增长曲线模型中回归系数的广义根方估计

本文对增长曲线模型中的回归系数B提出了一种新的估计形式－广义根方估计的B（K），其中K＝diag(k1,k2,…，kp）并证明了通过广义根方偏参数ki(i=1,2,…，p）的适当选取可使得该估计在均方误差矩阵的意义下优于已有的LS估计和根方估计，及广义根方估计是可容许估计，本文还给出了选取广义根方偏参数的两种方法，算法及一个应用实例。     

Determination of degree of conversion as a function of depth of a photo-initiated dental restoration composite—III application to commercial Prodigy Condensable™

In this third work, we evaluated the degree of conversion (DC) versus depth of dental filling composite named Prodigy Condensable™ using infrared spectroscopy. Confirming previous results, there was a gradual reduction of DC with increasing depth but the composite exhibited extreme values of DC, an upper value (45.9%) on the surface and a lower one (6.1%) at a depth of 5 mm. The composite presented the worst performance among materials studied. The composite formulation was 80% of inorganic fillers and BisfenolA/dimethacrylate (BisGMA) (18%)/triethyleneglycoldimethacrylate (TEGDMA) (2.0%) as monomers. As stated before, type/ratio/viscosity of monomers and type, amount, size and size distribution of fillers all together had an important role in the cure reaction contributing to the final performance of the composite.     

基于C语言的等效电子耦合原子态的编程计算

详述了用turboc2.0编程计算等效电子LS耦合原子态的方法,并给出了计算nf5电子组态的LS耦合原子态的具体程序.     

高氯酸盐与十六烷基三甲基溴化铵作用的光散射

利用光散射光谱法研究了高氯酸根和阳离子表面活性剂十六烷基三甲基溴化铵(CTAB)的作用。 在酸性条件下,高氯酸根和CTAB通过静电作用形成离子缔合物,导致体系光散射强度增强。 环境水样中的常见阴离子如Cl^-、Br^-、ClO₃^-、NO₃^-和PO₄^3-等与CTAB单独作用时其光散射强度很弱,而当它们与高氯酸根同时存在时,由于协同作用使体系散射强度发生改变。 以Cl^-为例,借助动态光散射测定,初步探讨了体系协同作用的机理。     

NSD序列加权和的中心极限定理及其在EV回归模型中的应用

基于负超可加相依(简称为NSD)随机序列的性质及其一些不等式,利用随机变量的截断方法建立了NSD随机序列加权和的中心极限定理,从而推广了负相协NA随机序列的相应结论.并将其应用到变系数EV回归模型,得到了未知参数LS估计的渐近正态性.     

LS解法和Fisher方程行波系统的定性分析

提出了求解非线性发展方程的新方法——LS解法.LS解法是基于(G’/G)展开法和扩展的双曲正切函数展开法.并引入了Poincar定性理论的思想,然后以Fisher方程为例进行了试验.通过定性分析首先获得了Fisher方程行波系统积分曲线的性质,然后解得了Fisher方程作为耗散系统时单调减少的波前解和作为扩张系统时单调递增的波前解.一些试验结果与Ablowitz所得结果一致.也得到了Fisher方程作为扩张系统时的新结果.LS解法是在定性理论指导下,在已获知解曲线性质的情况下进行精确求解的,求解目标明确.LS解法揭示了线性系统也可以用作辅助方程来求解非线性系统.     

Separation of lignosulfonate from its aqueous solution using supported liquid membrane

This paper presents an experimental and theoretical study on facilitated transport of lignosulfonate (LS) through a flat sheet supported liquid membrane using trioctylamine (TOA) as carrier and dichloroethane as diluent. The studies were carried out with various support materials and operating conditions (viz. carrier concentration, strip phase concentration, salt concentration, etc.) and their effects on the transport of LS. The results were analyzed to identify a suitable combination of support and operating condition that would yield best performance of the supported liquid membrane (SLM) in terms of fast and efficient transport of LS. The stability of the SLM was assessed in terms of loss of liquid from the pores of membrane support. The SLM is found to be stable till 10 h. Co-transport mechanism has been adopted in this work by using NaOH as the strip phase. It was observed that extraction of LS is increased with increase in concentration of NaOH up to a limiting value of 0.5 M NaOH. Difference of salt concentration between feed and strip phase considerably affect the separation process. The diffusional resistances of organic membrane (Δorg) and aqueous solution (Δaq) calculated from the permeation model, which is again a combination of three unique mechanisms viz., diffusion through a feed aqueous layer, a fast interfacial chemical reaction, and diffusion of carrier–complex through the organic membrane, are found to be 609.9 and 176.6 s cm⁻¹, respectively. The values of the diffusion coefficient in the membrane (D_org) and in the bulk organic phase (D_complex) are 1.67×10⁻⁹ and 6.68 × 10⁻⁸ m²s⁻¹, respectively. The extraction of LS is about 90%. Nearly 43% of LS can be recovered at optimum condition.     

Simultaneous separation of mercury and lignosulfonate from aqueous solution using supported liquid membrane

This paper presents an experimental investigation on facilitated and simultaneous transport of mercury and lignosulfonate (LS) through a flat sheet supported liquid membrane (SLM) having Nylon 6,6 as support, trioctylamine (TOA) as carrier and dichloroethane as solvent. The experiments were performed at various operating conditions such as strip phase concentration, feed pH, carrier concentration and feed concentration to find the best set of parameters that would yield the maximum separation of pure mercury as well as its mixture with LS. The experiments were performed in co-transport mode using NaOH as the strip phase. It was observed that extraction of mercury as well as its mixture increases with increase in concentration of NaOH up to a certain limit 0.1 M NaOH in case of pure solution and 0.2 M NaOH in case of mixture). Feed phase pH significantly affects the mercury separation process. However, initial feed concentration does not affect the extraction process appreciably. Separation of mixture of mercury and LS behaves in a similar way as their pure solution; however the extraction is low in comparison to pure solution. The extraction of mercury from its pure solution is about 81% in 1 h. The extraction of mercury and LS from their mixture is about 52.6% and 50.2%, respectively at optimum condition and in a period of 2 h.     

神经网络算法及其在GPS导航中的应用

GPS导航解算中常采用最小二乘算法。由于导航解算中存在观测异常（粗差），采用的模型精度很难满足用户需求，而高动态用户需求的精度却不断提高，为此文中提出一种利用神经网络的非线性逼近能力，在顾及观测信息权阵的条件下，利用Hopfieid神经网络进行GPS导航解算的新算法。该算法具有很好的抗差性和自适应性，能较好地抑制观测粗差对导航解的影响。计算结果证明了该算法的有效性。     

ⅡA,ⅡB族第一激发态原子中的角动量耦合

随着主子量子数ｎ增大，ⅡＡ，ⅡＢ族第一激发态原子中价壳电子间库仑排斥作用减弱，电子自身自旋－轨道相互作用相对增强，从而导致其对ＬＳ耦合方式的逐渐偏离和ｉｊ耦合方式的逐渐介入，组态混合方法可用来定量计算ＬＳ耦合方式的偏离程度。