Porous conductive interlayer for dendrite-free lithium metal battery

Lithium(Li) metal,possessing ultrahigh theoretical capacity and the lowest electrode potential,is regarded as a promising new generation anode material.However,the uncontrollable growth of Li dendrites during cycling process gives rise to problems as capacity decay and short circuit,suppressing the cycling and safety performances of Li metal battery.In this contribution,porous conductive interlayer(PCI),composed of carbon nanofibers(CNFs) and polyisophthaloyl metaphenylene diamine(PMIA),is developed to suppress Li dendrites and stabilize Li metal anode.PCI possesses the excellent conductive ability of CNFs and the preeminent mechanical properties of PMIA at the same time.When Li metal contacts with PCI during cycling process,an equipotential surface forms on their interface,which eliminates the tip effect on Li anode and homogenizes Li-ions flux in combination with the uniform porous structure of PCI.Employed PCI,the Li|Cu cell exhibits a remarkable cycling stability with a high average Coulombic efficiency of 97.5% for 100 cycles at 0.5 mA cm^-2.And the Li|LiFePO_4 cell exhibits improved rate capability(114.7 mAh g^-1 at 5.0 C) and enhanced cycling performance(78.9% capacity retention rate over 500 cycles at 1.0 C).This work provides a fresh and effective solving strategy for the problem of dendrites in Li metal battery.     

Ag+掺杂的立方相Y2O3:Eu纳米晶体粉末发光强度研究

采用化学自燃烧法制备了不同Ag⁺掺杂浓度的Y₂O₃:Eu纳米晶体粉末样品(［Y³⁺］∶［Eu³⁺］∶［Ag⁺］=99∶1∶X，X=0—3.5×10^-2)，以及通过退火处理得到了相应的体材料.根据X射线衍射谱确定所得纳米和体材料样品均为纯立方相.实验表明在纳米尺寸样品中随着Ag离子浓度的增加，荧光发射强度随之增加，当X=2×10^-2时达到最大值，其发光强度比X=0时提高了近50%.当Ag离子浓度继续增加，样品发光强度保持不变.在相应的体材料样品中则没有观察到此现象.通过对各样品的发射光谱，激发光谱，X射线衍射图谱，透射电镜(TEM)照片和荧光衰减曲线的研究，分析了引起纳米样品荧光强度变化的原因是由于Ag离子与表面悬键氧结合，从而使这一无辐射通道阻断，使发光中心Eu³⁺的量子效率提高；Ag⁺的引入所带来的另一个效应是使激发更为有效.这两方面原因使发光效率得到了提高.     

Li—方程族的换位表示和一个驻定系统

本文据文[1]的思路,得到了Li-谱所对应的发展方程族的换位表示,并讨论了一个驻定系统.     

锐钛矿二氧化钛超细纳米晶的三声子互作用

本文通过对粒径为2.2-25.5nm的锐钛矿二氧化钛超细纳米晶在83-293 K温度范围内的变温拉曼光谱的研究,得到了三声子互作用对拉曼频率和线宽的贡献随粒径的变化关系。结果表明锐钛矿二氧化钛超细纳米晶的三声子相互作用随粒径减小而加强。     

Liénard型系统解的定性行为

该文讨论非线性系统 x＝1/a(h(y)-F(x)), y＝-a(x)g(x) (E)解的一些定性行为,获得了系统(E)为振动,全局渐近稳定,全局中心的充要条件和周期解的存在的充分条件.     

理想的胰岛素晶体

在自然界或实验室内 ,“理想化”总是一个难以实现的概念 .但最近美国休斯顿大学的P .Vekilov教授及其同事们发现 ,他们常常可以将胰岛素晶体生长成理想的晶体形式 .他们让胰岛素蛋白质在一个已有的胰岛素晶体的螺旋位错缺陷处进行生长 ,蛋白质将绕着这个缺陷发生晶化并形成一个理想晶状胰岛素 .这是因为螺旋位错常常使晶层间产生一个微小的角度偏差 .对于大多数的晶体来说 ,晶层间的相互作用能促进晶体生长时界面间的配置 ,并导致晶层阶跃发生束缚和形成一个有条纹的晶体 .除此之外 ,在溶液中输入被溶解物质也能引起晶层阶跃的约束 .胰岛…     

Studies on Synthesis and properties of Mg-Al-nitrate Layered Ouble Hydroxides

A positive Mg-Al-nitrate layered double hydroxides(LDHs) has been synthesized using a non-steady coprecipitation method.The shape.size,chemical composition,electrical property and anion exchange property of the positve nanoparticle were studied by SEM,XRD,FTIR,chemical analysis,spectroanalysis and meaxsuring of electrophoretic mobilities.Preliminary results show the positive nanoparticle is a promising precursor of polymer/LDHs nanocomposite.     

ON THE UNIQUENESS OF LIMIT CYCLE FOR A GENERALIZED LINARD SYSTEM

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