全文获取类型
收费全文 | 221篇 |
免费 | 3篇 |
国内免费 | 102篇 |
专业分类
化学 | 317篇 |
力学 | 1篇 |
物理学 | 8篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 1篇 |
2021年 | 4篇 |
2020年 | 4篇 |
2019年 | 5篇 |
2018年 | 5篇 |
2017年 | 9篇 |
2016年 | 8篇 |
2015年 | 6篇 |
2014年 | 7篇 |
2013年 | 21篇 |
2012年 | 8篇 |
2011年 | 20篇 |
2010年 | 30篇 |
2009年 | 22篇 |
2008年 | 33篇 |
2007年 | 31篇 |
2006年 | 26篇 |
2005年 | 14篇 |
2004年 | 24篇 |
2003年 | 10篇 |
2002年 | 11篇 |
2001年 | 9篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1997年 | 2篇 |
1993年 | 1篇 |
1990年 | 1篇 |
排序方式: 共有326条查询结果,搜索用时 15 毫秒
1.
We wish to report synthesis of perfluorinated functionalized, branched ethers from their hydrocarbon analogues by direct fluorination. Yields up to 90%, with high purities, have been obtained at ambient temperature and pressure. This technique will likely develop into a new general method for producing perfluorinated, hyperbranched and dendritic polymers. 相似文献
2.
用ATRP法构筑核壳型梯度极性的多羟基多臂星状超支化聚合物及聚合物刷——双层聚合物刷的合成与表征 总被引:3,自引:0,他引:3
设计并通过原子转移自由基聚合方法 (ATRP)合成了核壳型多羟基多臂星状超支化聚合物刷 .以 2 溴异丁基酰溴封端的超支化聚 (3 乙基 3 羟甲基氧杂环丁烷 ) (HP Br)作为大分子引发剂 ,采用Cu(I)Br和N ,N ,N′ ,N′ ,N″ 五甲基二乙基三胺 (PMDETA)催化体系 ,在丁酮与丙醇的混和溶液中 ,通过甲基丙烯酸羟乙酯(HEMA)的ATRP溶液聚合 ,得到了一系列含有大量羟基的多臂星状超支化聚合物刷 (HP g PHEMA) ,并考察了其羟基的活性 ,发现羟基还可以与苯甲酰氯发生反应 .产物的结构和热性能用1 H NMR、FTIR、GPC、TGA、DSC等进行了表征和测试 . 相似文献
3.
Emilie Barriau Holger Frey Anton Kiry Manfred Stamm Franziska Gröhn 《Colloid and polymer science》2006,284(11):1293-1301
The preparation of carboxylated hyperbranched polyglycerols of narrow polydispersity was achieved by modification (78–90%) of the hydroxyl end groups via Michael addition of acrylonitrile, followed by hydrolysis. High conversion could only be achieved for low molecular weight starting materials (520 and 1,030 g mol−1). The solution properties of the resulting materials were investigated by dynamic light scattering (DLS), showing the formation of large aggregates with size depending on the pH value. After deposition on a negatively charged mica surface, the structures observed by atomic force microscope (AFM) show the coexistence of aggregates and single macromolecules. Most interesting, in the case of the lower molecular weight sample (PG 520 g mol−1), extended and ordered terrace structures were formed, which are unprecedented for hyperbranched polymers and are of interest for surface modification in general. 相似文献
4.
A series of novel multi-arm star side-chain liquid crystalline (LC) copolymers with hyperbranched core moieties were synthesized by atom transfer radical polymerization (ATRP) using a multi-functional hyperbranched polyether as the initiator and chlorobenzene as the solvent. The multi-functional hyperbranched polyether initiator was prepared from poly(3-ethyl-3-(hydroxymethyl)oxetane) (PEHO) and 2-bromo-2-methylpropionyl bromide. The azobenzene side-chain liquid crystalline arms were designed to have an LC conformation of poly[6-(4-methoxy-4′-oxy-azobenzene)hexyl methacrylate] with different molecular weights. Their characterization was performed with 1H NMR, size exclusion chromatograph (SEC), differential scanning calorimetry (DSC) and thermal polarized optical microscopy (POM). The multi-arm star side-chain liquid crystalline copolymers exhibited a smectic and a nematic phase, and the phase transition temperatures from the smectic to the nematic phase and from the nematic to isotropic phase increased with increasing the molecular weight of the multi-arm star side-chain liquid crystalline copolymers from 1.78 × 104 to 9.07 × 104. 相似文献
5.
Xiu Xia WANG Zhi Gang JIANG Yi Feng ZHANG 《中国化学快报》2006,17(1):125-128
Epoxy resins are widely used in coatings, adhesives and polymer composites, but the applications of cured epoxy resins are often restricted by their poor toughness. HBP can be used as toughener to improve the toughness of epoxy resins due to its high-dens… 相似文献
6.
Kinetics study of thermal decomposition of epoxy resins containing flame retardant components 总被引:1,自引:0,他引:1
Qingfeng Wang 《Polymer Degradation and Stability》2006,91(8):1747-1754
Hyperbranched polyphosphate ester (HPPE) and phenolic melamine (PM) were blended in different ratios with a commercial epoxy resin to obtain a series of flame retardant resins. The thermal decomposition mechanism of their cured products in air was studied by thermogravimetric analysis and in situ Fourier-transform infrared spectroscopy. The degradation behaviours of epoxy resins containing various flame retardant components were found to be greatly changed. The incorporation of phosphorus and nitrogen compounds improved the thermal stability at elevated temperature. The kinetics of thermal decomposition was evaluated by Kissinger method, Flynn-Wall-Ozawa method and Horowitz-Metzger method. The results showed that the activation energy at lower degree of the degradation decreased by the incorporation of flame retardant components, while increased at higher degree of the degradation. 相似文献
7.
SYNTHESIS OF HYPERBRANCHED CONJUGATIVE POLY(ARYLENEETHYNYLENE)S BY ALKYNE POLYCYCLOTRIMERIZATION 总被引:2,自引:0,他引:2
A series of new hyperbranched poly(aryleneethynylene)s are synthesized by the copolycyclotrimerizations oftetraynes(Ⅰand Ⅱ)with aliphatic monoynes(A-C)catalyzed by tantalum-,niobium-,and cobalt-based catalysts.All thereactions proceed smoothly and soluble polymers of high molecular weights(M_w up to 3.8×10~4)are obtained in high yields(up to 97%). 相似文献
8.
Jun‐Yi Chen Zi‐Long Xiang Feng Yu Bert F. Sels Yu Fu Ting Sun Mario Smet Wim Dehaen 《Journal of polymer science. Part A, Polymer chemistry》2014,52(18):2596-2603
A series of hyperbranched polyacenaphthenequinones has been prepared by superelectrophilic aromatic substitution of (substituted) acenaphthenequinone and 1,3,5‐tris‐(4‐phenoxybenzoyl)benzene via a facile A2 + B3 approach. Because of the strongly increased reactivity of the second A functionality, gelation was efficiently avoided during the polymerization. The structure of the resulting polymer was characterized by NMR spectroscopy and gel permeation chromatography. Further modification of the hyperbranched polyacenaphthenequinone was explored both on the acenaphthenequinone and aromatic moieties. Moreover, the polymer modified through sulfonation was investigated as a water‐soluble acid catalyst for the degradation of biomass resources. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 2596‐2603 相似文献
9.
《高分子科学杂志,A辑:纯化学与应用化学》2013,50(11):1301-1315
Three hyperbranched multi-methacrylates (H20-MMA, H30-MMA and H40-MMA) have been synthesized by reacting Boltorn dendritic polyols with methacrylic anhydride and methacryloyl chloride. Their structures were characterized by FT-IR and NMR (1H and 13C) and molecular weights were measured by GPC. These multi-methacrylates (H-MMAs) mixed well with a variety of monomers such as acrylic acid (AA), methacrylic acid (MA), methyl methacrylate (MMA), 2-hydroxy-ethyl methacrylate (HEMA), tri(ethylene glycol) dimethdimethacrylate (TEGDMA), and bisphenol A glycidyl dimethacrylate (BisGMA). The initial studies on thermal polymerization activities of 10% of H-MMAs with AA, MA, and MMA showed that they gave higher polymerization enthalpy than the corresponding homopolymerization. The resulting materials showed one glass transition temperature, indicating a typical single-phase resin. The H-MMAs can effectively copolymerize with AA, MA, and MMA, with essentially no homopolymers produced, as indicated by acetone extraction studies. This indicated that the hyperbranched multi-methacrylates have the potential to be used as crosslinking agents or modifiers with a number of monomers to produce new thermosets. 相似文献
10.
A novel approach for assembling homogeneous hyperbranched polymers based on non-covalent interactions with aflatoxins was developed; the polymers were used to evaluate the extraction of aflatoxins B1, B2, G1 and G2 (AFB1, AFB2, AFG1 and AFG2) in simulant solutions. The results showed that the extraction efficiencies of three kinds of synthesized polymers for the investigated analytes were not statistically different; as a consequence, one of the representative polymers (polymer I) was used as the solid-phase extraction (SPE) sorbent to evaluate the influences of various parameters, such as desorption conditions, pH, ionic strength, concentration of methanol in sample solutions, and the mass of the sorbent on the extraction efficiency. In addition, the extraction efficiencies for these aflatoxins were compared between the investigated polymer and the traditional sorbent C18. The results showed that the investigated polymer had superior extraction efficiencies. Subsequently, the proposed polymer for the SPE packing material was employed to enrich and analyze four aflatoxins in the cereal powder samples. The limits of detection (LODs) at a signal-to-noise (S/N) ratio of 3 were in the range of 0.012–0.120 ng g−1 for four aflatoxins, and the limits of quantification (LOQs) calculated at S/N = 10 were from 0.04 to 0.40 ng g−1 for four aflatoxins. The recoveries of four aflatoxins from cereal powder samples were in the range of 82.7–103% with relative standard deviations (RSDs) lower than 10%. The results demonstrate the suitability of the SPE approach for the analysis of trace aflatoxins in cereal powder samples. 相似文献