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排序方式: 共有417条查询结果,搜索用时 62 毫秒
1.
We study problems of interpolation of positive linear operators in couples of ordered Banach spaces. From this viewpoint, we study couples of noncommutative spaces L 1, L ∞ associated with weights and traces on von Neumann algebras. 相似文献
2.
3.
4.
考察了中性分子电对H_2Q/Q在13X型分子筛修饰电极上的电化学行为。发现H_2Q/Q电对在修饰电极上电响应迅速,为双电子可逆反应,不受溶液温度及电极与溶液相对运动的影响,而与溶液的pH值有关。当pH≤2.0时,修饰电极对H_2Q/Q电对的氧化/还原有明显的催化作用. 相似文献
5.
Nanostructure Pt Electrode Obtained via Self-assembly of Nanoparticles on Conductive Oxide-coated Glass Substrate 总被引:1,自引:0,他引:1
Self-assembly of platinum nanoparticles were applied to fabrication of counter electrode for dye-sensitized solar cells on conductive oxide-coated glass substrate. The present Pt electrode exhibits high exchange current density of 220 mA/cm^2, which is comparable to those prepared by electrodeposition, magnetron sputtering or thermal decomposition of platinum chloride. After analysis by transmission electron microscopy (TEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS), it was found that the catalyst was structurally characterized as nanosized platinum metal clusters and was continuously arranged on electrode surface. The present nanostructure electrode had high electrocatalytic activity for the reduction of iodine in organic solution. 相似文献
6.
This study aims to clarify the effects of carbon activation type and physical form on the extent of adsorption capacity and
desorption capacity of a bi-solute mixture of phenol and 2-chlorophenol (2-CP). For this purpose, two different PACs; thermally
activated Norit SA4 and chemically activated Norit CA1, and their granular countertypes with similar physical characteristics,
thermally activated Norit PKDA and chemically activated Norit CAgran, were used. The thermally activated carbons were better
adsorbers for phenol and 2-CP compared with chemically activated carbons, but adsorption was more reversible in the latter
case. 2-CP was adsorbed preferentially by each type of activated carbon, but adsorption of phenol was strongly suppressed
in the presence of 2-CP. The simplified ideal adsorbed solution (SIAS) model underestimated the 2-CP loadings and overestimated
the phenol loadings. However, the improved and modified forms of the SIAS model could better predict the competitive adsorption.
The type of carbon activation was decisive in the application of these models. For each activated carbon type, phenol was
desorbed more readily in the bi-solute case, but desorption of 2-CP was less compared with single-solute. This was attributed
to higher energies of 2-CP adsorption. 相似文献
7.
J. Tolchard 《Journal of solid state chemistry》2007,180(10):2808-2815
The chemical and physical compatibility of SrCeO3 is investigated with respect to LaMO3 (M=Mn, Fe, Co) and La2−xSrxNiO4 (x=0, 0.8), via the reaction of fine-grained powder compacts and solid-state diffusion couples. Compositions were chosen so as to give predictive insight into possible candidate materials for all-oxide electrochemical devices. Results show the primary reaction in these systems to be the dissolution of SrO from SrCeO3 into the LaMO3/La2−xSrxNiO4, and corresponding formation of La-doped CeO2. Reaction kinetics are observed to be relatively fast, with element profiles suggesting the diffusion of Sr2+ in ceria to be surprisingly rapid. It is demonstrated that perovskite starting materials represent poor candidates for use with SrCeO3, reacting completely to form Ruddlesden-Popper/K2NiF4 type oxides. Reaction with La2NiO4 is less pronounced, and formation of secondary phases suppressed for the composition La1.2Sr0.8NiO4. It is thus concluded that Ruddlesden-Popper type oxides represent good candidate materials for use with a SrCeO3-based electrolytes when doped with appropriate levels of Sr. 相似文献
8.
Laura S. Zamorano Francisco Gavilanes Ivan Yu. Sakharov Robert B. van Huystee Valery L. Shnyrov 《Thermochimica Acta》2004,417(1):67-73
Detailed differential scanning calorimetry (DSC), steady-state tryptophan fluorescence and far-UV circular dichroism (CD) studies, together with enzymatic assays, were carried out to monitor the thermal stability of anionic peanut peroxidase (aPrx) at pH 3.0. The spectral parameters were seen to be good complements to the highly sensitive but integral method of DSC. Thus, changes in far-UV CD corresponded to changes in the overall secondary structure of the enzyme, while changes in intrinsic tryptophan fluorescence emission corresponded to changes in the tertiary structure of the enzyme. The results, supported with data concerning changes in enzymatic activity with temperature, show that thermally induced transitions for aPrx are irreversible and strongly dependent upon the scan rate, suggesting that denaturation is under kinetic control. It is shown that the process of aPrx denaturation can be interpreted with sufficient accuracy in terms of the simple kinetic scheme, , where k is a first-order kinetic constant that changes with temperature, as given by the Arrhenius equation; N is the native state, and D is the denatured state. On the basis of this model, the parameters of the Arrhenius equation were calculated. 相似文献
9.
Ezequiel V. Albano 《Journal of statistical physics》1995,78(3-4):1147-1155
The spreading of a globally distributed damage, created in the stationary regime, is studied in a single-component irreversible reaction process, i.e., the BK model [Browne and Kleban,Phys. Rev. A
40, 1615 (1989)]. The BK model describes one variant of the A+AA2 reaction process on a lattice in contact with a reservoir of A species. The BK model has a single parameter, namely the rate of arrival of A species to the lattice (Y). The model, exhibits an irreversible phase transition between a stationary reactive state with production of A2 species and a poisoned state with the lattice fully covered by A species. The transition takes place at critical points (Y
C
) which solely depend on the Euclidean dimensiond. It is found that the system is immune ford=1 andd=2, in the sense that even 100% of initial damage is healed within a finite healing period (T
H
). Within the reactive regime,T
H
diverges when approachingY
C
according toT
H
(Y
C
–Y)–, with 1.62 and 1.08 ford=1 andd=2, respectively. Ford=3 a frozen-chaotic transition is found close toY
s
0.4125, i.e., well inside the reactive regime 0YY
C
0.4985. Just atY
S
the damageD(t) heals according toD(t) t
–, with 0.71. For the frozen-chaotic transition atd=3 the order parameter critical exponent 0.997 is determined. 相似文献
10.
热导式热量计特征热谱方程的建立 总被引:1,自引:0,他引:1
Based on the interfacial model of a conduction calorimeter, a characteristic thermogram equation is suggested in this paper. Measurements of only two quantities such as the maximum peak height △m and its time tm, enables us to calculate the peak height at any interval by using this model. Thermograms of alkaline hydrolysis of ethyl propionate and ethyl acetate have been measured at 25℃, respectively. The themographic data calculated by using the characteristic thermogram equation are in reasonable agreement with those read from the thermograms. 相似文献