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Hiroki Hirai Kiichi Nakajima Soichiro Nakatsuka Kazushi Shiren Jingping Ni Shintaro Nomura Toshiaki Ikuta Takuji Hatakeyama 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2015,127(46):13785-13789
The development of a one‐step borylation of 1,3‐diaryloxybenzenes, yielding novel boron‐containing polycyclic aromatic compounds, is reported. The resulting boron‐containing compounds possess high singlet‐triplet excitation energies as a result of localized frontier molecular orbitals induced by boron and oxygen. Using these compounds as a host material, we successfully prepared phosphorescent organic light‐emitting diodes exhibiting high efficiency and adequate lifetimes. Moreover, using the present one‐step borylation, we succeeded in the synthesis of an efficient, thermally activated delayed fluorescence emitter and boron‐fused benzo[6]helicene. 相似文献
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Mingze Li Jun Zhou Guojun Zhou Maxim S. Molokeev Jing Zhao Viktoriia Morad Maksym V. Kovalenko Zhiguo Xia 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(51):18843-18848
Very little is known about the realm of solid‐state metal halide compounds comprising two or more halometalate anions. Such compounds would be of great interest if their optical and electronic properties could be rationally designed. Herein, we report a new example of metal halide cluster‐assembled compound (C9NH20)9[Pb3Br11](MnBr4)2, featuring distinctly different anionic polyhedra, namely, a rare lead halide cluster [Pb3Br11]5? and [MnBr4]2?. In accordance with its multinary zero‐dimensional (0D) structure, this compound is found to contain two distinct emission centers, 565 nm and 528 nm, resulting from the formation of self‐trapped excitons and 4T1‐6A1 transition of Mn2+ ions, respectively. Based on the high durability of (C9NH20)9[Pb3Br11](MnBr4)2 upon light and heat, as well as high photoluminescence quantum yield (PLQY) of 49.8 % under 450 nm blue light excitation, white light‐emitting diodes (WLEDs) are fabricated, showcasing its potential in backlight application. 相似文献
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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(47):15202-15205
Two efficient blue thermally activated delayed fluorescence compounds, B‐oCz and B‐oTC , composed of ortho‐donor (D)–acceptor (A) arrangement were designed and synthesized. The significant intramolecular D–A interactions induce a combined charge transfer pathway and thus achieve small ΔE ST and high efficiencies. The concentration quenching can be effectively inhibited in films of these compounds. The blue non‐doped organic light emitting diodes (OLEDs) based on B‐oTC prepared from solution processes shows record‐high external quantum efficiency (EQE) of 19.1 %. 相似文献
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