel caso in cuip≤2.

     

Quadratic Functionals with General Boundary Conditions

The purpose of this paper is to give the Reid ``Roundabout Theorem' for quadratic functionals with general boundary conditions. In particular, we describe the so-called coupled point and regularity condition introduced in [16] in terms of Riccati equation solutions. Accepted 27 February 1996     

Optimal Control in Heterogeneous Domain Decomposition Methods for Advection-Diffusion Equations

New domain decomposition methods (DDM) based on optimal control approach are introduced for the coupling of first and second order equations on overlapping subdomains. Several cost functionals and control functions are proposed. Uniqueness and existence results are proved for the coupled problem, and the convergence of iterative processes is analyzed. The work was supported by the Russian Foundation for Basic Research (04-01-00615) and it was partly carried out while the first author was visiting the IACS at EPFL.     

A $\Gamma$-convergence result for doubling metric measures and associated perimeters

Abstract. In this paper we study the notion of perimeter associated with doubling metric measures or strongly weights. We prove that the metric perimeter in the sense of L. Ambrosio and M. Miranda jr. coincides with the metric Minkowski content and can be obtained also as a -limit of Modica-Mortola type degenerate integral functionals. Received: 27 August 2001 / Accepted: 29 November 2001 / Published online: 10 June 2002 Investigation supported by University of Bologna, funds for selected research topics and by GNAMPA of INdAM, Italy. The authors are very grateful to Luigi Ambrosio and Francesco Serra Cassano for making their preprints available to them, for listening with patience and for many unvaluable suggestions.     

Non-local approximation of the Mumford-Shah functional

The Mumford-Shah functional, introduced to study image segmentation problems, is approximated in the sense of -convergence by a sequence of non-local integral functionals. Received June 6, 1996 / Accepted July 11, 1996     

Exact solutions to linear programming problems

The use of floating-point calculations limits the accuracy of solutions obtained by standard LP software. We present a simplex-based algorithm that returns exact rational solutions, taking advantage of the speed of floating-point calculations and attempting to minimize the operations performed in rational arithmetic. Extensive computational results are presented.