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1.
Hongchao Li Yufeng Hu Yanguang Zhang Dongge Ma Lixiang Wang Xiabin Jing Fosong Wang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(16):3947-3953
A conjugated poly(p‐CN‐phenylenevinylene) (PCNPV) containing both electron‐donating triphenylamine units and electron‐withdrawing cyano groups was prepared via Knoevenagel condensation in a good yield. Gel permeation chromatography suggested that the soluble polymer had a very high weight‐average molecular weight of 309,000. A bright and saturated red emission was observed under UV excitation in solution and film. Cyclic voltammetry showed that the polymer presented quasi‐reversible oxidation with a relatively low potential because of the triphenylamine unit. A single‐layer indium tin oxide/PCNPV/Mg–Ag device emitted a bright red light (633 nm). © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3947–3953, 2004 相似文献
2.
We extend an earlier method for solving kinetic boundary layer problems to the case of particles moving in aspatially inhomogeneous background. The method is developed for a gas mixture containing a supersaturated vapor and a light carrier gas from which a small droplet condenses. The release of heat of condensation causes a temperature difference between droplet and gas in the quasistationary state; the kinetic equation describing the vapor is the stationary Klein-Kramers equation for Brownian particles diffusing in a temperature gradient. By means of an expansion in Burnett functions, this equation is transformed into a set of coupled algebrodifferential equations. By numerical integration we construct fundamental solutions of this equation that are subsequently combined linearly to fulfill appropriate mesoscopic boundary conditions for particles leaving the droplet surface. In view of the intrinsic numerical instability of the system of equations, a novel procedure is developed to remove the admixture of fast growing solutions to the solutions of interest. The procedure is tested for a few model problems and then applied to a slightly simplified condensation problem with parameters corresponding to the condensation of mercury in a background of neon. The effects of thermal gradients and thermodiffusion on the growth rate of the droplet are small (of the order of 1%), but well outside of the margin of error of the method. 相似文献
3.
微波促进下N,N-二甲基甲酰胺中的Knoevenagel反应 总被引:2,自引:0,他引:2
在微波促进下,芳醛与丙二腈或氰基乙酸乙酯在DMF中进行Knoevenagel缩合反应,以77%~98%的产率生成相应E-式烯烃。 相似文献
4.
2,6-二氨基吡啶与苦基氯的反应历程研究 总被引:2,自引:0,他引:2
对2,6-二氨基吡啶与苦基氯的反应历程进行了研究。通过二氨基吡啶与几种多硝基卤代苯的反应、溶剂效应、NaF的促进作用和紫外光谱吸收,证实该反应属于芳香族亲核取代反应类型,按加成-消除历程进行,反应过渡态涉及一个Mcisenheimer络合物。 相似文献
5.
Guo Hua GAO Jin Bao GAO Wen Juan ZHOU Liang LU Ming Yuan HE 《中国化学快报》2006,17(10):1293-1296
Since much more attention has been paid to the sustainable development, many researchers try to improve conventional chemical process and find new and more, environmentally friendly routes1. Aqueous-phase reactions are of interest as environ- mentally ben… 相似文献
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8.
碳苷合成研究——3-β-D-吡喃木糖基-1,2,4-氧杂二唑类化合物的合成 总被引:1,自引:0,他引:1
本文研究了1-(2,3,4-三-O-苯甲酰-β-D-吡喃木糖基)-偕氨基肟与酸酐及酰氯的缩合反应,探讨了不同缩合剂、不同取代基对环合反应的影响,与酸酐反应可以一步完成,且收率较好;与酰氯反应分两步进行,第一步酰化,第二步脱水环合,芳环上取代基的电性效应,决定环合反应的难易,并证明了该环系的碳苷对酸、碱、热具有化学稳定性,本文合成了12个氧杂二唑类木糖碳苷及2个木糖基化的开环产物,通过光谱及元素分析,确定了它们的结构。 相似文献
9.
以乙酰丙酮(1)的电氧化偶联产物3,4-二乙酰基-2,5-己二酮(2)为原料,在酸性介质中与取代苯胺(3a ̄3g)作用,得到1,4-二羰基的缩合产物2,5-二甲基-3,4-二乙酰基-1-芳基吡咯(4a ̄4g)。在相似的条件下,2与水合肼作用,则得到1,3-二羰基的缩合产物3,3',5,5'-四甲基-1,1'-二氢-4,4'-联吡唑(5)。 相似文献
10.
Martin Winterwerber Rouzita Geiger Ursula Predoiu Hans-Hartwig Otto 《Monatshefte für Chemie / Chemical Monthly》2006,137(11):1441-1451
Summary. Reactions of cyanomethanesulfonamides with aromatic aldehydes in the presence of AcOH and piperidine produced the addition products, the 1-cyano-2-arylethenesulfonamides, whereas reactions with benzonitrile
yielded the 2-amino-1-cyano-2-phenylethenesulfonamides only when done in THF with BuLi. No addition products were isolated from the analogue reactions with 2-hydroxybenzaldehyde (salicylaldehyde). Instead,
we obtained 2-imino-2H-chromene-3-sulfonamides with good to excellent yields. These 2H-chromene derivatives allowed a number of transformations, from which the reactions with orthoformates opened an approach
to the hitherto unknown benzopyrano[3,2-e] [1,2,4]thiadiazine ring system. 相似文献