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1.
B. Gillot F. Bouton J.F. Ferriot F. Chassagneux A. Rousset 《Journal of solid state chemistry》1977,21(4):375-385
When Fe3+ ions are substituted by aluminum or chromium on magnetite octahedral sites, the ir spectrum shows the conversion of an inverse spinel to a normal spinel. Both broad bands of magnetite are gradually replaced by the four characteristic bands of normal spinels II–III. They are also observed for solid solutions, FeCr2O4FeAl2O4, with, however, a further band at 780 cm?1 which may be assigned to Al3+ ions on tetrahedral sites. Low-temperature (<400°C) oxidation of these compounds whose sizes are less than 2000 Å results in lacunar spinels III–III. The ir spectrum of these solids is characterized by two absorption bands (as for inverse spinels II–III) except for compounds close to pure γFe2O3 in which an order of vacancies could be put in evidence. 相似文献
2.
E. Blasius und J. Münch 《Fresenius' Journal of Analytical Chemistry》1972,261(3):198-203
Zusammenfassung Das neue Mikrobestimmungsverfahren beruht auf der coulometrischen Titration von S2O3
2– nach vorheriger Abbaureaktion der Polythionate mit Sulfit bzw. Cyanid. Es werden 10 ml Probelösung (S4O6
2–: 5 · 10–5 bis 1 · 10–3 M; S5O6
2–; 2,5 · 10–5 bis 1· 10–3 M; S6O6
2–: 1,66 · 10–5 bis 1 · 10–3 M) benötigt. Die Titrationskurve wird von einem Schreiber registriert. Die Reproduzierbarkeit der jeweiligen Einzelbestimmung liegt bei VK
p±0,1 bis ± 1,6%.
Rapid coulometric microdetermination of individual polythionates
The method described is based on the coulometric titration of S2O3 2– after a preceding degradation of the polythionates with sulphite or cyanide. 10 ml of sample solution are required (S4O6 2–: 5× 10–5 to 1×10–3 M; S5O6 2– : 2.5×10–5 to 1×10–3 M; S6O6 2–: 1.66×10–5 to 1×10–3 M). The titration curve is recorded. The reproducibility of a single determination is VK p±0.1 to ± 1.6%.相似文献
3.
G. G. Fedoruk 《Journal of Applied Spectroscopy》2002,69(2):161-182
The application of transient nutations in EPR spectroscopy of condensed media is considered. The main methods of formation and observation of transient nutations are presented. The laws governing this phenomenon in twolevel and multilevel spin systems and also in inhomogeneous broadening of EPR lines are described. Recent advances in the use of transient nutations to separate overlapping spectra, identify quantum numbers and quantum transitions, investigate the kinetics of photoinduced paramagnetic centers, and determine relaxation times for a wide range of crystalline and disordered media are presented. 相似文献
4.
Model equations for the shape of the Eiffel Tower are investigated. One model purported to be based on Eiffel's writing does not give a tower with the correct curvature. A second popular model not connected with Eiffel's writings provides a fair approximation to the tower's skyline profile of 29 contiguous panels. Reported here is a third model derived from Eiffel's concern about wind loads on the tower, as documented in his communication to the French Civil Engineering Society on 30 March 1885. The result is a nonlinear, integro-differential equation which is solved to yield an exponential tower profile. It is further verified that, as Eiffel wrote, “in reality the curve exterior of the tower reproduces, at a determined scale, the same curve of the moments produced by the wind”. An analysis of the actual tower profile shows that it is composed of two piecewise continuous exponentials with different growth rates. This is explained by specific safety factors for wind loading that Eiffel & Company incorporated in the design of the free-standing tower. To cite this article: P. Weidman, I. Pinelis, C. R. Mecanique 332 (2004). 相似文献
5.
《Comptes Rendus Chimie》2015,18(3):315-323
To improve the hydrogen content of a biomass steam gasification syngas, Water–Gas Shift Fe/CeO2 catalysts supported on ceramic foams were developed. The impregnation of ceria as washcoat led to an increase in the support surface area (BET) and to the formation of well-dispersed iron particles (XRD and TPR) by iron oxide impregnation. Catalytic tests were performed at atmospheric pressure with minor pressure drops, under a gas mixture similar to that produced at the gasifier outlet. A satisfactory CO conversion and a large increase in H2 content were reached by adjusting the operating parameters of the WGS and the catalysts’ composition. After-test characterizations indicated in situ catalysts activation with no over-reduction and a positive action of ceria on iron dispersion and sintering prevention. 相似文献
6.
Igor Selezov Olga Avramenko Christian Kharif Karsten Trulsen 《Comptes Rendus Mecanique》2003,331(3):197-201
The nonlinear problem for propagation of wave-packets along the interface of two semi-infinite fluids is solved on the basis of multiple scale asymptotic expansions. Unlike all previous investigations dealing only with third-order approximations, here fourth-order approximation is developed. The corresponding solvability condition is obtained and the evolution equation in the case away from the cut-off wave number is derived. As a result, the nonlinear higher-order Schrödinger equation is obtained which contains the nonlinear part in a compact form. This equation is valid for a wide range of wave numbers. The stability diagram shows regions of stability and instability of capillary-gravity wave-packets. To cite this article: I. Selezov et al., C. R. Mecanique 331 (2003). 相似文献
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8.
Marie-Claude Arnaud 《Bulletin of the Brazilian Mathematical Society》2006,37(2):153-190
Résumé. Soit L : T M → ℝ un lagrangien optique et homogène dans la fibre défini sur le fibré tangent d’une variété orientable de dimension n et γ un lacet régulier 1-périodique qui est un point critique non dégénéré d’indice p de l’action lagrangienne associée à L (il lui correspond alors un point périodique (x, v) du flot d’Euler-Lagrange (φt )). Soit T une transversale en (x, v) au champ de vecteurs dans la surface d’énergie et P l’application de premier retour de Poincaré dans cette transversale; on montre alors que le nombre de Lefschetz pour P en (x, v) est (−1)n−1+p. On en déduit que si 2nh est le nombre de multiplicateurs de Floquet réels strictement positifs et non nuls, alors: nh = n − 1 + p (mod 2).
On explique comment déduire qu’un lagrangien optique quelconque défini sur le fibré tangent d’une variété orientable compacte
de dimension paire de π1 non trivial a une une orbite périodique qui est soit dégénérée, soit a un exposant de Floquet hyperbolique dans tout niveau
d’énergie au dessus du niveau critique de Ma?é.
相似文献
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10.
将平均晶粒尺寸为4.6 nm的金粒子通过静电作用粘附于聚苯乙烯(PS)微球表面用于化学镀,化学镀金后PS表面的金沉积层几乎达到完全包覆,厚度70~90 nm;在Au/PS表面进行化学镀银,沉积的银颗粒堆积紧密,颗粒大小较先前沉积的金颗粒大,镀覆层厚度增厚至200~400 nm;模板去除后,获得了完全自支撑的Au40Ag60空心微球结构的圆柱状泡沫材料。制备的金银合金泡沫由直径约10 m的空心球壳组成,圆柱体直径约5 mm,密度约1.2 g/cm3。 相似文献